Evolution from small sized Au nanoparticles to hollow Pt/Au nanostructures with Pt nanorods and a mechanistic study

RSC Advances ◽  
2015 ◽  
Vol 5 (126) ◽  
pp. 103797-103802 ◽  
Author(s):  
Ying Ma ◽  
Li Xu ◽  
Wei Chen ◽  
Chao Zou ◽  
Yun Yang ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Mechanistic Study ◽  
Growth Modifier

A facile method for synthesizing hollow Au/Pt nanostructures is reported; this strategy involves using small sized Au nanoparticles (NPs) as seeds and KI as growth modifier.

Mechanistic Study of Hydrogen-Driven Deoxydehydration over Ceria-Supported Rhenium Catalyst Promoted by Au Nanoparticles

ACS Catalysis ◽  
2017 ◽  
Vol 8 (1) ◽  
pp. 584-595 ◽  
Author(s):  
Yoshinao Nakagawa ◽  
Shuhei Tazawa ◽  
Tianmiao Wang ◽  
Masazumi Tamura ◽  
Norihito Hiyoshi ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Mechanistic Study

Mechanistic Study of a Place-Exchange Reaction of Au Nanoparticles with Spin-Labeled Disulfides

Langmuir ◽  
2004 ◽  
Vol 20 (26) ◽  
pp. 11536-11544 ◽  
Author(s):  
Petre Ionita ◽  
Agneta Caragheorgheopol ◽  
Bruce C. Gilbert ◽  
Victor Chechik
Keyword(s):  
Exchange Reaction ◽  
Au Nanoparticles ◽  
Mechanistic Study ◽  
Place Exchange

Mechanistic Study of C‒H Bond Activation by O2 on Negatively Charged Au Clusters: α,β-Dehydrogenation of 1-Methyl-4-piperidone by Supported Au Catalysts

2021 ◽  
Author(s):  
Ray Miyazaki ◽  
Xiongjie Jin ◽  
Daichi Yoshii ◽  
Takafumi Yatabe ◽  
Tomohiro Yabe ◽  
...  
Keyword(s):  
Manganese Oxide ◽  
Molecular Sieve ◽  
Au Nanoparticles ◽  
Bond Activation ◽  
Mechanistic Study ◽  
Au Clusters

Au nanoparticles supported on manganese oxide octahedral molecular sieve (OMS-2) can efficiently catalyze α,β-dehydrogenation of β-N-substituted saturated ketones using O2 as the terminal oxidant. However, despite the utility of this...

Mechanistic study of proliferation induced by Angelica sinensis in gastric epithelial cells

2001 ◽  
Vol 120 (5) ◽  
pp. A145-A145
Author(s):  
C CHO ◽  
Y YE ◽  
E LIU ◽  
V SHIN ◽  
N SHAM
Keyword(s):  
Epithelial Cells ◽  
Mechanistic Study ◽  
Angelica Sinensis ◽  
Gastric Epithelial Cells

Mechanistic study on the cardioprotective and chemosensitizing effects of a novel danshensu derivative

Planta Medica ◽  
2014 ◽  
Vol 80 (16) ◽  
Author(s):  
L Wang ◽  
L Shan ◽  
G Cui ◽  
Y Chen ◽  
J li ◽  
...  
Keyword(s):  
Mechanistic Study

Machine Learning Accelerated Genetic Algorithms for Computational Materials Search

2018 ◽  
Author(s):  
Steen Lysgaard ◽  
Paul C. Jennings ◽  
Jens Strabo Hummelshøj ◽  
Thomas Bligaard ◽  
Tejs Vegge
Keyword(s):  
Machine Learning ◽  
Genetic Algorithm ◽  
Genetic Algorithms ◽  
Au Nanoparticles ◽  
Learning Model ◽  
Energy Calculations ◽  
Atomic Distribution ◽  
Machine Learning Model ◽  
Fold Reduction ◽  
Computational Materials

A machine learning model is used as a surrogate fitness evaluator in a genetic algorithm (GA) optimization of the atomic distribution of Pt-Au nanoparticles. The machine learning accelerated genetic algorithm (MLaGA) yields a 50-fold reduction of required energy calculations compared to a traditional GA.

Mechanistic Study and Development of Catalytic Reactions of Sm(II)

2018 ◽  
Author(s):  
Sandepan Maity ◽  
Robert Flowers
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Proton Donor ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Mechanistic Studies ◽  
Cyclization Reactions ◽  
Mechanistic Approach ◽  
Donor Source

Despite the broad utility and application of SmI<sub>2</sub>in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivalents of electrons. We report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magnesium reductant and trimethyl silyl chloride in concert with a non-coordinating proton donor source. Reactions using this approach permitted reductions with as little as 1 mol% Sm. The mechanistic approach enabled catalysis employing HMPA as a ligand, facilitating the development of catalytic Sm(II) 5-<i>exo</i>-<i>trig </i>ketyl olefin cyclization reactions.

Activated carbon from molasses efficiency for Cr(VI), Pb(II) and Cu(II) adsorption: A mechanistic study

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Activated Carbon ◽  
Phosphoric Acid ◽  
Sugar Industry ◽  
Chemical Activation ◽  
High Surface ◽  
High Surface Area ◽  
Mechanistic Study ◽  
Acid Mixture ◽  
Maximum Adsorption Capacity ◽  
Good Potential

Activated carbon was prepared from molasses, which are natural precursors of vegetable origin resulting from the sugar industry. A simple elaboration process, based on chemical activation with phosphoric acid, was proposed. The final product, prepared by activation of molasses/phosphoric acid mixture in air at 500°C, presented high surface area (more than 1400 m2/g) and important maximum adsorption capacity for methylene blue (625 mg/g) and iodine (1660 mg/g). The activated carbon (MP2(500)) showed a good potential for the adsorption of Cr(VI), Cu(II) and Pb(II) from aqueous solutions. The affinity for the three ions was observed in the following order Cu2+ Cr6+ Pb2+. The process is governed by monolayer adsorption following the Langmuir model, with a correlation coefficient close to unity.

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