Structural characterization of a fluorescein hydrazone molecular switch with application towards logic gates

2018 ◽  
Vol 42 (22) ◽  
pp. 18050-18058 ◽  
Author(s):  
Juan D. Villada ◽  
Richard F. D’Vries ◽  
Mario Macías ◽  
Fabio Zuluaga ◽  
Manuel N. Chaur
Keyword(s):  
Structural Characterization ◽  
Metal Cations ◽  
Logic Gates ◽  
Molecular Switch ◽  
Logic Circuits ◽  
X Ray ◽  
Ph Changes ◽  
X Ray Crystallography ◽  
Half Adder

A new polymorph of fluorescein hydrazone was fully characterized via single X-ray crystallography. In addition, multiple logic circuits and a Half-Adder operator were designed using the fluorescence and UV-Vis switching responses of the fluorescein compound to different metal cations and pH changes.

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

Synthesis and structural characterization of a magnesium phthalocyanine(3–) anion

2012 ◽  
Vol 16 (01) ◽  
pp. 154-162 ◽  
Author(s):  
Edwin W.Y. Wong ◽  
Daniel B. Leznoff
Keyword(s):  
Absorption Spectrum ◽  
Solid State ◽  
Single Crystal ◽  
Structural Characterization ◽  
Heterometallic Complex ◽  
State Structure ◽  
Solid State Structure ◽  
X Ray ◽  
X Ray Crystallography

The reduction of magnesium phthalocyanine (MgPc) with 2.2 equivalents of potassium graphite in 1,2-dimethoxyethane (DME) gives [K2(DME)4]PcMg(OH)(1) in 67% yield. Compound 1 was structurally characterized using single crystal X-ray crystallography and was found to be a monomeric, heterometallic complex consisting of a μ3-OH ligand that bridges a [MgIIPc3-]- anion to two potassium cations solvated by four DME molecules. An absorption spectrum of 1 confirms the Pc ligand is singly reduced and has a 3–charge. The solid-state structure of 1 does not indicate breaking of the aromaticity of the Pc ligand. Compound 1 is only the second Pc3- complex and the first reduced MgPc to be isolated and structurally characterized.

scholarly journals Structural characterization of alloxazine and substituted isoalloxazines: NMR and X-ray crystallography

ARKIVOC ◽  
2006 ◽  
Vol 2007 (4) ◽  
pp. 20-38 ◽  
Author(s):  
Mª Ángeles Farrán ◽  
Rosa Mª Claramunt ◽  
Concepción López ◽  
Elena Pinilla ◽  
Mª Rosario Torres ◽  
...  
Keyword(s):  
Structural Characterization ◽  
X Ray ◽  
X Ray Crystallography

Activation of C–Cl Bonds: Synthesis and Structural Characterization of [Ru2(μ-Cl)(μ-PtBu2)(μ- Ph2PN(H)PPh2)(CO)4]

2013 ◽  
Vol 68 (5-6) ◽  
pp. 743-746 ◽  
Author(s):  
Tobias Mayer ◽  
Hans-Christian Böttcher
Keyword(s):  
Carbon Tetrachloride ◽  
Single Crystals ◽  
Structural Characterization ◽  
Title Compound ◽  
X Ray ◽  
X Ray Crystallography ◽  
High Yields

The synthesis and structural characterization of the complex [Ru2(μ-Cl)(μ-PtBu2)(μ-dppa)(CO)4] (4, dppa = Ph2PN(H)PPh2) are reported. The title compound and two other related complexes were obtained in high yields by the reaction of the coordinatively unsaturated species [Ru2(μ-H)(μ-PtBu2)(μ-PˆP)(CO)4] (PˆP = dppa, 3; PˆP =Ph2PN(Ph)PPh2, 5; PˆP =Ph2PN(CH2Ph)PPh2, 6) with carbon tetrachloride. Single crystals of 4 grown from dichloromethane-acetone have been analyzed by X-ray crystallography

scholarly journals Structural features and near infra-red (NIR) luminescence of isomeric Yb(iii) bipyridyl-N,N′-dioxide coordination polymers

2015 ◽  
Vol 44 (29) ◽  
pp. 13378-13383 ◽  
Author(s):  
Gail M. Sequeira ◽  
Wayne Y. Tan ◽  
Evan G. Moore
Keyword(s):  
Coordination Polymers ◽  
Structural Characterization ◽  
Lanthanide Complexes ◽  
Structural Features ◽  
X Ray ◽  
X Ray Crystallography ◽  
Infra Red ◽  
Nir Luminescence

The synthesis and structural characterization of a series of lanthanide complexes formed from YbX3 salts (X = NO3− or CF3SO3−) and the isomeric 4,4′-bipyridine-N,N′-dioxide (4,4′-bpdo) or 3,3′-bipyridine-N,N′-dioxide (3,3′-bpdo) ligands has been undertaken by X-ray crystallography.

Synthesis and structural characterization of m-terphenyl Schiff base ligands and their aluminum complexes

2004 ◽  
Vol 82 (9) ◽  
pp. 1346-1352 ◽  
Author(s):  
Diane A Dickie ◽  
Hanifa Jalali ◽  
Rahul G Samant ◽  
Michael C Jennings ◽  
Jason AC Clyburne
Keyword(s):  
Schiff Base ◽  
Schiff Bases ◽  
Structural Characterization ◽  
Condensation Reaction ◽  
Schiff Base Ligands ◽  
X Ray ◽  
X Ray Crystallography ◽  
Aluminum Complexes

2,4,6-Triphenylbenzaldehyde 1 undergoes a condensation reaction with 2-aminophenol to give N-(2′,4′,6′-triphenylbenzylidene)-2-iminophenol (TPIP) 2. The imine 2 can be reduced with NaBH4 in ethanol to form N-(2′,4′,6′-triphenylbenzyl)-2-aminophenol (TPAP) 3. Addition of trimethylaluminum to 2 or 3 results in the formation of the complexes TPIP-AlMe2·AlMe3 (4) or TPAP-AlMe2 (5). Compounds 2, 3, and 4 have been crystallographically characterized.Key words: N,O ligands, aluminum, m-terphenyl, Schiff bases, X-ray crystallography.

The Synthesis and Structural Characterization of a Two-Dimensional Coordination Polymer [Co(H2O)(phen)(μ4-bta)1/2]n (H4bta = Benzenetetracarboxylic Acid)

2001 ◽  
Vol 66 (6) ◽  
pp. 870-876 ◽  
Author(s):  
De-Qing Chu ◽  
Ji-Qing Xu ◽  
Ao-Qing Tang
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Characterization ◽  
Two Dimensional ◽  
Polymeric Structure ◽  
X Ray ◽  
X Ray Crystallography

Complex [Co(H2O)(phen)(μ4-bta)1/2]n was hydrothermally synthesized from sodium benzene-1,2,4,5-tetracarboxylate, 1,10-phenanthroline and CoCl2·6H2O, and structurally characterized by single-crystal X-ray crystallography, showing that it possesses a novel two-dimensional polymeric structure.

Methane Sorption and Structural Characterization of the Sorption Sites in Zn2(bdc)2(dabco) by Single Crystal X-ray Crystallography

2009 ◽  
Vol 4 (6) ◽  
pp. 886-891 ◽  
Author(s):  
Hyunuk Kim ◽  
Denis G. Samsonenko ◽  
Sunirban Das ◽  
Ghyung-Hwa Kim ◽  
Heung-Soo Lee ◽  
...  
Keyword(s):  
Single Crystal ◽  
Structural Characterization ◽  
X Ray ◽  
X Ray Crystallography ◽  
Methane Sorption

scholarly journals Biochemical and structural characterization of polyphosphate kinase 2 from the intracellular pathogen Francisella tularensis

2016 ◽  
Vol 36 (1) ◽  
Author(s):  
Laura E. Batten ◽  
Alice E. Parnell ◽  
Neil J. Wells ◽  
Amber L. Murch ◽  
Petra C. F. Oyston ◽  
...  
Keyword(s):  
Francisella Tularensis ◽  
Structural Characterization ◽  
Deletion Mutant ◽  
Antibiotic Sensitivity ◽  
Polyphosphate Kinase ◽  
Intracellular Pathogen ◽  
Gene Encoding ◽  
X Ray ◽  
X Ray Crystallography

The polyphosphate kinase 2 (PPK2) from the intracellular pathogen Francisella tularensis has been characterized by a range of biochemical methods and X-ray crystallography. The antibiotic sensitivity of a deletion mutant lacking the gene encoding PPK2 is also reported.

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