scholarly journals Synthesis of highly effective stabilized CaO sorbents via a sacrificial N-doped carbon nanosheet template

2019 ◽  
Vol 7 (15) ◽  
pp. 9173-9182 ◽  
Author(s):  
Ke Wang ◽  
Peter T. Clough ◽  
Pengfei Zhao ◽  
Edward J. Anthony

Highly macroporous MgO-stabilized CaO nanosheets with rapid reaction rates, high capacity, and good stability for high-temperature CO2 capture.

2019 ◽  
Vol 15 (4) ◽  
pp. 308-317
Author(s):  
Mei Ling Ng ◽  
Zaidah binti Rahmat ◽  
Mohd Shahir Shamsir bin Omar

Background: Orthosiphon stamineus is a traditional medicinal plant in Southeast Asia countries with various well-known pharmacological activities such as antidiabetic, diuretics and antitumor activities. Transketolase is one of the proteins identified in the leaves of the plant and transketolase is believed able to lower blood sugar level in human through non-pancreatic mechanism. In order to understand the protein behavioral properties, 3D model of transketolase and analysis of protein structure are of obvious interest. Methods: In the present study, 3D model of transketolase was constructed and its atomic characteristics revealed. Besides, molecular dynamic simulation of the protein at 310 K and 368 K deciphered transketolase may be a thermophilic protein as the structure does not distort even at elevated temperature. This study also used the protein at 310 K and 368 K resimulated back at 310 K environment. Results: The results revealed that the protein is stable at all condition which suggest that it has high capacity to adapt at different environment not only at high temperature but also from high temperature condition to low temperature where the structure remains unchanged while retaining protein function. Conclusion: The thermostability properties of transketolase is beneficial for pharmaceutical industries as most of the drug making processes are at high temperature condition.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Takahiro Kozawa ◽  
Kayo Fukuyama ◽  
Kizuku Kushimoto ◽  
Shingo Ishihara ◽  
Junya Kano ◽  
...  

AbstractMechanochemical reactions can be induced in a solution by the collision of balls to produce high-temperature and high-pressure zones, with the reactions occurring through a dissolution–precipitation mechanism due to a change in solubility. However, only a fraction of the impact energy contributes to the mechanochemical reactions, while the rest is mainly consumed by the wear of balls and the heat generation. To clarify whether the normal or tangential component of collisions makes a larger contribution on the reaction, herein we studied the effect of collision direction on a wet mechanochemical reaction through combined analysis of the experimental reaction rates and simulated ball motion. Collisions of balls in the normal direction were found to contribute strongly to the wet mechanochemical reaction. These results could be used to improve the synthesis efficiency, predict the reaction, and lower the wear in the wet mechanochemical reactions.


RSC Advances ◽  
2015 ◽  
Vol 5 (51) ◽  
pp. 40899-40906 ◽  
Author(s):  
Yanting Chu ◽  
Jinkui Feng ◽  
Yitai Qian ◽  
Shenglin Xiong

Co3O4@a-TiO2 structures have been realized by adjusting the solvent ratio. The excellent electrochemical activity of the composite is due to the good stability of TiO2 shell, high capacity of Co3O4 core, and the optimized porous size.


2021 ◽  
Author(s):  
Frank Figueroa ◽  
Gustavo Mejías ◽  
José Frías ◽  
Bonifacio Brito ◽  
Diana Velázquez ◽  
...  

Abstract Enhanced hydrocarbon production in a high-pressure/high-temperature (HP/HT) carbonate reservoir, involves generating highly conductive channels using efficient diversion techniques and custom-designed acid-based fluid systems. Advanced stimulation design includes injection of different reactive fluids, which involves challenges associated with controlling fluid leak-off, implementing optimal diversion techniques, controlling acid reaction rates to withstand high-temperature conditions, and designing appropriate pumping schedules to increase well productivity and sustainability of its production through efficient acid etching and uniform fluid distribution in the pay zone. Laboratory tests such as rock mineralogy, acid etching on core samples and solubility tests on formation cuttings were performed to confirm rock dissolving capability, and to identify stimulation fluids that could generate optimal fracture lengths and maximus etching in the zone of interest while corrosion test was run to ensure corrosion control at HT conditions. After analyzing laboratory tests results, acid fluid systems were selected together with a self-crosslinking acid system for its diversion properties. In addition, customized pumping schedule was constructed using acid fracturing and diverting simulators and based on optimal conductivity/productivity results fluid stages number and sequence, flow rates and acid volumes were selected. The engineered acid treatment generated a network of conductive fractures that resulted in a significant improvement over initial production rate. Diverting agent efficiency was observed during pumping treatment by a 1,300 psi increase in surface pressures when the diverting agent entered the formation. Oil production increased from 648.7 to 3105.89 BPD, and gas production increased from 4.9 to 26.92 MMSCFD. This success results demonstrates that engineering design coupled with laboratory tailor fluids designs, integrated with a flawless execution, are the key to a successful stimulation. This paper describes the details of acidizing technique, treatment design and lessons learned during execution and results.


2018 ◽  
Vol 6 (16) ◽  
pp. 7027-7033 ◽  
Author(s):  
Mikko Nisula ◽  
Maarit Karppinen

We demonstrate that the high-capacity organic electrode material, p-benzoquinone, is able to sustain ultrahigh redox reaction rates without any conductive additives when applied as ultrathin layers in an all-solid-state thin-film battery setup, viable for e.g. high-performance power sources in microelectronic devices.


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