A Review: Ion Transport of Two-Dimensional Materials in Novel Technologies from Macro to Nanoscopic Perspectives

Ion transport is a significant concept that underlies a variety of technologies including membrane technology, energy storages, optical, chemical, and biological sensors and ion-mobility exploration techniques. These applications are based on the concepts of capacitance and ion transport, so a prior understanding of capacitance and ion transport phenomena is crucial. In this review, the principles of capacitance and ion transport are described from a theoretical and practical point of view. The review covers the concepts of Helmholtz capacitance, diffuse layer capacitance and space charge capacitance, which is also referred to as quantum capacitance in low-dimensional materials. These concepts are attributed to applications in the electrochemical technologies such as energy storage and excitable ion sieving in membranes. This review also focuses on the characteristic role of channel heights (from micrometer to angstrom scales) in ion transport. Ion transport technologies can also be used in newer applications including biological sensors and multifunctional microsupercapacitors. This review improves our understanding of ion transport phenomena and demonstrates various applications that is applicable of the continued development in the technologies described.

Enzymatic enhancing of triplet–triplet annihilation upconversion by breaking oxygen quenching for background-free biological sensing

Triplet-triplet annihilation upconversion nanoparticles have attracted considerable interest due to their promises in organic chemistry, solar energy harvesting and several biological applications. However, triplet-triplet annihilation upconversion in aqueous solutions is challenging due to sensitivity to oxygen, hindering its biological applications under ambient atmosphere. Herein, we report a simple enzymatic strategy to overcome oxygen-induced triplet-triplet annihilation upconversion quenching. This strategy stems from a glucose oxidase catalyzed glucose oxidation reaction, which enables rapid oxygen depletion to turn on upconversion in the aqueous solution. Furthermore, self-standing upconversion biological sensors of such nanoparticles are developed to detect glucose and measure the activity of enzymes related to glucose metabolism in a highly specific, sensitive and background-free manner. This study not only overcomes the key roadblock for applications of triplet-triplet annihilation upconversion nanoparticles in aqueous solutions, it also establishes the proof-of-concept to develop triplet-triplet annihilation upconversion nanoparticles as background free self-standing biological sensors.

Carbon Nanotube Field-Effect Transistor-Based Chemical and Biological Sensors

Chemical and biological sensors have attracted great interest due to their importance in applications of healthcare, food quality monitoring, environmental monitoring, etc. Carbon nanotube (CNT)-based field-effect transistors (FETs) are novel sensing device configurations and are very promising for their potential to drive many technological advancements in this field due to the extraordinary electrical properties of CNTs. This review focuses on the implementation of CNT-based FETs (CNTFETs) in chemical and biological sensors. It begins with the introduction of properties, and surface functionalization of CNTs for sensing. Then, configurations and sensing mechanisms for CNT FETs are introduced. Next, recent progresses of CNTFET-based chemical sensors, and biological sensors are summarized. Finally, we end the review with an overview about the current application status and the remaining challenges for the CNTFET-based chemical and biological sensors.

Exploring the use of upconversion nanoparticles in chemical and biological sensors: from surface modifications to point-of-care devices

Upconversion nanoparticles (UCNPs) have emerged as promising luminescent nanomaterials due to their unique features that allow the overcoming of several problems associated with conventional fluorescent probes. Although the UCNPs have...

The Solid-State Emission of Bilirubin

<p>Bilirubin (BR) is a human-biological compound formed during the haem metabolism that is insoluble in most solvents. BR has shown short emission lifetime with low quantum yield in limited number of solvents, due to the non-radiative ultrafast isomerization process. However, in solid-state, red-shifted emission of long-lived species of BR are detected at room temperature, due to the aggregation-induced emission formed by Frenkel exciton of J-system. This solid-state emission of BR depends on the crystal quality of BR as shown by SEM and XRD. This study allows for better understandings of the photophysics of BR in solid-state, opening opportunities for its applications in luminescent biological sensors. </p>