The superior performance of a Pt catalyst supported on nanoporous SiC–C composites for liquid-phase selective hydrogenation of cinnamaldehyde

RSC Advances ◽  
2016 ◽  
Vol 6 (84) ◽  
pp. 81211-81218 ◽  
Author(s):  
Ruihua Yao ◽  
Junrui Li ◽  
Peng Wu ◽  
Xiaohong Li

The Pt/SiC–C catalyst: active, selective (80% selectivity to unsaturated alcohol) and reusable for liquid-phase hydrogenation of cinnamaldehyde at room temperature.

2019 ◽  
Vol 9 (12) ◽  
pp. 3226-3237 ◽  
Author(s):  
Qixiang Wang ◽  
Guimei Wang ◽  
Huiyue Xin ◽  
Jiaxu Liu ◽  
Guang Xiong ◽  
...  

3Pt0.05Sn/HPZSM-5 serves as a much more active and recyclable catalyst for the liquid-phase selective hydrogenation of cinnamaldehyde to cinnamyl alcohol.


RSC Advances ◽  
2018 ◽  
Vol 8 (60) ◽  
pp. 34370-34373 ◽  
Author(s):  
Mhamed Benaissa ◽  
Abdullah M. Alhanash ◽  
Ahmed T. Mubarak ◽  
Morad Eissa ◽  
Taher Sahlabji ◽  
...  

Total conversion of cyclohexene to cyclohexane was achieved in a liquid phase hydrogenation reaction at room temperature, 1 atm H2 pressure and solvent-free system.


1986 ◽  
Vol 89 ◽  
Author(s):  
S. H. Shin ◽  
J. G. Pasko ◽  
D. S. Lo ◽  
W. E. Tennant ◽  
J. R. Anderson ◽  
...  

AbstractHgMnCdTe/CdTe photodiodes with responsivity cutoffs of up to 1.54 pm have been fabricated by liquid phase epitaxy (LPE). The mesa device structure consists of a boron-implanted mosaic fabricated on a p-type Hg1−x−yMnxCdyTe layer grown on a CdTe substrate. A reverse breakdown voltage (VB) of 50 V and a leakage current density of 1.5 × 10−4 A/cm2 at V = −10 V was measured at room temperature (295K). A 0.75 pF capacitance was also measured under a 5 V reverse bias at room temperature. This device performance based on the quaternary HgMnCdTe shows both theoretical and practical promise of superior performance for wavelengths in the range 1.3 to 1.8 μm for fiber optic applications.


2019 ◽  
Vol 55 (23) ◽  
pp. 3363-3366 ◽  
Author(s):  
Yujie Xue ◽  
Huiyue Xin ◽  
Wenhui Xie ◽  
Peng Wu ◽  
Xiaohong Li

The Pt/YCo0.3Fe0.7O3 catalyst furnished ca. 95% selectivity to cinnamyl alcohol at nearly full conversion for the selective hydrogenation of cinnamaldehyde.


2014 ◽  
Vol 960-961 ◽  
pp. 221-224
Author(s):  
Jie Wu ◽  
Guang Yin Fan ◽  
Wen Jun Huang

FexOy@C nanocomposites were synthesized and used as carriers for depositing Pt nanoparticles. Catalytic properties of the nanocomposites were investigated for the hydrogenation of p-chloronitrobenzene at room temperature and balloon hydrogen pressure. The catalyst Pt/FexOy@C was extremely active for the hydrogenation of p-chloronitrobenzene. Completely conversion of p-chloronitrobenzene was achieved with a selectivity of 99.7 % in ethanol-water mixture in a reaction time of 40 min. Moreover, it can be reused four times without loss of any activity.


2019 ◽  
Vol 62 (1-2) ◽  
pp. 89-109 ◽  
Author(s):  
DV . Glyzdova ◽  
N.S . Smirnova ◽  
D.A . Shlyapin ◽  
P.G. Tsyrul’nikov

In the presented review the results of studies devoted to the selective hydrogenation of acetylene to ethylene over bimetallic palladium-containing catalysts are systematized. General regularities and peculiarities of the catalysts action in gas-phase hydrogenation of traces of acetylene in the acetylene-ethylene mixture obtained by pyrolysis of petroleum raw materials, as well as in the process of liquid-phase hydrogenation of mixtures enriched with acetylene and hydrogen are analyzed. The advantages of obtaining ethylene by hydrogenation of acetylene in the liquid phase are shown and ways of increasing the selectivity of this process are considered.


RSC Advances ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 602-610
Author(s):  
Yingxin Liu ◽  
Kai Liu ◽  
Meihua Zhang ◽  
Kaiyue Zhang ◽  
Jiao Ma ◽  
...  

Herein, we report a highly efficient and recyclable Cu–Re(1 : 1)/TiO2 bimetallic catalyst for liquid phase hydrogenation of levulinic acid to γ-valerolactone.


2011 ◽  
Vol 183-185 ◽  
pp. 2322-2326 ◽  
Author(s):  
Chang Hai Du ◽  
Yong Zhao ◽  
De Sun

The Co-promoted Ni-B amorphous nanoalloy catalysts were prepared by the chemical reduction of the aqueous solution containing nickel acetate and cobalt acetate with NaBH4 at room temperature and characterized by BET, XRD and DSC. They were used as catalysts for the liquid phase hydrogenation of furfural to furfural alcohol in alcohol at 353 K under 2.0 MPa of hydrogen. Ni-Co-B catalyst was characterized by XRD as amorphous structure. It was active in the hydrogenation of furfural, and it was significantly more active than Ni-B and Co-B. The optimal Co/ ( Co+Ni ) mole ratio in Ni-Co-B was 0.5.


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