Bi-functional heterogeneous iron complexes for catalytic conversion of epoxides to cyclic carbonates and their application in the synthesis of polyurethane

2018 ◽  
Vol 2 (6) ◽  
pp. 1312-1322 ◽  
Author(s):  
Shailesh Verma ◽  
Mohd. Nazish ◽  
Rukhsana I. Kureshy ◽  
Noor-ul H. Khan
Keyword(s):  
Heterogeneous Catalyst ◽  
Value Added ◽  
Catalytic Conversion ◽  
Iron Complexes ◽  
Direct Conversion ◽  
Cyclic Carbonates

The development of a sustainable heterogeneous catalyst for direct conversion of CO2 to value-added chemicals is of great interest.

Efficient catalytic conversion of terminal/internal epoxides to cyclic carbonates by porous Co(ii) MOF under ambient conditions: structure–property correlation and computational studies

2019 ◽  
Vol 7 (6) ◽  
pp. 2884-2894 ◽  
Author(s):  
Bhavesh Parmar ◽  
Parth Patel ◽  
Renjith S. Pillai ◽  
Rukhsana I. Kureshy ◽  
Noor-ul H. Khan ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Catalytic Conversion ◽  
Ambient Condition ◽  
Computational Studies ◽  
Cyclic Carbonates ◽  
Structure Property ◽  
Ambient Conditions ◽  
Property Correlation

Efficient CO2 capture/utilization by Co(ii) MOF as a heterogeneous catalyst in CO2–epoxide cycloaddition at ambient condition has been investigated and correlated with computational studies.

A highly stable polyoxovanadate-based Cu(i)–MOF for the carboxylative cyclization of CO2 with propargylic alcohols at room temperature

2020 ◽  
Vol 22 (21) ◽  
pp. 7513-7520
Author(s):  
Hong-Rui Tian ◽  
Zhong Zhang ◽  
Shu-Mei Liu ◽  
Tian-Yi Dang ◽  
Zhuo Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Room Temperature ◽  
Value Added ◽  
High Catalytic Activity ◽  
Cyclic Carbonates ◽  
Propargylic Alcohols

A POVs-based Cu(i)–MOF was synthesized and utilized as a heterogeneous catalyst for the cyclization of CO2 with propargylic alcohols to obtain value-added α-alkylidene cyclic carbonates, exhibiting high catalytic activity and sustainability.

Catalytic conversion of CO2: Electrochemically to ethanol and thermochemically to cyclic carbonates using nanoporous polytriazine

2021 ◽  
Vol 52 ◽  
pp. 101676
Author(s):  
Ruchi Sharma ◽  
Monika Chaudhary ◽  
Akansha Pandey ◽  
Prakash Biswas ◽  
Paritosh Mohanty
Keyword(s):  
Catalytic Conversion ◽  
Cyclic Carbonates

Hydrogen bond donor functionalized poly(ionic liquid)s for efficient synergistic conversion of CO2 to cyclic carbonates

2020 ◽  
Author(s):  
Haibin Gou ◽  
Xifei Ma ◽  
Qian Su ◽  
Lei Liu ◽  
Ting Ying ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquid ◽  
Value Added ◽  
Pivotal Role ◽  
Cyclic Carbonates ◽  
Hydrogen Bond Donor ◽  
Metal Free ◽  
Recyclable Catalysts ◽  
Poly Ionic Liquid ◽  
Value Added Products

The development of metal-free, high effective and recyclable catalysts plays a pivotal role in transforming CO2 into high value-added products such as cyclic carbonates. In this paper, we have introduced...

Direct conversion of cellulose to high-yield methyl lactate over Ga-doped Zn/H-nanozeolite Y catalysts in supercritical methanol

2017 ◽  
Vol 19 (8) ◽  
pp. 1969-1982 ◽  
Author(s):  
Deepak Verma ◽  
Rizki Insyani ◽  
Young-Woong Suh ◽  
Seung Min Kim ◽  
Seok Ki Kim ◽  
...  
Keyword(s):  
Lignocellulosic Biomass ◽  
Value Added ◽  
Direct Conversion ◽  
High Yield ◽  
Supercritical Methanol ◽  
Methyl Lactate ◽  
High Yields

For realizing sustainable bio-based refineries, it is crucial to obtain high yields of value-added chemicalsviadirect conversion of cellulose and lignocellulosic biomass.

scholarly journals Recent Advances in Catalytic Conversion of Biomass to 2,5-Furandicarboxylic Acid

Catalysts ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1113
Author(s):  
Hanyu Cong ◽  
Haibo Yuan ◽  
Zekun Tao ◽  
Hanlin Bao ◽  
Zheming Zhang ◽  
...  
Keyword(s):  
Terephthalic Acid ◽  
Fossil Fuel ◽  
Value Added ◽  
Catalytic Conversion ◽  
Future Research ◽  
Research Directions ◽  
Biodegradable Polyesters ◽  
Fuels And Chemicals ◽  
Future Research Directions ◽  
Furandicarboxylic Acid

Converting biomass into high value-added compounds has attracted great attention for solving fossil fuel consumption and global warming. 5-Hydroxymethylfurfural (HMF) has been considered as a versatile biomass-derived building block that can be used to synthesize a variety of sustainable fuels and chemicals. Among these derivatives, 2,5-furandicarboxylic acid (FDCA) is a desirable alternative to petroleum-derived terephthalic acid for the synthesis of biodegradable polyesters. Herein, to fully understand the current development of the catalytic conversion of biomass to FDCA, a comprehensive review of the catalytic conversion of cellulose biomass to HMF and the oxidation of HMF to FDCA is presented. Moreover, future research directions and general trends of using biomass for FDCA production are also proposed.

Synthesis of cyclic organic carbonates via catalytic oxidative carboxylation of olefins in flow reactors

2017 ◽  
Vol 7 (1) ◽  
pp. 84-89 ◽  
Author(s):  
Ajay A. Sathe ◽  
Anirudh M. K. Nambiar ◽  
Robert M. Rioux
Keyword(s):  
Carbon Dioxide ◽  
Continuous Flow ◽  
Catalytic Conversion ◽  
Cyclic Carbonates ◽  
Flow Reactors ◽  
Organic Carbonates ◽  
Continuous Flow Reactors

The direct catalytic conversion of olefins into cyclic carbonates using peroxide and carbon dioxide is demonstrated using continuous flow reactors.

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