Optimization of the facet structure of cobalt oxide catalysts for enhanced hydrogen evolution reaction

2020 ◽  
Vol 10 (4) ◽  
pp. 1040-1047 ◽  
Author(s):  
Minghong Wu ◽  
Shuqiang Ke ◽  
Wenqian Chen ◽  
Shaomei Zhang ◽  
Min Zhu ◽  
...  

The three different exposed crystal planes of Co3O4 catalysts, in which the {112} and {011} planes with abundant Co3+ sites exhibited photocatalytic hydrogen evolution activity superior to that of the {001} plane.

Author(s):  
Xiaoqiang Zhan ◽  
Zhi Fang ◽  
Bing Li ◽  
Haitao Zhang ◽  
Leyao Xu ◽  
...  

Highly-active heterojunctions hold the pivotal function in photocatalytic hydrogen evolution reaction (HER). Herein, Ta3N5@ReS2 photocatalysts are rationally designed via the combination of template-assisted, hydrothermal and solution-adsorption processes, in which few...


Materials ◽  
2019 ◽  
Vol 12 (8) ◽  
pp. 1302 ◽  
Author(s):  
Jhony Xavier Flores-Lasluisa ◽  
Javier Quílez-Bermejo ◽  
Ana Cristina Ramírez-Pérez ◽  
Francisco Huerta ◽  
Diego Cazorla-Amorós ◽  
...  

The development of electrocatalysts based on the doping of copper over cobalt spinel supported on a microporous activated carbon has been studied. Both copper–cobalt and cobalt spinel nanoparticles were synthesized using a silica-template method. Hybrid materials consisting of an activated carbon (AC), cobalt oxide (Co3O4), and copper-doped cobalt oxide (CuCo2O4) nanoparticles, were obtained by dry mixing technique and evaluated as electrocatalysts in alkaline media for hydrogen evolution reaction. Physical mixtures containing 5, 10, and 20 wt.% of Co3O4 or CuCo2O4 with a highly microporous activated carbon were prepared and characterized by XRD, TEM, XPS, physical adsorption of gases, and electrochemical techniques. The electrochemical tests revealed that the electrodes containing copper as the dopant cation result in a lower overpotential and higher current density for the hydrogen evolution reaction.


2020 ◽  
Vol 486 ◽  
pp. 110850 ◽  
Author(s):  
Thang Phan Nguyen ◽  
Dinh Minh Tuan Nguyen ◽  
Dai Lam Tran ◽  
Hai Khoa Le ◽  
Dai-Viet N. Vo ◽  
...  

2019 ◽  
Vol 7 (9) ◽  
pp. 4797-4803 ◽  
Author(s):  
Aijie Liu ◽  
Cheuk-Wai Tai ◽  
Kateřina Holá ◽  
Haining Tian

Mimicking nature is always beneficial for improving the performance of artificial systems.


2019 ◽  
Vol 55 (71) ◽  
pp. 10631-10634 ◽  
Author(s):  
Shixiong Min ◽  
Yuan Xue ◽  
Fang Wang ◽  
Zhengguo Zhang ◽  
Haitao Zhu

In situ grown Pt NPs on Ti3C2Tx NSs show ∼30 times higher H2 evolution activity than free Pt NPs and an AQY of 5.81% at 520 nm in an ErB–TEOA system.


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