scholarly journals Oxygen electrode reactions of doped BiFeO3 materials for low and elevated temperature fuel cell applications

RSC Advances ◽  
2017 ◽  
Vol 7 (75) ◽  
pp. 47643-47653 ◽  
Author(s):  
Rana Arslan Afzal ◽  
Ka-Young Park ◽  
Sung-Hwa Cho ◽  
Nam-In Kim ◽  
Sung Ryul Choi ◽  
...  

Bi0.6Ca0.4FeO3 demonstrates potential as an oxygen electrode material (for oxygen evolution and reduction reactions) for operation at room and elevated temperatures.

2019 ◽  
Vol 1 (8) ◽  
pp. 3243-3251 ◽  
Author(s):  
Pranav K. Gangadharan ◽  
Siddheshwar N. Bhange ◽  
Nasrin Kabeer ◽  
Rajith Illathvalappil ◽  
Sreekumar Kurungot

A three-dimensional interconnected nanostructure (NCS) consisting of the NiCo2O4 nanoarray over CNT modified melamine foam, which acts as an efficient bifunctional electrocatalyst for the oxygen evolution reaction and oxygen reduction reactions.


Nanoscale ◽  
2020 ◽  
Vol 12 (39) ◽  
pp. 20413-20424
Author(s):  
Riming Hu ◽  
Yongcheng Li ◽  
Fuhe Wang ◽  
Jiaxiang Shang

Bilayer single atom catalysts can serve as promising multifunctional electrocatalysts for the HER, ORR, and OER.


2021 ◽  
Author(s):  
Song-Jeng Isaac Huang ◽  
Adil Muneeb ◽  
Sabhapathy Palani ◽  
Anjaiah Sheelam ◽  
Bayikadi Khasimsaheb ◽  
...  

Developing a non-precious metal electrocatalyst for oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) is desirable for low-cost energy conversion devices. Herein, we designed and developed a new class...


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1473
Author(s):  
Jun Zhao ◽  
Kang Wang ◽  
Shuaibin Wang ◽  
Zike Wang ◽  
Zhaohui Yang ◽  
...  

This paper presents results from experimental work on mechanical properties of geopolymer concrete, mortar and paste prepared using fly ash and blended slag. Compressive strength, splitting tensile strength and flexural strength tests were conducted on large sets of geopolymer and ordinary concrete, mortar and paste after exposure to elevated temperatures. From Thermogravimetric analyzer (TGA), X-ray diffraction (XRD), Scanning electron microscope (SEM) test results, the geopolymer exhibits excellent resistance to elevated temperature. Compressive strengths of C30, C40 and C50 geopolymer concrete, mortar and paste show incremental improvement then followed by a gradual reduction, and finally reach a relatively consistent value with an increase in exposure temperature. The higher slag content in the geopolymer reduces residual strength and the lower exposure temperature corresponding to peak residual strength. Resistance to elevated temperature of C40 geopolymer concrete, mortar and paste is better than that of ordinary concrete, mortar and paste at the same grade. XRD, TGA and SEM analysis suggests that the heat resistance of C–S–H produced using slag is lower than that of sulphoaluminate gel (quartz and mullite, etc.) produced using fly ash. This facilitates degradation of C30, C40 and C50 geopolymer after exposure to elevated temperatures.


Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1000
Author(s):  
Guoxiao Xu ◽  
Juan Zou ◽  
Zhu Guo ◽  
Jing Li ◽  
Liying Ma ◽  
...  

Although sulfonic acid (SA)-based proton-exchange membranes (PEMs) dominate fuel cell applications at low temperature, while sulfonation on polymers would strongly decay the mechanical stability limit the applicable at elevated temperatures due to the strong dependence of proton conduction of SA on water. For the purpose of bifunctionally improving mechanical property and high-temperature performance, Nafion membrane, which is a commercial SA-based PEM, is composited with fabricated silica nanofibers with a three-dimensional network structure via electrospinning by considering the excellent water retention capacity of silica. The proton conductivity of the silica nanofiber–Nafion composite membrane at 110 °C is therefore almost doubled compared with that of a pristine Nafion membrane, while the mechanical stability of the composite Nafion membrane is enhanced by 44%. As a result, the fuel cell performance of the silica nanofiber-Nafion composite membrane measured at high temperature and low humidity is improved by 38%.


2011 ◽  
Vol 261-263 ◽  
pp. 416-420 ◽  
Author(s):  
Fu Ping Jia ◽  
Heng Lin Lv ◽  
Yi Bing Sun ◽  
Bu Yu Cao ◽  
Shi Ning Ding

This paper presents the results of elevated temperatures on the compressive of high fly ash content concrete (HFCC). The specimens were prepared with three different replacements of cement by fly ash 30%, 40% and 50% by mass and the residual compressive strength was tested after exposure to elevated temperature 250, 450, 550 and 650°C and room temperature respectively. The results showed that the compressive strength apparently decreased with the elevated temperature increased. The presence of fly ash was effective for improvement of the relative strength, which was the ratio of residual compressive strength after exposure to elevated temperature and ordinary concrete. The relative compressive strength of fly ash concrete was higher than those of ordinary concrete. Based on the experiments results, the alternating simulation formula to determine the relationship among relative strength, elevated temperature and fly ash replacement is developed by using regression of results, which provides the theoretical basis for the evaluation and repair of HFCC after elevated temperature.


Sign in / Sign up

Export Citation Format

Share Document