Hierarchical porous carbon nanofibrous membranes with an enhanced shape memory property for effective adsorption of proteins

RSC Advances ◽  
2015 ◽  
Vol 5 (79) ◽  
pp. 64318-64325 ◽  
Author(s):  
Gang Fan ◽  
Jianlong Ge ◽  
Hak-Yong Kim ◽  
Bin Ding ◽  
Salem S. Al-Deyab ◽  
...  

A hierarchical porous CNF membrane with robust mechanical properties, exhibiting intriguing shape memory properties and efficient protein adsorption performance.

2018 ◽  
Vol 51 (7-8) ◽  
pp. 626-643
Author(s):  
Chengliang Li ◽  
Xingxing Ji ◽  
Yang Lyu ◽  
Xinyan Shi

In this work, a damping material was successfully prepared by blending acrylic rubber (ACM) and polylactide (PLA) with sulfur and soap salt as the curing agents. A phenol-formaldehyde (PF) resin was used as a modifier. The effects of PF on the mechanical properties, damping properties, compatibility and shape memory properties of the blends were studied. The compatibility and damping properties were characterized by dynamic mechanical analysis, Fourier transform infrared spectroscope and microstructure analysis. The shape memory properties were examined by thermal mechanical analyser. The results revealed that the tensile strength of the blends was decreased and the toughness was increased with the increase of PF loadings. The introduction of PF improved the compatibility between PLA and ACM, which was deduced from the fact that the glass transition temperature of ACM was increased and the two loss factor peaks became closer. It was also found that the loss factor peak became higher and the effective damping temperature range became wider due to the formation of hydrogen bonding, implying that the damping properties of ACM/PLA blends were significantly improved. The ACM/PLA blends exhibited good dual-shape memory effect and its shape recovery ratio was increased by introduction of PF and raising the trigger temperature. The blends also exhibited good triple-shape memory property, which was dramatically improved by the introduction of PF. The mechanisms for the enhanced shape memory effects were then analysed.


2021 ◽  
Vol 33 (1) ◽  
Author(s):  
Jiaxin Li ◽  
Rudolf Holze ◽  
Simbarashe Moyo ◽  
Song Wang ◽  
Sanxi Li ◽  
...  

Abstract Background Dealing with the ever-increasing water pollution has become an urgent global problem, especially the organic containing polluted water. Physical adsorption has become one of the most popular ways for removal of organic dyes from wastewater due to its low cost as well as high efficiency. However, the adsorption performance is still limited by the low specific surface area (SSA) and unsuitable pore size. Hence, it is still a challenge to synthesize active carbon (AC) with high SSA, suitable pore size distribution as well as low cost for polluted water treatment. Here, we report an efficient method to prepare AC with large SSA from jujube for removal of both cationic dye and anionic dye from aqueous solution. The present results demonstrate that biomass-derived hierarchical porous carbon has a real potential application for wastewater treatment. Results The as-prepared hierarchical porous structure carbon material (PC-500-6) shows a high specific surface area (3203 m2/g) and pore size distribution in the range 0.8 to 3.0 nm, while exhibiting an enhanced adsorption performance for both methylene blue (MB) and methylene orange (MO) from an aqueous solution. The maximum adsorption capacity even reaches 925.93 mg/g and 1281.39 mg/g for MB and MO, which was calculated from Langmuir model. Through analysis of the adsorption data, it was found that the corresponding adsorption kinetic fits the pseudo-second-order model very well. Conclusions It can be concluded that the adsorption of MB has a strong correlation with SSA, pore size distribution as well as the pore volume. The present study paved a practical way for wastewater treatment by using biomass-derived hierarchical porous carbon.


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