scholarly journals Towards stable and efficient electrolytes for room-temperature rechargeable calcium batteries

2019 ◽  
Vol 12 (12) ◽  
pp. 3496-3501 ◽  
Author(s):  
Zhenyou Li ◽  
Olaf Fuhr ◽  
Maximilian Fichtner ◽  
Zhirong Zhao-Karger
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
High Ionic Conductivity ◽  
Electrochemical Window

A novel Ca electrolyte with a broad electrochemical window and high ionic conductivity is demonstrated.

Multi-variable Bayesian optimization for a new composition with high Na+ conductivity in the Na3PS4 family

2022 ◽  
Author(s):  
Jung Yong Seo ◽  
Sunggeun Shim ◽  
Jin-Woong Lee ◽  
Byung Do Lee ◽  
Sangwon Park ◽  
...  
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Room Temperature ◽  
High Ionic Conductivity ◽  
Bayesian Optimization ◽  
Solid State Electrolyte ◽  
Aliovalent Substitution

Na3PS4 is an archetypal room-temperature (RT), Na+-conducting, solid-state electrolyte. Various compositional modifications of this compound via iso/aliovalent substitution are known to provide a high ionic conductivity (ion) that is comparable...

Materials for All-Solid-State Lithium Ion Batteries

2013 ◽  
Vol 1496 ◽  
Author(s):  
Sumaletha Narayanan ◽  
Lina Truong ◽  
Venkataraman Thangadurai
Keyword(s):  
Ionic Conductivity ◽  
Chemical Stability ◽  
Room Temperature ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
High Ionic Conductivity ◽  
Li Ion Batteries ◽  
Li Battery ◽  
Li Ion ◽  
Very High

ABSTRACTGarnet-type electrolytes are currently receiving much attention for applications in Li-ion batteries, as they possess high ionic conductivity and chemical stability. Doping the garnet structure has proved to be a good way to improve the Li ion conductivity and stability. The present study includes effects of Y- doping in Li5La3Nb2O12 on Li ion conductivity and stability of “Li5+2xLa3Nb2-xYxO12” (0.05 ≤ x ≤ 0.75) under various environments, as well as chemical stability studies of Li5+xBaxLa3-xM2O12 (M = Nb, Ta) in water. “Li6.5La3Nb1.25Y0.75O12” showed a very high ionic conductivity of 2.7 х 10−4 Scm−1 at 25 °C, which is comparable to the highest value reported for garnet-type compounds, e.g., Li7La3Zr2O12. The selected members show very good stability against high temperatures, water, Li battery cathode Li2CoMn3O8 and carbon. The Li5+xBaxLa3-xNb2O12 garnets have shown to readily undergo an ion-exchange (proton) reaction under water treatment at room temperature; however, the Ta-based garnet appears to exhibit considerably higher stability under the same conditions.

Intercalated hybrid of kaolinite with KH 2 PO 4 showing high ionic conductivity (∼10 −4  S cm −1 ) at room temperature

2017 ◽  
Vol 74 ◽  
pp. 95-100 ◽  
Author(s):  
Shao-Xian Liu ◽  
Chen Xue ◽  
Hao Yang ◽  
Xiao-Qing Huang ◽  
Yang Zou ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Room Temperature ◽  
High Ionic Conductivity

scholarly journals An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6946
Author(s):  
Bin Zhao ◽  
Qi Wang ◽  
Boheng Yuan ◽  
Yafei Lu ◽  
Xiaogang Han
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Glass Fiber ◽  
Room Temperature ◽  
Specific Capacity ◽  
High Ionic Conductivity ◽  
Plastic Crystal ◽  
Metal Anode ◽  
Solid State Battery ◽  
Interface Contact

Solid-state plastic crystal electrolytes (SPCEs) have attracted much attention due to their high ionic conductivity at room temperature and polymer-like plasticity. Herein, we made a LiFePO4||Li solid state battery based on SPCEs. A SPCE film is made up of glass fiber, succinonitrile (SN), lithium bis (triflu-romethanesulphonyl) imid (LiTFSI), and LiNO3. Glass fiber is introduced to improve the mechanical property, and LiNO3 served as an additive to stabilize electrolyte/Li interface. The SPCE film delivers a high ionic conductivity of 7.3 × 10−4 S cm−1 at room temperature and has excellent stability with Li-metal anode. SPCE is also infused into cathode electrode and used as the interface with cathode particles, which can access a large interface contact area and deform reversibly with volume change. The LiFePO4||Li solid state battery based on SPCE can work well at ambient temperature, which shows a high initial specific capacity of 121.4 mAh g−1 and has 86.9% retention after 90 cycles at 0.5 C.

Solvothermal synthesis high lithium ionic conductivity of Gd-doped Li1.3 Al0.3Ti1.7(PO4)3 solid electrolyte

2021 ◽  
pp. 2140002
Author(s):  
Mingxia Fan ◽  
Xiangyu Deng ◽  
Anqiao Zheng ◽  
Songdong Yuan
Keyword(s):  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Room Temperature ◽  
Lithium Ion ◽  
High Ionic Conductivity ◽  
Doping Content ◽  
First Time ◽  
Maximum Content ◽  
Material Price

NASICON-type Li[Formula: see text]Al[Formula: see text]Ti[Formula: see text](PO[Formula: see text] (LATP) solid electrolytes have been widely studied because of its stability in the air, low material price and high ionic conductivity. Gd-doped Li[Formula: see text]Al[Formula: see text]Gd[Formula: see text]Ti[Formula: see text](PO[Formula: see text] ([Formula: see text]= 0, 0.025, 0.05, 0.075 and 0.1) with high ionic conductivity was successfully synthesized by solvothermal method for the first time in this work. The effect of Gd doping content on the structure and electrochemical performance of solid electrolytes was systematically studied. The optimal doping content of Gd is [Formula: see text]= 0.075. With the Gd doping content of 0.075, the solid electrolyte has the highest ionic conductivity of 4.23 × 10[Formula: see text] S cm[Formula: see text] at room temperature, the lowest activation energy of 0.247 eV and the highest relative density of 94.89%. This is because the fact that when [Formula: see text]= 0.075, it is the maximum content of Gd[Formula: see text] to replace Al[Formula: see text] and can completely enter the lattice of LATP, and does not emerge too much non-lithium ion conductive GdPO4 phase.

High Ionic Conductivity of Polymer Complexes Formed by Polypyridinium, Pyridinium, and Aluminium Chloride

1992 ◽  
Vol 293 ◽  
Author(s):  
Masahiro Rikukawa ◽  
Shinichiro Yamada ◽  
Kohei Sanui ◽  
Naoya Ogata ◽  
Masayoshi Watanabe
Keyword(s):  
Ionic Conductivity ◽  
Molten Salts ◽  
Room Temperature ◽  
Conductive Polymer ◽  
Ionic Conductivities ◽  
High Ionic Conductivity ◽  
Aluminium Chloride ◽  
Polymer Complexes

AbstractNew ion conductive polymer complexes were formed by dissolving poly(1-butyl-4- vinylpyridinium) salts into room temperature molten salts consisting of 1-butylpyridinium salts and aluminium chloride. The viscoelastic films were fabricated from the molten salts added at least 10 mol % of the polypyridinium salts. The ionic conductivities of the polymer complexes were in the range of 10−3−10−4 Scm−1 at room temperature and were affected by their composition.

Montmorillonite (MONT) Complex and their Application

1990 ◽  
Vol 210 ◽  
Author(s):  
Yu Wenhai ◽  
Liu Wanyu
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
Room Temperature ◽  
Ionic Conduction ◽  
Electric Properties ◽  
High Ionic Conductivity ◽  
Polymer Complex ◽  
Solid State Battery ◽  
New Type

AbstractMontmorillonite(Mont) has been proved to be a kind of very promising solid electrolyte in recent years because of its good electric properties. It can be composed by polymer to prepare a mont-polymer complex which has high ionic conductivity and excellent plasticity. The film made of mont-polymer complex with room temperature ionic conduction has been used in solid state battery as solid electrolyte. It may be a new type of function material with futher application.

Electromagnetic Drive of Room-Temperature Ionic Liquids and Application

2012 ◽  
Vol 189 ◽  
pp. 374-378 ◽  
Author(s):  
Jing Wan ◽  
Chong Cheng Liang ◽  
Feng Yan ◽  
Ke Gu ◽  
Shuai Zhang ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Ionic Conductivity ◽  
Room Temperature ◽  
Room Temperature Ionic Liquids ◽  
Magnetic Flux Density ◽  
Electromagnetic Drive ◽  
Electrochemical Window ◽  
Bottle Neck ◽  
Theory And Experiments ◽  
Liquid Pump

Room-temperature ionic liquids are new emerging green material. They have good chemical and thermal stability, negligible vapor pressure, nonflammability, high ionic conductivity, transparence, and a wide electrochemical window. So the ionic liquid material strongly tempts many researchers. But ionic liquids are usually applied in chemistry and rarely applied in physics. In fact ionic liquids are good photoelectric medium material owing to its well ionic conductivity, transparence. However, in applications, the drive of ionic liquids is the key technic and is also a bottle-neck. Here a kind of electromagnetic drive way is presented, There are not any mechanical moving elements and the drive is bidirectional. Theory and experiments indicate the drive pressure and flow rate are distinct undering a few voltages and 0.5T magnetic flux density. So this drive way can be used as a low power liquid pump. Latency applications in Microfluidics, Optoelectronics and industry are given.

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