Ultrathin nickel hydroxide on carbon coated 3D-porous copper structures for high performance supercapacitors

2018 ◽  
Vol 20 (2) ◽  
pp. 719-727 ◽  
Author(s):  
Kyeong-Nam Kang ◽  
Ik-Hee Kim ◽  
Ananthakumar Ramadoss ◽  
Sun-I Kim ◽  
Jong-Chul Yoon ◽  
...  
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Three Dimensional ◽  
Rate Capability ◽  
High Energy ◽  
High Energy Density ◽  
Cycle Stability ◽  
Porous Copper ◽  
Carbon Coated ◽  
Copper Structure

Ultrahigh rate capability, cycle stability, and high energy density supercapacitors supported by the three-dimensional (3D) carbon coated copper structure.

A three-dimensional graphene framework-enabled high-performance stretchable asymmetric supercapacitor

2018 ◽  
Vol 6 (4) ◽  
pp. 1802-1808 ◽  
Author(s):  
Ke Li ◽  
Yanshan Huang ◽  
Jingjing Liu ◽  
Mansoor Sarfraz ◽  
Phillips O. Agboola ◽  
...  
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Three Dimensional ◽  
High Energy ◽  
Cycling Stability ◽  
High Energy Density ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors ◽  
Superior Cycling Stability

Three-dimensional graphene frameworks enable the development of stretchable asymmetric supercapacitors with a record high energy density of 77.8 W h kg−1, and also excellent stretchability and superior cycling stability.

Nanospace-confined synthesis of oriented porous carbon nanosheets for high-performance electrical double layer capacitors

2016 ◽  
Vol 4 (43) ◽  
pp. 16879-16885 ◽  
Author(s):  
Ya Wang ◽  
Hui Dou ◽  
Bing Ding ◽  
Jie Wang ◽  
Zhi Chang ◽  
...  
Keyword(s):  
Energy Density ◽  
Porous Carbon ◽  
Electrical Double Layer ◽  
High Performance ◽  
Three Dimensional ◽  
High Energy ◽  
High Energy Density ◽  
Carbon Nanosheets ◽  
Electrical Double Layer Capacitors ◽  
Double Layer Capacitors

A symmetric capacitor based on facilely synthesized three-dimensional oriented porous carbon nanosheets delivers high energy density.

Three-dimensional Co3O4@C@Ni3S2 sandwich-structured nanoneedle arrays: towards high-performance flexible all-solid-state asymmetric supercapacitors

2015 ◽  
Vol 3 (31) ◽  
pp. 16150-16161 ◽  
Author(s):  
Dezhi Kong ◽  
Chuanwei Cheng ◽  
Ye Wang ◽  
Jen It Wong ◽  
Yaping Yang ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Solid State ◽  
High Performance ◽  
Three Dimensional ◽  
Negative Electrode ◽  
High Energy ◽  
High Energy Density ◽  
Asymmetric Supercapacitor ◽  
Cycle Stability ◽  
Asymmetric Supercapacitors

A novel asymmetric supercapacitor composed of Co3O4@C@Ni3S2 NNAs as the positive electrode and activated carbon (AC) as the negative electrode can deliver a high energy density and excellent long cycle stability.

Hierarchical three-dimensional mesoporous MnO2 nanostructures for high performance aqueous asymmetric supercapacitors

2016 ◽  
Vol 4 (2) ◽  
pp. 587-595 ◽  
Author(s):  
Sourav Bag ◽  
C. Retna Raj
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Three Dimensional ◽  
High Energy ◽  
High Energy Density ◽  
Asymmetric Supercapacitor ◽  
Asymmetric Supercapacitors

Nanocrystalline mesoporous α-MnO2 is synthesized for the fabrication of a high energy density aqueous asymmetric supercapacitor device.

scholarly journals Dielectric capacitors with three-dimensional nanoscale interdigital electrodes for energy storage

2015 ◽  
Vol 1 (9) ◽  
pp. e1500605 ◽  
Author(s):  
Fangming Han ◽  
Guowen Meng ◽  
Fei Zhou ◽  
Li Song ◽  
Xinhua Li ◽  
...  
Keyword(s):  
Energy Storage ◽  
Energy Density ◽  
Breakdown Voltage ◽  
High Performance ◽  
Traditional Approach ◽  
Three Dimensional ◽  
High Energy ◽  
High Energy Density ◽  
Interdigital Electrodes ◽  
Large Capacitance

Dielectric capacitors are promising candidates for high-performance energy storage systems due to their high power density and increasing energy density. However, the traditional approach strategies to enhance the performance of dielectric capacitors cannot simultaneously achieve large capacitance and high breakdown voltage. We demonstrate that such limitations can be overcome by using a completely new three-dimensional (3D) nanoarchitectural electrode design. First, we fabricate a unique nanoporous anodic aluminum oxide (AAO) membrane with two sets of interdigitated and isolated straight nanopores opening toward opposite planar surfaces. By depositing carbon nanotubes in both sets of pores inside the AAO membrane, the new dielectric capacitor with 3D nanoscale interdigital electrodes is simply realized. In our new capacitors, the large specific surface area of AAO can provide large capacitance, whereas uniform pore walls and hemispheric barrier layers can enhance breakdown voltage. As a result, a high energy density of 2 Wh/kg, which is close to the value of a supercapacitor, can be achieved, showing promising potential in high-density electrical energy storage for various applications.

scholarly journals High-Energy and High-Power Pseudocapacitor–Battery Hybrid Sodium-Ion Capacitor with Na+ Intercalation Pseudocapacitance Anode

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Qiulong Wei ◽  
Qidong Li ◽  
Yalong Jiang ◽  
Yunlong Zhao ◽  
Shuangshuang Tan ◽  
...  
Keyword(s):  
Energy Density ◽  
High Power ◽  
Anode Materials ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Specific Capacity ◽  
Rate Capability ◽  
High Energy ◽  
Sodium Ion ◽  
High Energy Density

AbstractHigh-performance and low-cost sodium-ion capacitors (SICs) show tremendous potential applications in public transport and grid energy storage. However, conventional SICs are limited by the low specific capacity, poor rate capability, and low initial coulombic efficiency (ICE) of anode materials. Herein, we report layered iron vanadate (Fe5V15O39 (OH)9·9H2O) ultrathin nanosheets with a thickness of ~ 2.2 nm (FeVO UNSs) as a novel anode for rapid and reversible sodium-ion storage. According to in situ synchrotron X-ray diffractions and electrochemical analysis, the storage mechanism of FeVO UNSs anode is Na+ intercalation pseudocapacitance under a safe potential window. The FeVO UNSs anode delivers high ICE (93.86%), high reversible capacity (292 mAh g−1), excellent cycling stability, and remarkable rate capability. Furthermore, a pseudocapacitor–battery hybrid SIC (PBH-SIC) consisting of pseudocapacitor-type FeVO UNSs anode and battery-type Na3(VO)2(PO4)2F cathode is assembled with the elimination of presodiation treatments. The PBH-SIC involves faradaic reaction on both cathode and anode materials, delivering a high energy density of 126 Wh kg−1 at 91 W kg−1, a high power density of 7.6 kW kg−1 with an energy density of 43 Wh kg−1, and 9000 stable cycles. The tunable vanadate materials with high-performance Na+ intercalation pseudocapacitance provide a direction for developing next-generation high-energy capacitors.

scholarly journals Supercritical CO2 Synthesis of Freestanding Se1-xSx Foamy Cathodes for High-Performance Li-Se1-xSx Battery

2021 ◽  
Vol 9 ◽  
Author(s):  
Chengwei Lu ◽  
Ruyi Fang ◽  
Kun Wang ◽  
Zhen Xiao ◽  
G. Gnana kumar ◽  
...  
Keyword(s):  
High Performance ◽  
Specific Capacity ◽  
Three Dimensional ◽  
Rate Capability ◽  
Carbon Matrix ◽  
High Energy ◽  
Rechargeable Batteries ◽  
High Energy Density ◽  
Rechargeable Lithium Batteries ◽  
Practical Applications

Selenium-sulfur solid solutions (Se1-xSx) are considered to be a new class of promising cathodic materials for high-performance rechargeable lithium batteries owing to their superior electric conductivity than S and higher theoretical specific capacity than Se. In this work, high-performance Li-Se1-xSx batteries employed freestanding cathodes by encapsulating Se1-xSx in a N-doped carbon framework with three-dimensional (3D) interconnected porous structure (NC@SWCNTs) are proposed. Se1-xSx is uniformly dispersed in 3D porous carbon matrix with the assistance of supercritical CO2 (SC-CO2) technique. Impressively, NC@SWCNTs host not only provides spatial confinement for Se1-xSx and efficient physical/chemical adsorption of intermediates, but also offers a highly conductive framework to facilitate ion/electron transport. More importantly, the Se/S ratio of Se1-xSx plays an important role on the electrochemical performance of Li- Se1-xSx batteries. Benefiting from the rationally designed structure and chemical composition, NC@[email protected] cathode exhibits excellent cyclic stability (632 mA h g−1 at 200 cycle at 0.2 A g−1) and superior rate capability (415 mA h g−1 at 2.0 A g−1) in carbonate-based electrolyte. This novel NC@[email protected] cathode not only introduces a new strategy to design high-performance cathodes, but also provides a new approach to fabricate freestanding cathodes towards practical applications of high-energy-density rechargeable batteries.

Self-assembled three-dimensional hierarchical porous V2O5/graphene hybrid aerogels for supercapacitors with high energy density and long cycle life

2015 ◽  
Vol 3 (5) ◽  
pp. 1828-1832 ◽  
Author(s):  
Yingjie Wu ◽  
Guohua Gao ◽  
Guangming Wu
Keyword(s):  
Energy Density ◽  
High Performance ◽  
Three Dimensional ◽  
High Energy ◽  
Cycle Life ◽  
High Energy Density ◽  
Long Cycle Life ◽  
Hierarchical Porous ◽  
Self Assembled ◽  
Hybrid Aerogels

A self-assembled three-dimensional hierarchical porous V2O5/graphene hybrid aerogel for high-performance supercapacitor was synthesized.

NIPS derived three-dimensional porous copper membrane for high-energy-density lithium-ion batteries

2019 ◽  
Vol 312 ◽  
pp. 424-431 ◽  
Author(s):  
Xinxin Guan ◽  
Zhijia Zhang ◽  
Shaofei Zhang ◽  
Yixiao Wang ◽  
Huan Yang ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Three Dimensional ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Porous Copper

scholarly journals Free-Standing and Heteroatoms-Doped Carbon Nanofiber Networks as a Binder-Free Flexible Electrode for High-Performance Supercapacitors

Nanomaterials ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1189 ◽  
Author(s):  
Yan ◽  
You ◽  
Liu ◽  
Wang ◽  
Wu
Keyword(s):  
High Performance ◽  
Carbon Nanofiber ◽  
Three Dimensional ◽  
Rate Capability ◽  
Mesoporous Structure ◽  
High Energy ◽  
High Energy Density ◽  
Free Standing ◽  
Electrode Cell ◽  
Binder Free

Flexible and heteroatoms-doped (N, O and P) activated carbon nanofiber networks (ACFNs) have been successfully prepared with a mixture of polyamic acid (PAA) and poly(diaryloxyphosphazene) (PDPP) as a solution through electrospinning, followed by a heat post-treatment. The resultant heteroatoms-doped ACFNs can be used as binder-free electrodes for high-performance flexible supercapacitors (SCs) due to lightweight, three-dimensional open-pore structure and good mechanical strength. Despite its surface area being lower than 130.6 m2·g−1, the heteroatoms-doped ACFNs exhibited a high heteroatoms (N, O and P) content of 17.9%, resulting in a highly specific capacitance of 182 F·g−1 at a current density of 1 A·g−1 in 6 M KOH electrolyte in a two-electrode cell and an excellent rate capability of 74.7% of its initial capacitance from 1 A·g−1 to 10 A·g−1 under the mass loading of 1.5 mg·cm−2. The electrical double-layer (EDL) capacitance and pseudocapacitance can be easily decoupled in the heteroatoms-doped mesoporous ACFNs. SCs device based on heteroatoms-doped ACFNs exhibited a high energy density of 6.3 W·h·kg−1 with a power density of 250 W·kg−1, as well as excellent cycling stability with 88% capacitance retention after 10,000 charge–discharge cycles. The excellent electrochemical performance was attributed to the mesoporous structure of ACFNs and pseudocapacitive heteroatoms.

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