Enantioselective adsorption in homochiral metal–organic frameworks: the pore size influence

2015 ◽  
Vol 51 (43) ◽  
pp. 8998-9001 ◽  
Author(s):  
Zhi-Gang Gu ◽  
Sylvain Grosjean ◽  
Stefan Bräse ◽  
Christof Wöll ◽  
Lars Heinke
Keyword(s):  
Thin Films ◽  
Pore Size ◽  
Metal Organic Frameworks ◽  
P Uptake ◽  
Stereogenic Centers ◽  
Enantioselective Adsorption ◽  
Metal Organic

Uptake experiments in thin films of isoreticular chiral MOFs of type Cu2(Dcam)2(L) with identical stereogenic centers but different pore dimensions show that the enantioselectivity is significantly influenced by the pore size.

Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders: Tuning the Pore Size for Enantioselective Adsorption

2015 ◽  
Vol 21 (28) ◽  
pp. 9964-9969 ◽  
Author(s):  
Kyriakos C. Stylianou ◽  
Laura Gómez ◽  
Inhar Imaz ◽  
Cristóbal Verdugo-Escamilla ◽  
Xavi Ribas ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Enantioselective Adsorption ◽  
Metal Organic

Frontispiece: Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders: Tuning the Pore Size for Enantioselective Adsorption

2015 ◽  
Vol 21 (28) ◽  
pp. n/a-n/a
Author(s):  
Kyriakos C. Stylianou ◽  
Laura Gómez ◽  
Inhar Imaz ◽  
Cristóbal Verdugo-Escamilla ◽  
Xavi Ribas ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Enantioselective Adsorption ◽  
Metal Organic

scholarly journals On the Use of MOFs and ALD Layers as Nanomembranes for the Enhancement of Gas Sensors Selectivity

Nanomaterials ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 1552 ◽  
Author(s):  
Weber ◽  
Graniel ◽  
Balme ◽  
Miele ◽  
Bechelany
Keyword(s):  
Thin Films ◽  
Gas Sensors ◽  
Gas Sensing ◽  
Metal Organic Frameworks ◽  
Atomic Layer ◽  
Operational Performance ◽  
Layer Deposition ◽  
Metal Organic ◽  
Further Development ◽  
Different Gases

Improving the selectivity of gas sensors is crucial for their further development. One effective route to enhance this key property of sensors is the use of selective nanomembrane materials. This work aims to present how metal-organic frameworks (MOFs) and thin films prepared by atomic layer deposition (ALD) can be applied as nanomembranes to separate different gases, and hence improve the selectivity of gas sensing devices. First, the fundamentals of the mechanisms and configuration of gas sensors will be given. A selected list of studies will then be presented to illustrate how MOFs and ALD materials can be implemented as nanomembranes and how they can be implemented to improve the operational performance of gas sensing devices. This review comprehensively shows the benefits of these novel selective nanomaterials and opens prospects for the sensing community.

scholarly journals Rational Design of Pore Size and Functionality in a Series of Isoreticular Zwitterionic Metal–Organic Frameworks

2018 ◽  
Vol 30 (22) ◽  
pp. 8332-8342 ◽  
Author(s):  
Darpandeep Aulakh ◽  
Timur Islamoglu ◽  
Veronica F. Bagundes ◽  
Juby R. Varghese ◽  
Kyle Duell ◽  
...  
Keyword(s):  
Pore Size ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Metal Organic

cis-to-trans isomerization of azobenzene investigated by using thin films of metal–organic frameworks

2015 ◽  
Vol 17 (35) ◽  
pp. 22721-22725 ◽  
Author(s):  
Xiaojuan Yu ◽  
Zhengbang Wang ◽  
Maria Buchholz ◽  
Nena Füllgrabe ◽  
Sylvain Grosjean ◽  
...  
Keyword(s):  
Thin Films ◽  
Metal Organic Frameworks ◽  
Model System ◽  
Trans Isomerization ◽  
System P ◽  
Metal Organic

The energetic barrier for the cis-to-trans isomerization of azobenzene was experimentally investigated by using thin films of azobenzene-containing MOFs as well-defined model system.

scholarly journals MOF thin films with bi-aromatic linkers grown by molecular layer deposition

2020 ◽  
Vol 8 (5) ◽  
pp. 2539-2548 ◽  
Author(s):  
Kristian Blindheim Lausund ◽  
Malin Solheim Olsen ◽  
Per-Anders Hansen ◽  
Håkon Valen ◽  
Ola Nilsen
Keyword(s):  
Thin Films ◽  
Molecular Layer ◽  
Metal Organic Frameworks ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Wide Range ◽  
Metal Organic ◽  
Sensor Materials

Thin films of metal–organic frameworks (MOFs) are promising for a wide range of applications including membranes for separations and sensor materials in microelectronics.

Pore Size Reduction in Zirconium Metal–Organic Frameworks for Ethylene/Ethane Separation

2019 ◽  
Vol 7 (7) ◽  
pp. 7118-7126 ◽  
Author(s):  
Yuxiang Wang ◽  
Shuai Yuan ◽  
Zhigang Hu ◽  
Tanay Kundu ◽  
Jian Zhang ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Size Reduction ◽  
Metal Organic ◽  
Zirconium Metal
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