A bright red-emitting flavonoid for Al3+ detection in live cells without quenching ICT fluorescence

2019 ◽  
Vol 55 (49) ◽  
pp. 7041-7044 ◽  
Author(s):  
Chathura S. Abeywickrama ◽  
Keti A. Bertman ◽  
Yi Pang
Keyword(s):  
Stokes Shift ◽  
Live Cells ◽  
Quantum Yields ◽  
Large Stokes Shift ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence

A bright red-emitting flavonoid derivative was synthesized, which exhibited a large Stokes shift (Δλ > 150 nm) and high fluorescence quantum yields (ϕfl = 0.10–0.35).

Red-emitting boron difluoride complexes with a mega-large Stokes shift and unexpectedly high fluorescence quantum yield

2020 ◽  
Vol 56 (14) ◽  
pp. 2159-2162 ◽  
Author(s):  
Xiaojie Ren ◽  
Fan Zhang ◽  
Hongchen Luo ◽  
Lide Liao ◽  
Xiangzhi Song ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Stokes Shift ◽  
Quantum Yields ◽  
Large Stokes Shift ◽  
Fluorescence Quantum Yields ◽  
Boron Difluoride ◽  
High Fluorescence ◽  
Stokes Shifts ◽  
High Fluorescence Quantum Yield

Introduction of a tetrahydroquinoxaline donor into boron difluoride complexes largely extended their emissions (617–684 nm), highly improved their fluorescence quantum yields (up to 0.68) and greatly increased their Stokes shifts (up to 209 nm).

Regioselective Oxidative Cross-Coupling Reaction: Synthesis of Imidazo[1,2-a]pyridine Fluorophores

Synthesis ◽  
2021 ◽  
Author(s):  
Xianglong Chu ◽  
Yadi Niu ◽  
Chen Ma ◽  
Xiaodong Wang ◽  
Yunliang Lin ◽  
...  
Keyword(s):  
Photophysical Properties ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
Cross Coupling Reaction ◽  
Color Tunable ◽  
Palladium Catalyzed ◽  
Structure Relationship ◽  
High Fluorescence

AbstractA rapid access to a series of N-heteroarene fluorophores has been developed on the basis of the palladium-catalyzed direct oxidative C–H/C–H coupling of imidazo[1,2-a]pyridines with thiophenes/furans. The photophysical properties–structure relationship was systematically investigated. The resulting N-heteroarene fluorophores present color-tunable emissions (λem: 431–507 nm in CH2Cl2) and high fluorescence quantum yields (up to 91% in CH2Cl2).

scholarly journals Photoluminescence in m-carborane–anthracene triads: a combined experimental and computational study

2018 ◽  
Vol 6 (42) ◽  
pp. 11336-11347 ◽  
Author(s):  
Mahdi Chaari ◽  
Zsolt Kelemen ◽  
José Giner Planas ◽  
Francesc Teixidor ◽  
Duane Choquesillo-Lazarte ◽  
...  
Keyword(s):  
Computational Study ◽  
Fluorescence Emission ◽  
Fluorescence Properties ◽  
Quantum Yields ◽  
Aggregate State ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence

m-Carborane has demonstrated to be a perfect platform to boost the fluorescence properties of anthracene, giving rise to high fluorescence quantum yields in solution and also retaining fluorescence emission in the aggregate state.

A dual-emission and large Stokes shift fluorescence probe for real-time discrimination of ROS/RNS and imaging in live cells

2013 ◽  
Vol 49 (18) ◽  
pp. 1862 ◽  
Author(s):  
Ting Guo ◽  
Lei Cui ◽  
Jiaoning Shen ◽  
Rui Wang ◽  
Weiping Zhu ◽  
...  
Keyword(s):  
Real Time ◽  
Fluorescence Probe ◽  
Stokes Shift ◽  
Live Cells ◽  
Dual Emission ◽  
Large Stokes Shift ◽  
Time Discrimination

Alkynylpyrenes as Improved Pyrene-Based Biomolecular Probes with the Advantages of High Fluorescence Quantum Yields and Long Absorption/Emission Wavelengths

2006 ◽  
Vol 12 (3) ◽  
pp. 824-831 ◽  
Author(s):  
Hajime Maeda ◽  
Tomohiro Maeda ◽  
Kazuhiko Mizuno ◽  
Kazuhisa Fujimoto ◽  
Hisao Shimizu ◽  
...  
Keyword(s):  
Quantum Yields ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence

SYNTHESIS, FLUORESCENCE AND ELECTROCHEMICAL PROPERTIES OF SYMMETRICAL CHROMOPHORES WITH ELECTRON ACCEPTING OXADIAZOLE

2008 ◽  
Vol 17 (04) ◽  
pp. 473-485 ◽  
Author(s):  
XIAOQIN ZHU ◽  
YING QIAN ◽  
WEI HUANG ◽  
CHANGGUI LU ◽  
YIPING CUI
Keyword(s):  
Single Photon ◽  
Quantum Yields ◽  
Compound I ◽  
Central Wavelength ◽  
Good Thermal Stability ◽  
Fluorescence Quantum Yields ◽  
Two Photon ◽  
Homo And Lumo ◽  
High Fluorescence ◽  
Compound Ii

Two symmetrical TPA chromophores containing 1,3,4-oxadiazole group were designed and synthesized through the Wittig–Horner reaction. All compounds were characterized by NMR, IR, UV and melting point. Chromophore I and II showed good thermal stability and did lose less than 5% weight on heating to about 300°C. The electrochemical property was explored by cyclic voltammetry. The HOMO and LUMO energy of compound I were estimated to be -3.65 eV and -1.09 eV. That of compound II were -3.69 eV and -1.10 eV. Both chromophores exhibited a positive solvatochromic behavior. In CH2Cl2 , the maximum peaks of single-photon-excited fluorescence (SPEF) were at 512 nm for compound I and at 495 nm for compound II with high fluorescence quantum yields 0.73 and 0.70, respectively. The two-photon-excited fluorescence (TPEF) had also been investigated. Pumped by femtosecond laser at 800 nm, strong up-conversion emissions with the central wavelength were at 532 nm for compound I and 550 nm for compound II in the solution of CH2Cl2 .

High-Quality Water-Soluble Core/Shell/Shell CdSe/CdS/ZnS Quantum Dots Balanced by Ionic and Nonionic Hydrophilic Capping Ligands

NANO ◽  
2016 ◽  
Vol 11 (07) ◽  
pp. 1650073 ◽  
Author(s):  
Lu Liu ◽  
Hu Xu ◽  
Bing Shen ◽  
Xinhua Zhong
Keyword(s):  
Quantum Dots ◽  
Colloidal Stability ◽  
Water Soluble ◽  
Quantum Yields ◽  
Surface Charges ◽  
Fluorescence Quantum Yields ◽  
Carboxylic Groups ◽  
Potential Applications ◽  
High Fluorescence ◽  
Capping Ligands

Pentaerythritol tetrakis 3-mercaptopropionate (PTMP) grafted poly(acryl acid) (PAA) ionic hydrophilic oligomer PAA-PTMP (PP) and dihydrolipoic acid (DHLA) grafted methoxypoly(ethylene glycol) (mPEG) nonionic hydrophilic oligomer mPEG-DHLA (PD) have been designed, synthesized and used as co-capping ligands in water-solubilization of hydrophobic quantum dots (QDs) via ligand exchange. The obtained oligomers with multi-thiol groups could bind strongly to the surface atoms of QDs. Meanwhile, the carboxyl groups (from PP) and mPEG segment (from PD) can render QDs water-soluble, and the free carboxylic groups can possibly be used for the further bioconjugation. The resulting water-soluble QDs have been characterized by ultraviolet-visible (UV-Vis), fluorescence, Fourier transform infrared (FTIR) spectroscopy as well as transmission electron microscopy (TEM) and dynamic light scattering (DLS) techniques. The water-soluble QDs have relatively small hydrodynamic size (10[Formula: see text]12 nm), and importantly, retain high fluorescence quantum yields (up to 45%) compared with that of the originally hydrophobic QDs (49%). In addition, they have tunable surface charges and show excellent colloidal stability over a relatively broad pH range ([Formula: see text]), in high salt concentration, and even after thermal treatment at 100[Formula: see text]C. These results indicate that the water-soluble QDs coated by PP and PD oligomers have potential applications in cellular imaging and biosensor.

scholarly journals Towards Mycobacterium tuberculosis detection at the point-of-care: a brighter solvatochromic probe permits the detection of mycobacteria within minutes

2020 ◽  
Author(s):  
Mireille Kamariza ◽  
Samantha G. L. Keyser ◽  
Ashley Utz ◽  
Benjamin D. Knapp ◽  
Green Ahn ◽  
...  
Keyword(s):  
Mycobacterium Tuberculosis ◽  
Fluorescence Intensity ◽  
Point Of Care ◽  
Fold Increase ◽  
Diagnostic Methods ◽  
Quantum Yields ◽  
Low Resource Settings ◽  
Fluorescence Quantum Yields ◽  
High Fluorescence ◽  
Solvatochromic Dye

ABSTRACTThere is an urgent need for point-of-care tuberculosis (TB) diagnostic methods that are fast, inexpensive, and operationally simple. Here, we report on a bright solvatochromic dye trehalose conjugate that specifically detects Mycobacterium tuberculosis (Mtb) in minutes. 3-hydroxychromone (3HC) dyes, known to yield high fluorescence quantum yields, exhibit shifts in fluorescence intensity in response to changes in environmental polarity. We synthesized two analogs of 3HC-trehalose conjugates (3HC-2-Tre and 3HC-3-Tre) and determined that 3HC-3-Tre has exceptionally favorable properties for Mtb detection. 3HC-3-Tre-labeled mycobacterial cells displayed a 10-fold increase in fluorescence intensity compared to our previously reports on the dye 4,4-N,N-dimethylaminonapthalimide (DMN-Tre). Excitingly, we detected fluorescent Mtb cells within 10 minutes of probe treatment. Thus, 3HC-3-Tre permits rapid visualization of mycobacteria that ultimately could empower improved Mtb detection at the point-of-care in low-resource settings.

A naphthalene-based fluorescent probe with a large Stokes shift for mitochondrial pH imaging

The Analyst ◽  
2018 ◽  
Vol 143 (20) ◽  
pp. 5054-5060 ◽  
Author(s):  
Bo Lin ◽  
Li Fan ◽  
Jinyin Ge ◽  
Wenjia Zhang ◽  
Caihong Zhang ◽  
...  
Keyword(s):  
Fluorescent Probe ◽  
Stokes Shift ◽  
Live Cells ◽  
Ph Changes ◽  
Large Stokes Shift ◽  
Ph Probe ◽  
Ph Imaging

A naphthalene-based fluorescent pH probe with a pKa of 8.8 for imaging mitochondrial pH changes in live cells.

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