Photocatalytic hydrogenation of nitroarenes: supporting effect of CoOx on TiO2 nanoparticles

2019 ◽  
Vol 43 (2) ◽  
pp. 748-754 ◽  
Author(s):  
Srinivasa Rao Amanchi ◽  
K. V. Ashok Kumar ◽  
Bhairi Lakshminarayana ◽  
G. Satyanarayana ◽  
Ch. Subrahmanyam
Keyword(s):  
Solid State ◽  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Visible Light Irradiation ◽  
Functional Group ◽  
Synthesis Method ◽  
Light Irradiation ◽  
Supporting Effect ◽  
High Yields ◽  
Solid State Synthesis Method

We report a nanocatalyst CoOx/TiO2 with different loadings of CoOx by a solid state synthesis method for the green hydrogenation of nitroarenes under visible light irradiation. Notably, we observed very good selectivity, conversion and functional group tolerance with high yields.

Acetylation of Alcohols and Amines under Visible Light Irradiation: Diacetyl as an Acylation Reagent and Photosensitizer

2021 ◽  
Author(s):  
Pengcheng Lian ◽  
Ruyi Li ◽  
Xiao Wan ◽  
Zixin Xiang ◽  
Hang Liu ◽  
...  
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Functional Group ◽  
Environmentally Friendly ◽  
Light Irradiation ◽  
Environmentally Friendly Process

This work developed an unprecedented strategy for the acetylation of alcohols and amines using diacetyl as both an acylation reagent and photosensitizer. This environmentally friendly process exhibits excellent functional group...

Hydrogen production from organic fatty acids using carbon-doped TiO2 nanoparticles under visible light irradiation

2018 ◽  
Vol 43 (9) ◽  
pp. 4335-4346 ◽  
Author(s):  
Yang Li ◽  
Liyuan Kuang ◽  
Dequan Xiao ◽  
Appala Raju Badireddy ◽  
Maocong Hu ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Hydrogen Production ◽  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Doped Tio2 ◽  
Carbon Doped

scholarly journals Photocatalytic degradation of deoxynivalenol over dendritic-like α-Fe2O3 under visible light irradiation

Toxins ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 105 ◽  
Author(s):  
Huiting Wang ◽  
Jin Mao ◽  
Zhaowei Zhang ◽  
Qi Zhang ◽  
Liangxiao Zhang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Visible Light ◽  
Photocatalytic Degradation ◽  
Visible Light Irradiation ◽  
Photoelectron Spectroscopy ◽  
High Performance ◽  
Synthesis Method ◽  
Light Irradiation ◽  
Trichothecene Mycotoxin ◽  
X Ray

Deoxynivalenol (DON) is a secondary metabolite produced by Fusarium, which is a trichothecene mycotoxin. As the main mycotoxin with high toxicity, wheat, barley, corn and their products are susceptible to contamination of DON. Due to the stability of this mycotoxin, traditional methods for DON reduction often require a strong oxidant, high temperature and high pressure with more energy consumption. Therefore, exploring green, efficient and environmentally friendly ways to degrade or reduce DON is a meaningful and challenging issue. Herein, a dendritic-like α-Fe2O3 was successfully prepared using a facile hydrothermal synthesis method at 160 °C, which was systematically characterized by X-ray diffraction (XRD), high-resolution transmission electron microscopy (HRTEM), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). It was found that dendritic-like α-Fe2O3 showed superior activity for the photocatalytic degradation of DON in aqueous solution under visible light irradiation (λ > 420 nm) and 90.3% DON (initial concentration of 4.0 μg/mL) could be reduced in 2 h. Most of all, the main possible intermediate products were proposed through high performance liquid chromatography-mass spectrometry (HPLC-MS) after the photocatalytic treatment. This work not only provides a green and promising way to mitigate mycotoxin contamination but also may present useful information for future studies.

scholarly journals Enhanced Photocatalytic Properties of PET Filaments Coated with Ag-N Co-Doped TiO2 Nanoparticles Sensitized with Disperse Blue Dyes

Nanomaterials ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 987 ◽  
Author(s):  
Hui Zhang ◽  
Qi Tang ◽  
Qingshan Li ◽  
Qingwen Song ◽  
Hailiang Wu ◽  
...  
Keyword(s):  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Visible Light Irradiation ◽  
Reaction Rate Constant ◽  
Light Irradiation ◽  
Photocatalytic Properties ◽  
Blue Dye ◽  
Dye Sensitization ◽  
Doped Tio2 ◽  
Co Doped

In this study, the effects of disperse blue dye-sensitization on the photocatalytic properties of the Ag-N co-doped TiO2 nanoparticles loaded on polyethylene terephthalate (PET) filaments are investigated under visible light irradiation. The microstructure and photocatalytic properties of the as-synthesized TiO2 nanocomposites, as well as the as-prepared PET filaments, are systematically characterized. The photocatalytic performance of the PET filaments coated with the Ag-N co-doped TiO2 nanoparticles sensitized with disperse blue dyes is evaluated via its capacity of photo-degrading methyl orange (MO) dyes under visible light irradiation. It is found that the holes are the predominant reactive radical species and the hydroxyl and superoxide radicals play a subordinate role in the photocatalytic reaction process. The reaction rate constant of the photocatalytic composite filaments is nearly 4.0 times higher than that of the PET filaments loaded solely with TiO2 nanoparticles. The resultant photocatalytic composite filaments are evident to be capable of repeatedly photo-degrading MO dyes without losing its photocatalytic activity significantly.

A photo-auxiliary approach – enabling excited state classical phototransformations with metal free visible light irradiation

2017 ◽  
Vol 53 (10) ◽  
pp. 1692-1695 ◽  
Author(s):  
Akila Iyer ◽  
Steffen Jockusch ◽  
Jayaraman Sivaguru
Keyword(s):  
Excited State ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Uv Light ◽  
Light Irradiation ◽  
Metal Free ◽  
High Yields

To address the problem of using UV light to initiate traditional photoreactions, hydrazide based chromophores are evaluated as a “photo-auxiliary“ with visible light using a metal free photocatalyst to afford photoproducts in high yields.

Metal free visible light driven oxidation of alcohols to carbonyl derivatives using 3,6-di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst

RSC Advances ◽  
2015 ◽  
Vol 5 (102) ◽  
pp. 84328-84333 ◽  
Author(s):  
Suvendu Samanta ◽  
Papu Biswas
Keyword(s):  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Metal Free ◽  
Carbonyl Derivatives ◽  
Oxidation Of Alcohols ◽  
Visible Light Driven ◽  
High Yields

A metal-free transformation of alcohols to the corresponding carbonyls in high yields under visible-light irradiation has been achieved at room temperature using di(pyridin-2-yl)-1,2,4,5-tetrazine (pytz) as catalyst.

scholarly journals Synthesis of p-Co3O4/n-TiO2 Nanoparticles for Overall Water Splitting under Visible Light Irradiation

Nanomaterials ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 138 ◽  
Author(s):  
Qiang Zhang ◽  
Zhenyin Hai ◽  
Aoqun Jian ◽  
Hongyan Xu ◽  
Chenyang Xue ◽  
...  
Keyword(s):  
Visible Light ◽  
Tio2 Nanoparticles ◽  
Water Splitting ◽  
Visible Light Irradiation ◽  
Light Irradiation ◽  
Overall Water Splitting
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