scholarly journals Development of a tubular continuous flow reactor for the investigation of improved gas–solid interaction in photocatalytic CO2 reduction on TiO2

2019 ◽  
Vol 18 (2) ◽  
pp. 314-318 ◽  
Author(s):  
Martin Dilla ◽  
Ahmet E. Becerikli ◽  
Alina Jakubowski ◽  
Robert Schlögl ◽  
Simon Ristig

Newly developed tubular reactor geometry allows intensive gas–solid interaction in photocatalytic gas-phase CO2 reduction.

2017 ◽  
Vol 4 (6) ◽  
pp. 1115-1121 ◽  
Author(s):  
Felix Rechberger ◽  
Markus Niederberger

A newly developed prototype of a flow reactor enables the exploitation of nanoparticle based aerogel monoliths as macroscopically sized photocatalysts in gas phase reactions.


RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 29872-29877 ◽  
Author(s):  
Kan-Sen Chou ◽  
Chung-Yen Hsu ◽  
Bo-Tau Liu

Silver nanowires were successfully synthesized by a polyol reduction method in a continuous-flow reactor with a yield of 2 g h−1.


2007 ◽  
Vol 2007 ◽  
pp. 1-6 ◽  
Author(s):  
Anna Kachina ◽  
Sergei Preis ◽  
German Charles Lluellas ◽  
Juha Kallas

Photocatalytic oxidation (PCO) of methylamine (MA) on titanium dioxide in aqueous and gaseous phases was studied. A simple batch glass reactor for aqueous PCO and an annular continuous flow reactor for the gas-phase PCO were used. Maximum aqueous PCO efficiency was achieved in alkaline media. Two mechanisms of aqueous PCO—decomposition to formate and ammonia, and oxidation of organic nitrogen directly to nitrite—lead ultimately toCO2, water, ammonia, and nitrate: formate and nitrite were observed as intermediates. A part of the ammonia formed in the reaction was oxidized to nitrite and nitrate. Volatile PCO products of MA included ammonia, nitrogen dioxide(NO2), nitrous oxide(N2O), carbon dioxide, and water. Thermal catalytic oxidation (TCO) resulted in the formation of ammonia, hydrogen cyanide, carbon monoxide, carbon dioxide, and water. The gas-phase PCO kinetics is described by the monomolecular Langmuir-Hinshelwood model. No deactivation ofTiO2catalyst was observed.


2018 ◽  
Vol 40 (17) ◽  
pp. 2276-2289 ◽  
Author(s):  
Eduardo Borges Lied ◽  
Camilo Freddy Mendoza Morejon ◽  
Rodrigo Leonardo de Oliveira Basso ◽  
Ana Paula Trevisan ◽  
Paulo Rodrigo Stival Bittencourt ◽  
...  

ChemCatChem ◽  
2020 ◽  
Vol 12 (21) ◽  
pp. 5420-5429
Author(s):  
Wenyu Diao ◽  
Hongyue Cai ◽  
Lu Wang ◽  
Xi Rao ◽  
Yongping Zhang

Surfaces ◽  
2019 ◽  
Vol 2 (4) ◽  
pp. 546-559 ◽  
Author(s):  
Vincenzo Vaiano ◽  
Diana Sannino

Heterogeneous photocatalysis in the gas phase has been applied as a promising technique for organic syntheses in mild conditions. Modified zeolites have been used under UV irradiation as novel photocatalysts. In this study, we preliminarily investigated the photoxidation of cyclohexane on ferrierite and MoOx-functionalized ferrierite in a gas–solid continuous flow reactor. In the presence of UV light, MoOx-functionalized ferrierite showed the formation of benzene and cyclohexene as reaction products, indicating the occurrence of photocatalysed cyclohexane oxydehydrogenation. By contrast, unmodified ammonium ferrierite exhibited relevant activity for total oxidation of cyclohexane to carbon dioxide and water. The influence of Mo loading on cyclohexane conversion and products selectivity was evaluated.


2017 ◽  
Vol 2 (2) ◽  
pp. 180-188 ◽  
Author(s):  
A. Avril ◽  
C. H. Hornung ◽  
A. Urban ◽  
D. Fraser ◽  
M. Horne ◽  
...  

Continuous flow reactor for the hydrogenation of organic substrates using novel catalytic static mixers.


Sign in / Sign up

Export Citation Format

Share Document