Pyridine as a trigger in transformation chemistry from Au144(SR)60 to aromatic thiolate-ligated gold clusters

Nanoscale ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 4982-4987 ◽  
Author(s):  
Quanquan Shi ◽  
Zhaoxian Qin ◽  
Changlin Yu ◽  
Shuang Liu ◽  
Hui Xu ◽  
...  

Transformation chemistry is a systematic methodology for achieving new atomically precise gold nanoclusters with specific physical and chemical properties.

2017 ◽  
Vol 5 (28) ◽  
pp. 5608-5615 ◽  
Author(s):  
Jianqiao Zhang ◽  
Chen Cai ◽  
Shumaila Razzaque ◽  
Irshad Hussain ◽  
Qun-Wei Lu ◽  
...  

Gold nanoclusters are used as excellent scaffolds for the development of chemical and biological sensors due to their outstanding physical and chemical properties.


Molecules ◽  
2019 ◽  
Vol 24 (17) ◽  
pp. 3045 ◽  
Author(s):  
Zhi He ◽  
Tong Shu ◽  
Lei Su ◽  
Xueji Zhang

Recent booming advances in luminescent gold nanoclusters (AuNCs), have prompted the development of novel fluorescent sensors. The luminescent AuNCs possess unique and intriguing physical and chemical properties including responsive photoluminescence and peroxide-like activity, providing abundant potentials for sensing strategy design. As of now, a wide variety of chem-/bio-sensors based on AuNCs have been developed and reviewed according to varied analytes. In this review, from a different point of view, we follow the route of how those sensors realize their functions and focus on the actual roles AuNCs play, in order to hierarchically and logically display the recent progress in the sensing applications of AuNCs. This review not only opens new windows to understand the development of sensors based on AuNCs but can also inspire broader and deeper utilization of luminescent nanomaterials.


1966 ◽  
Vol 24 ◽  
pp. 101-110
Author(s):  
W. Iwanowska

In connection with the spectrophotometric study of population-type characteristics of various kinds of stars, a statistical analysis of kinematical and distribution parameters of the same stars is performed at the Toruń Observatory. This has a twofold purpose: first, to provide a practical guide in selecting stars for observing programmes, second, to contribute to the understanding of relations existing between the physical and chemical properties of stars and their kinematics and distribution in the Galaxy.


2017 ◽  
pp. 31-43
Author(s):  
Berta Ratilla ◽  
Loreme Cagande ◽  
Othello Capuno

Organic farming is one of the management strategies that improve productivity of marginal uplands. The study aimed to: (1) evaluate effects of various organic-based fertilizers on the growth and yield of corn; (2) determine the appropriate combination for optimum yield; and (3) assess changes on the soil physical and chemical properties. Experiment was laid out in Randomized Complete Block Design, with 3 replications and 7 treatments, namely; T0=(0-0-0); T1=1t ha-1 Evans + 45-30-30kg N, P2O5, K2O ha-1; T2=t ha-1 Wellgrow + 45-30-30kg N, P2O5, K2O ha-1; T3=15t ha-1 chicken dung; T4=10t ha-1 chicken dung + 45-30-30kg N, P2O5, K2O ha-1; T5=15t ha-1 Vermicast; and T6=10t ha-1 Vermicast + 45-30-30kg N, P2O5, K2O ha-1. Application of organic-based fertilizers with or without inorganic fertilizers promoted growth of corn than the control. But due to high infestation of corn silk beetle(Monolepta bifasciata Horns), its grain yield was greatly affected. In the second cropping, except for Evans, any of these fertilizers applied alone or combined with 45-30-30kg N, P2O5, K2O ha-1 appeared appropriate in increasing corn earyield. Soil physical and chemical properties changed with addition of organic fertilizers. While bulk density decreased irrespective of treatments, pH, total N, available P and exchangeable K generally increased more with chicken dung application.


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