scholarly journals Exploration of the phase diagram of liquid water in the low-temperature metastable region using synthetic fluid inclusions

2016 ◽  
Vol 18 (40) ◽  
pp. 28227-28241 ◽  
Author(s):  
C. Qiu ◽  
Y. Krüger ◽  
M. Wilke ◽  
D. Marti ◽  
J. Rička ◽  
...  
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Low Temperature ◽  
Fluid Inclusions ◽  
Liquid Water ◽  
Theoretical Models ◽  
Metastable Region ◽  
Synthetic Fluid Inclusions

The paper presents experimental data of the low-temperature metastable region of liquid water to evaluate and improve theoretical models describing the p–V–T properties of water.

TEMPERATURE DEPENDENCE BEHAVIOR OF ELECTRICAL RESISTIVITY IN NOBLE METALS AT LOW TEMPERATURES

2014 ◽  
Vol 5 (3) ◽  
pp. 982-992 ◽  
Author(s):  
M AL-Jalali
Keyword(s):  
Experimental Data ◽  
Electrical Resistivity ◽  
Temperature Dependence ◽  
Concentration Dependence ◽  
Low Temperatures ◽  
Noble Metals ◽  
Phonon Scattering ◽  
Theoretical Models ◽  
Residual Resistivity ◽  
Electron Phonon Scattering

Resistivity temperature – dependence and residual resistivity concentration-dependence in pure noble metals(Cu, Ag, Au) have been studied at low temperatures. Dominations of electron – dislocation and impurity, electron-electron, and electron-phonon scattering were analyzed, contribution of these mechanisms to resistivity were discussed, taking into consideration existing theoretical models and available experimental data, where some new results and ideas were investigated.

Simple theoretical models of elimination reactions on polar catalysts; Dehydration reactivity of secondary alcohols on acidic and basic catalysts

1985 ◽  
Vol 50 (4) ◽  
pp. 920-929 ◽  
Author(s):  
Jiří Sedláček
Keyword(s):  
Experimental Data ◽  
Quantum Chemical ◽  
Theoretical Models ◽  
Aliphatic Alcohols ◽  
Secondary Alcohols ◽  
Carbonium Ion ◽  
Dehydration Reactions ◽  
Aromatic Alcohols ◽  
Basic Catalysts ◽  
Simple Models

CNDO/2 calculations for simple models of adsorption and dehydration reactions of secondary aliphatic and aromatic alcohols on polar catalysts are presented. The models involve selected stages of elimination mechanisms of various types (E1, E2 and E1cB elimination). Calculated quantum chemical quantities were correlated with reported experimental data. It is shown that reactivities for the series of substituted phenylethanols correlate very well with the ease of carbonium ion formation. In the case of aliphatic alcohols, calculated quantities correlate generally with the reactivities on SiO2 and are in anticorrelation with the reactivities on Al2O3.NaOH.

Seeking the Good Fitting Procedure of PALS Polymer Spectra

2008 ◽  
Vol 607 ◽  
pp. 64-66
Author(s):  
Nicolas Laforest ◽  
Jérémie De Baerdemaeker ◽  
Corine Bas ◽  
Charles Dauwe
Keyword(s):  
Experimental Data ◽  
Low Temperature ◽  
Positron Annihilation ◽  
Physical Meaning ◽  
Lifetime Measurements ◽  
Positron Annihilation Lifetime ◽  
Fitting Procedure ◽  
Fitting Procedures ◽  
Blob Model

Positron annihilation lifetime measurements on polymethylmethacrylate (PMMA) at low temperature were performed. Different discrete fitting procedures have been used to analyze the experimental data. It shows that the extracted parameters depend strongly on the fitting procedure. The physical meaning of the results is discussed. The blob model seems to give the best annihilation parameters.

scholarly journals Low-temperature thermal hydrolysis of sludge prior to anaerobic digestion: principal component analysis (PCA) of experimental data

Data in Brief ◽  
2021 ◽  
pp. 107323
Author(s):  
Mohamed N.A. Meshref ◽  
Seyed Mohammad Mirsoleimani Azizi ◽  
Wafa Dastyar ◽  
Rasha Maal-Bared ◽  
Bipro Ranjan Dhar
Keyword(s):  
Experimental Data ◽  
Principal Component Analysis ◽  
Anaerobic Digestion ◽  
Low Temperature ◽  
Principal Component ◽  
Component Analysis ◽  
Thermal Hydrolysis ◽  
Hydrolysis Of

scholarly journals Measurement of the sound velocity of shock compressed water

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Hua Shu ◽  
Jiangtao Li ◽  
Yucheng Tu ◽  
Junjian Ye ◽  
Junyue Wang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Molecular Dynamics ◽  
Equation Of State ◽  
Liquid Water ◽  
Diamond Anvil Cell ◽  
Quantum Molecular Dynamics ◽  
Laser Shock ◽  
Diamond Anvil ◽  
Ionization Processes ◽  
Sound Velocities

AbstractThe sound velocities of water in the Hugoniot states are investigated by laser shock compression of precompressed water in a diamond anvil cell. The obtained sound velocities in the off-Hugoniot region of liquid water at precompressed conditions are used to test the predictions of quantum molecular dynamics (QMD) simulations and the SESAME equation-of-state (EOS) library. It is found that the prediction of QMD simulations agrees with the experimental data while the prediction of SESAME EOS library underestimates the sound velocities probably due to its improper accounting for the ionization processes.

Modeling and Experimental Validation of the Effective Bulk Modulus of a Mixture of Hydraulic Oil and Air

2014 ◽  
Vol 136 (5) ◽  
Author(s):  
Hossein Gholizadeh ◽  
Doug Bitner ◽  
Richard Burton ◽  
Greg Schoenau
Keyword(s):  
Experimental Data ◽  
Bulk Modulus ◽  
Theoretical Models ◽  
Operating Conditions ◽  
Air Bubbles ◽  
Pressure Sensitivity ◽  
Hydraulic Oil ◽  
Effective Bulk Modulus ◽  
Experimental Apparatus ◽  
Major Factors

It is well known that the presence of entrained air bubbles in hydraulic oil can significantly reduce the effective bulk modulus of hydraulic oil. The effective bulk modulus of a mixture of oil and air as pressure changes is considerably different than when the oil and air are not mixed. Theoretical models have been proposed in the literature to simulate the pressure sensitivity of the effective bulk modulus of this mixture. However, limited amounts of experimental data are available to prove the validity of the models under various operating conditions. The major factors that affect pressure sensitivity of the effective bulk modulus of the mixture are the amount of air bubbles, their size and the distribution, and rate of compression of the mixture. An experimental apparatus was designed to investigate the effect of these variables on the effective bulk modulus of the mixture. The experimental results were compared with existing theoretical models, and it was found that the theoretical models only matched the experimental data under specific conditions. The purpose of this paper is to specify the conditions in which the current theoretical models can be used to represent the real behavior of the pressure sensitivity of the effective bulk modulus of the mixture. Additionally, a new theoretical model is proposed for situations where the current models fail to truly represent the experimental data.

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