A review of upgrading heavy oils with supercritical fluids

RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75129-75140 ◽  
Author(s):  
Ting Yan ◽  
Jie Xu ◽  
Litao Wang ◽  
Yindong Liu ◽  
Chun Yang ◽  
...  

Due to the decrease in light crude oil and the ever-increasing demand for the upgrading of heavy oils, the development of new heavy oil processing technology has been attracting wide attention.

2018 ◽  
Vol 177 ◽  
pp. 309-327 ◽  
Author(s):  
Rajeev Kumar ◽  
Ravi Kumar Voolapalli ◽  
Sreedevi Upadhyayula

Author(s):  
Darya I. Chuikina ◽  
Tatiana V. Petrenko ◽  
Larisa D. Stakhina

The paper deals with a sol-forming system for oil recovery enhancement (EOR system) used to increase the rate of heavy oil displacement. The effect of sol-forming EOR system during the heavy oil displacement on the composition and stability of oil sampled from the Usinskoye oil field of Russia is investigated. The composition of a crude oil also plays an important role in changing its stability. The work is aimed to investigate stability of heavy crude oil in regards to asphaltene precipitation. For asphaltene toluene/n-heptane solutions, the aggregation stability of asphaltenes based on сhange in the optical density with time is investigated via spectrophotometry. SARA analysis is used to characterize the compositions of heavy oils. First, the content of asphaltenes precipitated from the oil samples is determined and then the samples of deasphalted crude oil (maltenes) are analyzed by the method of liquid adsorption chromatography for the purpose to study the composition of oil sampled from the wells before and after their treatment with the sol-forming EOR system. It is found out that the treatment of reservoir crude oil with the sol-forming EOR system results in changes in composition of saturated, aromatic hydrocarbons, resins, and asphaltenes (SARA components) and aggregative stability of produced oil. The results obtained showed that the aggregative stability of heavy oil depends not only on the content of SARA components in the dispersion medium but on the presence of metalloporphyrins in the oil. Metalloporphyrins could act as inhibitors of asphaltene precipitation, which is an additional factor responsible for the stabilization of the oil dispersed system


2015 ◽  
Vol 670 ◽  
pp. 39-43 ◽  
Author(s):  
Larisa D. Stakhina ◽  
Danil S. Petrenko ◽  
Adina S. Spabekova

The effect of EOR technologies on the contents of petroporphyrins and naphthenic acids in recovered crude oil was studied using heavy oil from Usinskoye oil field (Republic Komi), which has high density, high content nickel and vanadium porphyrin complexes, the oxygen compounds and naphthenic acids. It is found that EOR system in combination with thermal steam treatment injection brings about an increase in the content of vanadium porphyrin complexes of crude oils. As a result of the oil-displacement EOR system injection, the naphthenic acids content would decrease in heavy oils.


Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3557
Author(s):  
Athina Mandalenaki ◽  
Nicolas Kalogerakis ◽  
Eleftheria Antoniou

Typically, oil pollution cleanup procedures following first response actions include dispersion. Crude oil is biodegradable, and its bioavailability can be increased when dispersed into very fine droplets by means of chemical surfactants. Although their use is widely spread in many applications, the latter may prove toxic, depending on the extent of use. The use of biological means, such as bioremediation and biosurfactants, has emerged over the past years as a very promising ‘green’ alternative technology. Biosurfactants (BSs) are amphiphilic molecules produced by microorganisms during biodegradation, thus increasing the bioavailability of the organic pollutants. It is their biodegradability and low toxicity that render BSs as a very promising alternative to the synthetic ones. Alcanivorax borkumensis SK2 strain ability to produce BSs, without any impurities from the substrate, was investigated. The biosurfactant production was scaled up by means of a sequencing batch reactor (SBR) and a heavy oil residue substrate as the carbon source. The product is free from substrate impurities, and its efficiency is tested on oil bioremediation in the marine environment. The product’s dispersion efficiency was determined by the baffled flask test. The production method proposed can have a significant impact to the market, given the ever-increasing demand for ecologically friendly, reliable, commercially viable and economically competitive environmental cleanup techniques.


2017 ◽  
Vol 31 (11) ◽  
pp. 12677-12684 ◽  
Author(s):  
Abdulhafiz Usman ◽  
Abdullah Aitani ◽  
Sulaiman Al-Khattaf

2021 ◽  
Author(s):  
Ningchen Fu ◽  
Zicheng Lai ◽  
Yuping Zhang ◽  
Yan Ma

The octane number is one of the important indicators in crude oil processing, and it is related to the anti-knock performance of gasoline engines. The loss of octane number in...


1991 ◽  
Vol 46 (2) ◽  
pp. 61-68 ◽  
Author(s):  
M.M. Ramirez de Agudelo ◽  
C. Galarraga

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