Solvent-free synthesis of new magnesium phosphate–oxalates displaying diverse framework topologies

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9296-9299 ◽  
Author(s):  
Wei Zhang ◽  
Maoping Kang ◽  
Meng Yang ◽  
Daibing Luo ◽  
Zhien Lin
Keyword(s):  
Membered Ring ◽  
Solvent Free ◽  
Magnesium Phosphate ◽  
Open Framework ◽  
Solvent Free Conditions ◽  
First Time ◽  
Solvent Free Synthesis

A series of open-framework magnesium phosphate–oxalates with pore apertures ranging from an 8-membered ring (8 MR) to 20 MR were prepared for the first time under solvent-free conditions.

Solvent-free synthesis of new metal phosphite–oxalates with open-framework structures

2014 ◽  
Vol 43 (21) ◽  
pp. 7695-7698 ◽  
Author(s):  
Lin Liu ◽  
Daibing Luo ◽  
Defu Li ◽  
Zhien Lin
Keyword(s):  
Layered Structures ◽  
Solvent Free ◽  
Open Framework ◽  
Solvent Free Conditions ◽  
Solvent Free Synthesis

Two open-framework metal phosphite–oxalates with diamondoid and pillared-layered structures have been synthesized under solvent-free conditions.

scholarly journals Solvent-free synthesis of symmetric methylene diesters via direct reaction of aromatic carboxylates with 1,n-dihaloalkanes

RSC Advances ◽  
2021 ◽  
Vol 11 (46) ◽  
pp. 28711-28715
Author(s):  
Lin Bai ◽  
Shenglong Ding ◽  
Xiaofang Ma
Keyword(s):  
Solvent Free ◽  
Direct Reaction ◽  
Highly Efficient ◽  
Solvent Free Conditions ◽  
Aromatic Carboxylates ◽  
Solvent Free Synthesis

This work provides a highly efficient and feasible strategy for the synthesis of symmetric methylene diesters, involving the direct diesterification of various carboxylates with 1,n-dihaloalkanes under solvent-free conditions.

Solvent-free synthesis of novel vanillidene derivatives of Meldrum's acid: biological evaluation, DNA and BSA binding study

RSC Advances ◽  
2016 ◽  
Vol 6 (45) ◽  
pp. 39452-39459 ◽  
Author(s):  
Nenad Janković ◽  
Jovana Muškinja ◽  
Zoran Ratković ◽  
Zorica Bugarčić ◽  
Branislav Ranković ◽  
...  
Keyword(s):  
Biological Evaluation ◽  
Solvent Free ◽  
Binding Study ◽  
Meldrum's Acid ◽  
Meldrum’S Acid ◽  
Bsa Binding ◽  
Solvent Free Conditions ◽  
Derivatives Of ◽  
Solvent Free Synthesis

A series of novel O-alkyl vanillidene derivatives containing Meldrum's acid scaffold under solvent-free conditions were synthesized.

Solvent-free synthesis of pyrrolo [2,1-α]isoquinolines via one-pot four-component reaction

2021 ◽  
Vol 18 ◽  
Author(s):  
Ali Aminkhani ◽  
Sina Sharifi
Keyword(s):  
Cycloaddition Reaction ◽  
Aromatic Aldehydes ◽  
Solvent Free ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Solvent Free Synthesis

: An efficient four-component reaction to synthesize pyrrolo[2,1-a]isoquinolines from malononitrile, aromatic aldehydes, isoquinoline, and cyclohexyl isocyanide under solvent-free conditions is described. In a convenient, simple, and efficient one-pot procedure, the domino Knoevenagel-nucleophilic cycloaddition reaction affords excellent yields of products in less than 1 h.

Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives

2009 ◽  
Vol 63 (1) ◽  
Author(s):  
Viera Mazíková ◽  
Iva Sroková ◽  
Anna Ebringerová
Keyword(s):  
Fatty Acid ◽  
Methyl Esters ◽  
Solvent Free ◽  
Water Soluble ◽  
Polymeric Surfactants ◽  
Acid Complex ◽  
Carboxymethyl Starch ◽  
Solvent Free Conditions ◽  
Structural Surface ◽  
Solvent Free Synthesis

AbstractWater-soluble, partially hydrophobized polysaccharides have become attractive due to their potential to act as polymeric surfactants. From carboxymethyl starch (CMS), water-soluble polymeric surfactants were prepared by esterification using two unconvential methods based on (A) a reaction with mixed anhydrides and (B) with methyl laureate (MELA) and methyl esters of the fatty acid complex of rape seed oil (MERO) under ‘solvent-free’ conditions. The obtained CMS derivatives were characterized by structural, surface-active and surfactant performance properties. Esterification using method B was successful in contrast to method A which yielded derivatives with a very low extent of esterification. Although the derivatives reduced the surface tension moderately, they exhibited remarkable emulsifying properties. The performance tests indicated good washing power and antiredeposition efficiency. The results suggest that suitable polymeric surfactants can be prepared by the unconventional esterification method B using both acylation agents. The preparations might substitute the expensive and invasive industrially applied conventional methods.

Seed-assisted, solvent-free synthesis of a CHA-type aluminophosphate molecular sieve

RSC Advances ◽  
2015 ◽  
Vol 5 (116) ◽  
pp. 95690-95694 ◽  
Author(s):  
Xinhong Zhao ◽  
Jiangbo Zhao ◽  
Xiangping Gao ◽  
Yu Zhao
Keyword(s):  
Molecular Sieve ◽  
Solvent Free ◽  
Solvent Free Conditions ◽  
Solvent Free Synthesis

Triclinic AlPO4-34 with CHA topology has been successfully synthesized under seed-assisted, solvent-free conditions.

Rapid mechanochemical synthesis of metal–organic frameworks using exogenous organic base

2020 ◽  
Vol 49 (45) ◽  
pp. 16238-16244 ◽  
Author(s):  
Zihao Wang ◽  
Zongzhe Li ◽  
Marcus Ng ◽  
Phillip J. Milner
Keyword(s):  
Mechanochemical Synthesis ◽  
Metal Organic Frameworks ◽  
Solvent Free ◽  
Organic Base ◽  
Metal Organic ◽  
First Time ◽  
Solvent Free Synthesis

We describe the mechanochemical, solvent-free synthesis of metal–organic frameworks using liquid organic base for the first time.

Highly Chemoselective Solvent-Free Synthesis of 1,3,5-Triaryl-1,5-diketones: Crystallographic Investigation and Intramolecular Weak Bifurcated H Bonds Involving Aliphatic C–H Group

Synlett ◽  
2019 ◽  
Vol 30 (19) ◽  
pp. 2143-2147
Author(s):  
Zhongyou Yin ◽  
Changkun Xiong ◽  
Jianxin Guo ◽  
Xiaoyun Hu ◽  
Zixing Shan ◽  
...  
Keyword(s):  
Solid State ◽  
Decisive Role ◽  
Solvent Free ◽  
Dihedral Angles ◽  
Crystallographic Investigation ◽  
Structural Arrangement ◽  
Bond Lengths ◽  
Solvent Free Conditions ◽  
Solvent Free Synthesis

Several 1,3,5-triaryl-1,5-diketones have been chemoselectively synthesized under solvent-free conditions. It was found that intramolecular weak bifurcated H-bonds interaction of aliphatic C–H group plays a decisive role in the structural arrangement of 3-(2,6-dichlorophenyl)-1,5-diphenylpentane-1,5-dione in a solid state resulting in significant impact on the corresponding bond lengths and dihedral angles.

A One-Pot, Three-Component, Solvent-Free Synthesis of Novel 6H-Chromeno[3’,4’:5,6]Pyrido[2,3-d]Pyrimidine-Triones under Microwave Irradiation

2018 ◽  
Vol 42 (12) ◽  
pp. 604-607
Author(s):  
Loghman Firoozpour ◽  
Hoda Yahyavi ◽  
Ramona Ejtemaei ◽  
Setareh Moghimi ◽  
Alireza Foroumadi
Keyword(s):  
Microwave Irradiation ◽  
Efficient Method ◽  
Barbituric Acid ◽  
Reaction Times ◽  
Solvent Free ◽  
One Pot ◽  
Solvent Free Conditions ◽  
Substituted Benzaldehydes ◽  
High Yields ◽  
Solvent Free Synthesis

A green and efficient method for preparing novel heterocyclic systems is established through the reaction of differently substituted benzaldehydes, barbituric acid and 4-amino-2H-chromene-2-one under solvent-free conditions. This method affords 6H-chromeno[3’,4’:5,6] pyrido[2,3-d]pyrimidine-trione derivatives in high yields and short reaction times.

A solvent-free protocol for the green synthesis of arylalkylidene rhodanines in a task-specific ionic liquid

2010 ◽  
Vol 88 (6) ◽  
pp. 514-518 ◽  
Author(s):  
Abdolhamid Alizadeh ◽  
Mohammad M. Khodaei ◽  
Ali Eshghi
Keyword(s):  
Ionic Liquid ◽  
Green Synthesis ◽  
Carbonyl Compounds ◽  
Catalytic Effect ◽  
Knoevenagel Condensation ◽  
Solvent Free ◽  
Detailed Mechanism ◽  
Solvent Free Conditions ◽  
First Time ◽  
Task Specific Ionic Liquid

2-Hydroxyethylammonium formate acts as a task-specific ionic liquid (TSIL) for the Knoevenagel condensation of carbonyl compounds with rhodanine to afford arylalkylidene rhodanines under solvent-free conditions and in good-to-excellent yields. Additionally, compared with those in organic solvents, the yields obtained in the presence of our ionic liquid (IL) were significantly increased. The detailed mechanism of the catalytic effect of TSIL is also reported for the first time.

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