A nanoporous Ag(i) coordination polymer for selective adsorption of carcinogenic dye Acid Red 26

2017 ◽  
Vol 53 (35) ◽  
pp. 4767-4770 ◽  
Author(s):  
Cheng-Peng Li ◽  
Hang Zhou ◽  
Si Wang ◽  
Hong-Han Yuan ◽  
Su-Zhen Zhang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Coordination Polymer ◽  
Selective Adsorption ◽  
Complete Removal ◽  
Size Exclusion ◽  
Matching Effect

This work presents a unique Ag(i) nanoporous coordination polymer, showing selective and complete removal of carcinogenic dye Acid Red 26 from aqueous solution upon the size-exclusion and charge-matching effect.

Application of iron-coated sand on the treatment of toxic metals

2004 ◽  
Vol 4 (5-6) ◽  
pp. 335-341 ◽  
Author(s):  
Jae-Kyu Yang ◽  
Yoon-Young Chang ◽  
Sung-Il Lee ◽  
Hyung-Jin Choi ◽  
Seung-Mok Lee
Keyword(s):  
Heavy Metals ◽  
Selective Adsorption ◽  
Complete Removal ◽  
Batch Adsorption ◽  
Column Experiments ◽  
Adsorption Behaviour ◽  
Optimum Amount ◽  
Initial Ph ◽  
New Treatment ◽  
Coated Sand

Iron-coated sand (ICS) prepared by using FeCl3 and Joomoonjin sand widely used in Korea was used in this study. In batch adsorption kinetics, As(V) adsorption onto ICS was completed within 20 minutes, while adsorption of Pb(II), Cd(II), and Cu(II) onto ICS was slower than that of As(V) and strongly depended on initial pH. At pH 3.5, ICS showed a selective adsorption of Pb(II) compared to Cd( II) and Cu(II) . However, above pH 4.5, near complete removal of Pb(II), Cd(II), and Cu(II) was observed through adsorption or precipitation depending on pH. As(V) adsorption onto ICS occurred through an anionic-type and followed a Langmuir-type adsorption behaviour. In column experiments, pH was identified as an important parameter in the breakthrough of As(V). As(V) breakthrough at pH 4.5 was much slower than at pH 9 due to a strong chemical bonding between As(V) and ICS as similar with batch adsorption behaviour. With variation of ICS amounts, the optimum amount of ICS at pH 4.5 was identified as 5.0 grams in this research. At this condition, ICS could be used to treat 200 mg of As(V) with 1 kg of ICS until 50 ppb of As(V) appeared in the effluent. In this research, as a new treatment system, ICS can be potentially used to treat As(V) and cationic heavy metals.

scholarly journals Sulfobetaine Cryogels for Preferential Adsorption of Methyl Orange from Mixed Dye Solutions

Polymers ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 208
Author(s):  
Ramona B. J. Ihlenburg ◽  
Anne-Catherine Lehnen ◽  
Joachim Koetz ◽  
Andreas Taubert
Keyword(s):  
Aqueous Solution ◽  
Methylene Blue ◽  
Methyl Orange ◽  
Dye Removal ◽  
Selective Adsorption ◽  
Water Soluble ◽  
Organic Substances ◽  
Preferential Adsorption ◽  
Dimethyl Ammonium ◽  
Dye Solutions

New cryogels for selective dye removal from aqueous solution were prepared by free radical polymerization from the highly water-soluble crosslinker N,N,N’,N’-tetramethyl-N,N’-bis(2-ethylmethacrylate)-propyl-1,3-diammonium dibromide and the sulfobetaine monomer 2-(N-3-sulfopropyl-N,N-dimethyl ammonium)ethyl methacrylate. The resulting white and opaque cryogels have micrometer sized pores with a smaller substructure. They adsorb methyl orange (MO) but not methylene blue (MB) from aqueous solution. Mixtures of MO and MB can be separated through selective adsorption of the MO to the cryogels while the MB remains in solution. The resulting cryogels are thus candidates for the removal of hazardous organic substances, as exemplified by MO and MB, from water. Clearly, it is possible that the cryogels are also potentially interesting for removal of other compounds such as pharmaceuticals or pesticides, but this must be investigated further.

An Adsorbate Discriminatory Gate Effect in a Flexible Porous Coordination Polymer for Selective Adsorption of CO2 over C2H2

2016 ◽  
Vol 138 (9) ◽  
pp. 3022-3030 ◽  
Author(s):  
Maw Lin Foo ◽  
Ryotaro Matsuda ◽  
Yuh Hijikata ◽  
Rajamani Krishna ◽  
Hiroshi Sato ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Selective Adsorption ◽  
Gate Effect ◽  
Porous Coordination Polymer ◽  
Adsorption Of Co2

scholarly journals Synthesis and Characterisation of Ligand Free Cadmium Imprinted Polymer for Sensing of Cd(II) from Aqueous Solution

2019 ◽  
Vol 4 (3) ◽  
pp. 153-157
Author(s):  
Anuradha Baghel ◽  
Akula Bhuvaneswari ◽  
Virendra Vikram Singh ◽  
Mannan Boopathi ◽  
Beer Singh
Keyword(s):  
Aqueous Solution ◽  
Complete Removal ◽  
Carbonyl Oxygen ◽  
Sem Analysis ◽  
Bet Surface Area ◽  
Imprinted Polymer ◽  
Selective Electrode ◽  
Ligand Free ◽  
Interference Study ◽  
Tga Analysis

Cadmium(II)-imprinted polymer [Cd(II)-IIP] was synthesized without using the conventional complexing ligand to reduce unnecessary step for complexing Cd(II). During synthesis of Cd(II)-IIP, the complete removal of Cd(II) from the polymer was confirmed using EDAX and AAS. Synthesized polymers ([Cd(II)-IIP], non-imprinted polymer (NIP) and polymer with cadmium (CdP) were also characterized and compared. SEM analysis of Cd(II)-IIP indicated the changes in surface morphology after imprinting, the polymer looked like a flaky material in comparison with NIP and CdP. BET surface area of Cd(II)-IIP (68 m2/g) was found to be more than that of NIP (24.6 m2/g) and CdP (17 m2/g). Cd(II)-IIP formed a complex with Cd(II) in the solution through carbonyl oxygen of the acrylamide as confirmed by FTIR. TGA analysis showed less char yield for Cd(II)-IIP than NIP. Cd(II)-IIP was further explored for the fabrication of ion selective electrode (ISE), which on binding with Cd(II) gave higher potential than NIP-ISE. Interference study was also performed using Cd(II)-IIP as such and also with fabricated ISE with Cd(II)-IIP using different cations such as Pb(II), Zn(II), Mn(II), Hg(II), and found that imprinted polymer showed more selectivity towards Cd(II) in aqueous solutions.

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