Characterization of molecular channel in photodissociation of SOCl2 at 248 nm: Cl2 probing by cavity ring-down absorption spectroscopy

2015 ◽  
Vol 17 (12) ◽  
pp. 7838-7847 ◽  
Author(s):  
Bo-Jung Chen ◽  
Po-Yu Tsai ◽  
Ting-Kang Huang ◽  
Zhu-Hong Xia ◽  
King-Chuen Lin ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Chlorine Molecule ◽  
The One ◽  
Molecular Channel ◽  
Cavity Ring Down

A primary elimination channel of the chlorine molecule in the one-photon dissociation of SOCl2 at 248 nm was investigated using cavity ring-down absorption spectroscopy (CRDS).

Cavity Ring-Down Absorption Spectroscopy: Optical Characterization of ICl Product in Photodissociation of CH2ICl at 248 nm

2018 ◽  
Vol 122 (42) ◽  
pp. 8344-8353
Author(s):  
Denís Paredes-Roibás ◽  
Muthiah Balaganesh ◽  
Toshio Kasai ◽  
José María Gavira-Vallejo ◽  
King Chuen Lin
Keyword(s):  
Absorption Spectroscopy ◽  
Optical Characterization ◽  
Spectroscopy Optical ◽  
Cavity Ring Down

Characterization of an Effusive Rubidium Atomic Jet Source by Tunable Diode Laser Absorption Spectroscopy

2021 ◽  
Author(s):  
Hayden P. Morgan ◽  
William L. Hodges ◽  
Rohan D. Jillapalli ◽  
Christopher Limbach
Keyword(s):  
Diode Laser ◽  
Absorption Spectroscopy ◽  
Tunable Diode Laser ◽  
Laser Absorption Spectroscopy ◽  
Laser Absorption ◽  
Diode Laser Absorption

scholarly journals Synthesis and Polymerization Kinetics of Rigid Tricyanate Ester

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1686
Author(s):  
Andrey Galukhin ◽  
Roman Nosov ◽  
Ilya Nikolaev ◽  
Elena Melnikova ◽  
Daut Islamov ◽  
...  
Keyword(s):  
Kinetic Analysis ◽  
Single Step ◽  
Polymerization Kinetics ◽  
Scanning Calorimetry ◽  
Modulated Differential Scanning Calorimetry ◽  
Diffusion Controlled ◽  
Polymerization Product ◽  
The One ◽  
Kinetics Of

A new rigid tricyanate ester consisting of seven conjugated aromatic units is synthesized, and its structure is confirmed by X-ray analysis. This ester undergoes thermally stimulated polymerization in a liquid state. Conventional and temperature-modulated differential scanning calorimetry techniques are employed to study the polymerization kinetics. A transition of polymerization from a kinetic- to a diffusion-controlled regime is detected. Kinetic analysis is performed by combining isoconversional and model-based computations. It demonstrates that polymerization in the kinetically controlled regime of the present monomer can be described as a quasi-single-step, auto-catalytic, process. The diffusion contribution is parameterized by the Fournier model. Kinetic analysis is complemented by characterization of thermal properties of the corresponding polymerization product by means of thermogravimetric and thermomechanical analyses. Overall, the obtained experimental results are consistent with our hypothesis about the relation between the rigidity and functionality of the cyanate ester monomer, on the one hand, and its reactivity and glass transition temperature of the corresponding polymer, on the other hand.

scholarly journals Characterization of Temperature Distributions in a Swirled Oxy-fuel Coal Combustor using Tomographic Absorption Spectroscopy with Fluctuation Modelling

2021 ◽  
pp. 100025
Author(s):  
Johannes Emmert ◽  
Henrik Schneider ◽  
Christian Meißner ◽  
Evaggelos Sidiropoulos ◽  
Jonas I. Hölzer ◽  
...  
Keyword(s):  
Absorption Spectroscopy ◽  
Temperature Distributions

Probing BrCl from photodissociation of CH2BrCl and CHBr2Cl at 248 nm using cavity ring-down spectroscopy

2021 ◽  
Vol 23 (10) ◽  
pp. 6098-6106
Author(s):  
Balaganesh Muthiah ◽  
Toshio Kasai ◽  
King-Chuen Lin
Keyword(s):  
Absorption Spectroscopy ◽  
Cavity Ring Down Spectroscopy ◽  
Cavity Ringdown ◽  
Cavity Ring Down

Investigation of molecular halogens as a primary product from the photodissociation of CH2BrCl and CHBr2Cl at 248 nm using cavity ringdown absorption spectroscopy (CRDS).

scholarly journals Congruence pairs of principal MS-algebras and perfect extensions

2020 ◽  
Vol 70 (6) ◽  
pp. 1275-1288
Author(s):  
Abd El-Mohsen Badawy ◽  
Miroslav Haviar ◽  
Miroslav Ploščica
Keyword(s):  
Boolean Algebra ◽  
Congruence Lattices ◽  
Descriptive Solution ◽  
The One ◽  
Special Case ◽  
Congruence Pair

AbstractThe notion of a congruence pair for principal MS-algebras, simpler than the one given by Beazer for K2-algebras [6], is introduced. It is proved that the congruences of the principal MS-algebras L correspond to the MS-congruence pairs on simpler substructures L°° and D(L) of L that were associated to L in [4].An analogy of a well-known Grätzer’s problem [11: Problem 57] formulated for distributive p-algebras, which asks for a characterization of the congruence lattices in terms of the congruence pairs, is presented here for the principal MS-algebras (Problem 1). Unlike a recent solution to such a problem for the principal p-algebras in [2], it is demonstrated here on the class of principal MS-algebras, that a possible solution to the problem, though not very descriptive, can be simple and elegant.As a step to a more descriptive solution of Problem 1, a special case is then considered when a principal MS-algebra L is a perfect extension of its greatest Stone subalgebra LS. It is shown that this is exactly when de Morgan subalgebra L°° of L is a perfect extension of the Boolean algebra B(L). Two examples illustrating when this special case happens and when it does not are presented.

scholarly journals Insights into Mechanical Properties of the 1980 Irpinia Fault System from the Analysis of a Seismic Sequence

Geosciences ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 28
Author(s):  
Gaetano Festa ◽  
Guido Maria Adinolfi ◽  
Alessandro Caruso ◽  
Simona Colombelli ◽  
Grazia De Landro ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Early Warning Systems ◽  
Fault System ◽  
Minimum Size ◽  
Double Difference ◽  
Warning Systems ◽  
Initiation Mechanism ◽  
Earthquake Early Warning Systems ◽  
The One

Seismic sequences are a powerful tool to locally infer geometrical and mechanical properties of faults and fault systems. In this study, we provided detailed location and characterization of events of the 3–7 July 2020 Irpinia sequence (southern Italy) that occurred at the northern tip of the main segment that ruptured during the 1980 Irpinia earthquake. Using an autocorrelation technique, we detected more than 340 events within the sequence, with local magnitude ranging between −0.5 and 3.0. We thus provided double difference locations, source parameter estimation, and focal mechanisms determination for the largest quality events. We found that the sequence ruptured an asperity with a size of about 800 m, along a fault structure having a strike compatible with the one of the main segments of the 1980 Irpinia earthquake, and a dip of 50–55° at depth of 10.5–12 km and 60–65° at shallower depths (7.5–9 km). Low stress drop release (average of 0.64 MPa) indicates a fluid-driven initiation mechanism of the sequence. We also evaluated the performance of the earthquake early warning systems running in real-time during the sequence, retrieving a minimum size for the blind zone in the area of about 15 km.

scholarly journals Mineralogical and Geochemical Characterization of Gold Mining Tailings and Their Potential to Generate Acid Mine Drainage (Minas Gerais, Brazil)

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 39
Author(s):  
Mariana Lemos ◽  
Teresa Valente ◽  
Paula Marinho Reis ◽  
Rita Fonseca ◽  
Itamar Delbem ◽  
...  
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Minas Gerais ◽  
Acid Mine ◽  
Fine Grain ◽  
Mineralogical Characteristics ◽  
Tailing Dams ◽  
The One ◽  
And Control

For more than 30 years, sulfide gold ores were treated in metallurgic plants located in Nova Lima, Minas Gerais, Brazil, and accumulated in the Cocoruto tailings dam. Both flotation and leaching tailings from a deactivated circuit, as well as roasted and leaching tailings from an ongoing plant, were studied for their acid mine drainage potential and elements’ mobility. Detailed characterization of both tailings types indicates the presence of fine-grain size material hosting substantial amounts of sulfides that exhibit distinct geochemical and mineralogical characteristics. The samples from the ongoing plant show high grades of Fe in the form of oxides, cyanide, and sulfates. Differently, samples from the old circuit shave higher average concentrations of Al (0.88%), Ca (2.4%), Mg (0.96%), and Mn (0.17%), present as silicates and carbonates. These samples also show relics of preserved sulfides, such as pyrite and pyrrhotite. Concentrations of Zn, Cu, Au, and As are higher in the tailings of the ongoing circuit, while Cr and Hg stand out in the tailings of the deactivated circuit. Although the obtained results show that the sulfide wastes do not tend to generate acid mine drainage, leaching tests indicate the possibility of mobilization of toxic elements, namely As and Mn in the old circuit, and Sb, As, Fe, Ni, and Se in the tailings of the plant that still works. This work highlights the need for proper management and control of tailing dams even in alkaline drainage environments such as the one of the Cocoruto dam. Furthermore, strong knowledge of the tailings’ dynamics in terms of geochemistry and mineralogy would be pivotal to support long-term decisions on wastes management and disposal.

Preparation and characterization of tannin-based adhesives reinforced with cellulose nanofibrils for wood bonding

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Uasmim Lira Zidanes ◽  
Matheus Cordazzo Dias ◽  
Mário Sérgio Lorenço ◽  
Elesandra da Silva Araujo ◽  
Maryella Júnnia Ferreira e Silva ◽  
...  
Keyword(s):  
Cellulose Nanofibrils ◽  
Glue Line ◽  
Mechanical Resistance ◽  
Thermogravimetric Analyses ◽  
Humidity Resistance ◽  
Wood Bonding ◽  
Toona Ciliata ◽  
Solids Content ◽  
The One

AbstractAdhesives based on vegetable tannins are already a reality in the market. However, their use is still limited due to their low mechanical resistance and weak humidity resistance. Cellulose nanofibrils (CNFs) are being used as reinforcing materials in various composites, resulting in an improvement of mechanical proprieties in general. The objective of this work was to evaluate the incorporation of CNFs in adhesives made of tannins obtained from the Angico tree (Anadenanthera peregrine). Concentrations of nanofibrils at 1, 5, and 10% were added to the adhesives on a dry basis. Tests of viscosity, pH, solids content, and gel time were performed to determine the physical proprieties of the adhesives. The Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy (ATR-FTIR) and Raman spectra measurements were also determined to understand the interaction between tannins and CNFs. Thermogravimetric analyses (TGA) were carried out to determine the thermal resistance of the composite. The FTIR and Raman characterization identified some differences in the peaks in the chemical composition of the adhesives with different percentages of CNFs. The adhesives showed no different decomposition in the thermogravimetric analyses. The shear strength in the glue line of the adhesive with 5% of CNFs in Toona ciliata woods was determined. Among all the adhesives analyzed, the one with 5% of CNFs produced an improvement in the mechanical resistance and humidity resistance on the glue line.

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