Near-infrared Ag2Se quantum dots with distinct absorption features and high fluorescence quantum yields

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 38183-38186 ◽  
Author(s):  
Li-Juan Shi ◽  
Chun-Nan Zhu ◽  
He He ◽  
Dong-Liang Zhu ◽  
Zhi-Ling Zhang ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Near Infrared ◽  
Quantum Yields ◽  
Extinction Coefficients ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence ◽  
Absorption Features ◽  
Molar Extinction Coefficients

Near-infrared Ag2Se QDs with distinct absorption features ranging between 830–954 nm and fluorescence quantum yields up to 23.4% were controllably synthesized, and the molar extinction coefficients of the Ag2Se QDs were determined.

The Synthesis, Characterisation, Photophysical and Thermal Properties, and Photovoltaic Performance of 7-Coumarinoxy-4-Methyltetrasubstituted Metallophthalocyanines

2015 ◽  
Vol 68 (7) ◽  
pp. 1025 ◽  
Author(s):  
Jun-Jie Guo ◽  
Shi-Rong Wang ◽  
Xiang-Gao Li ◽  
Fei Zhang ◽  
Yin Xiao ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Transition Metal Complexes ◽  
Photovoltaic Performance ◽  
Quantum Yields ◽  
Stability Studies ◽  
Time Resolved ◽  
Extinction Coefficients ◽  
Fluorescence Quantum Yields ◽  
Photoluminescence Decay ◽  
Molar Extinction Coefficients

The synthesis, characterisation, photophysical and thermal properties of 2(3),9(10),16(17),23(24)-tetrakis(7-coumarinoxy-4-methyl)-phthalocyaninatozinc(ii) (ZnPc-Coumarin) and 2(3),9(10),16(17),23(24)-tetrakis(7-coumarinoxy-4-methyl)-phthalocyaninatocobalt(ii) (CoPc-Coumarin) are reported. The ground state absorbance of ZnPc-Coumarin shows molar extinction coefficients as high as 1.80 × 105 dm3 mol–1 cm–1. The fluorescence spectrum and fluorescence quantum yields of compounds ZnPc-Coumarin and CoPc-Coumarin are also investigated. The photoluminescence decay of the two transition-metal complexes in DMF solution, in poly(methyl methacrylate) (PMMA), and on TiO2 films has been studied with time-resolved emission. This study shows that the electron transfer from the dye to TiO2 is through space. The thermal stability studies indicate that both of the two complexes are stable up to 390°C. The ZnPc-Coumarin achieved a higher overall conversion efficiency than the reported SnPcCl2-Coumarin, InPcCl-Coumarin, and RuPcCl-Coumarin because of its slower charge recombination rate and faster electron injection from the dye to the conduction band of the conducting glass.

High-Quality Water-Soluble Core/Shell/Shell CdSe/CdS/ZnS Quantum Dots Balanced by Ionic and Nonionic Hydrophilic Capping Ligands

NANO ◽  
2016 ◽  
Vol 11 (07) ◽  
pp. 1650073 ◽  
Author(s):  
Lu Liu ◽  
Hu Xu ◽  
Bing Shen ◽  
Xinhua Zhong
Keyword(s):  
Quantum Dots ◽  
Colloidal Stability ◽  
Water Soluble ◽  
Quantum Yields ◽  
Surface Charges ◽  
Fluorescence Quantum Yields ◽  
Carboxylic Groups ◽  
Potential Applications ◽  
High Fluorescence ◽  
Capping Ligands

Pentaerythritol tetrakis 3-mercaptopropionate (PTMP) grafted poly(acryl acid) (PAA) ionic hydrophilic oligomer PAA-PTMP (PP) and dihydrolipoic acid (DHLA) grafted methoxypoly(ethylene glycol) (mPEG) nonionic hydrophilic oligomer mPEG-DHLA (PD) have been designed, synthesized and used as co-capping ligands in water-solubilization of hydrophobic quantum dots (QDs) via ligand exchange. The obtained oligomers with multi-thiol groups could bind strongly to the surface atoms of QDs. Meanwhile, the carboxyl groups (from PP) and mPEG segment (from PD) can render QDs water-soluble, and the free carboxylic groups can possibly be used for the further bioconjugation. The resulting water-soluble QDs have been characterized by ultraviolet-visible (UV-Vis), fluorescence, Fourier transform infrared (FTIR) spectroscopy as well as transmission electron microscopy (TEM) and dynamic light scattering (DLS) techniques. The water-soluble QDs have relatively small hydrodynamic size (10[Formula: see text]12 nm), and importantly, retain high fluorescence quantum yields (up to 45%) compared with that of the originally hydrophobic QDs (49%). In addition, they have tunable surface charges and show excellent colloidal stability over a relatively broad pH range ([Formula: see text]), in high salt concentration, and even after thermal treatment at 100[Formula: see text]C. These results indicate that the water-soluble QDs coated by PP and PD oligomers have potential applications in cellular imaging and biosensor.

Stable CsPbBr3 perovskite quantum dots with high fluorescence quantum yields

2018 ◽  
Vol 42 (12) ◽  
pp. 9496-9500 ◽  
Author(s):  
Min Zhang ◽  
Zhi-Quan Tian ◽  
Dong-Liang Zhu ◽  
He He ◽  
San-Wei Guo ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
Perovskite Quantum Dots ◽  
High Fluorescence ◽  
The Stability

After replacing oleylamine with (3-aminopropyl)triethoxysilane, the stability of the as-prepared CsPbBr3 QDs was significantly improved.

Regioselective Oxidative Cross-Coupling Reaction: Synthesis of Imidazo[1,2-a]pyridine Fluorophores

Synthesis ◽  
2021 ◽  
Author(s):  
Xianglong Chu ◽  
Yadi Niu ◽  
Chen Ma ◽  
Xiaodong Wang ◽  
Yunliang Lin ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
Cross Coupling Reaction ◽  
Color Tunable ◽  
Palladium Catalyzed ◽  
Structure Relationship ◽  
High Fluorescence

AbstractA rapid access to a series of N-heteroarene fluorophores has been developed on the basis of the palladium-catalyzed direct oxidative C–H/C–H coupling of imidazo[1,2-a]pyridines with thiophenes/furans. The photophysical properties–structure relationship was systematically investigated. The resulting N-heteroarene fluorophores present color-tunable emissions (λem: 431–507 nm in CH2Cl2) and high fluorescence quantum yields (up to 91% in CH2Cl2).

Chlorination vs. fluorination: a study of halogenated benzo[c][1,2,5]thiadiazole-based organic semiconducting dots for near-infrared cellular imaging

2020 ◽  
Vol 44 (19) ◽  
pp. 7740-7748
Author(s):  
Daize Mo ◽  
Li Lin ◽  
Pengjie Chao ◽  
Hanjian Lai ◽  
Qingwen Zhang ◽  
...  
Keyword(s):  
Near Infrared ◽  
Cellular Imaging ◽  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
Stokes Shifts

The chlorinated dots based on chlorinated benzo[c][1,2,5]thiadiazole unit possess higher fluorescence quantum yields, larger Stokes shifts, and better photostability than the fluorinated dots.

scholarly journals Photoluminescence in m-carborane–anthracene triads: a combined experimental and computational study

2018 ◽  
Vol 6 (42) ◽  
pp. 11336-11347 ◽  
Author(s):  
Mahdi Chaari ◽  
Zsolt Kelemen ◽  
José Giner Planas ◽  
Francesc Teixidor ◽  
Duane Choquesillo-Lazarte ◽  
...  
Keyword(s):  
Computational Study ◽  
Fluorescence Emission ◽  
Fluorescence Properties ◽  
Quantum Yields ◽  
Aggregate State ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence

m-Carborane has demonstrated to be a perfect platform to boost the fluorescence properties of anthracene, giving rise to high fluorescence quantum yields in solution and also retaining fluorescence emission in the aggregate state.

Alkynylpyrenes as Improved Pyrene-Based Biomolecular Probes with the Advantages of High Fluorescence Quantum Yields and Long Absorption/Emission Wavelengths

2006 ◽  
Vol 12 (3) ◽  
pp. 824-831 ◽  
Author(s):  
Hajime Maeda ◽  
Tomohiro Maeda ◽  
Kazuhiko Mizuno ◽  
Kazuhisa Fujimoto ◽  
Hisao Shimizu ◽  
...  
Keyword(s):  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence
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