Triazole linked ruthenium(ii)–porphyrin: influence of the connectivity pattern on photophysical and electrochemical properties
Keyword(s):
Band Gap
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A family of inverse and regular triazolyl–pyridyl porphyrin–ruthenium(ii) conjugates display an energy transfer from porphyrin to the ruthenium bipyridyl moiety and a narrow HOMO/LUMO energy band gap is responsible for enhanced electronic coupling.