Reversible photo/thermal stimuli-responsive electrical bistability performance in supramolecular co-crystals accompanied by crystalline-to-amorphous transformations

2020 ◽  
Vol 8 (9) ◽  
pp. 3258-3267
Author(s):  
Qian Liu ◽  
Liming Zhao ◽  
Wei Wu ◽  
Yan He ◽  
Kaiyue Song ◽  
...  

A co-crystal-based device exhibits reversibly stimuli-responsive switchable conductivity states, and its photo/thermal responsive electrically bistable switching mechanism was proposed.

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhaoxian Qin ◽  
Jiangwei Zhang ◽  
Chongqing Wan ◽  
Shuang Liu ◽  
Hadi Abroshan ◽  
...  

AbstractThermal-stimuli responsive nanomaterials hold great promise in designing multifunctional intelligent devices for a wide range of applications. In this work, a reversible isomeric transformation in an atomically precise nanocluster is reported. We show that biicosahedral [Au13Ag12(PPh3)10Cl8]SbF6 nanoclusters composed of two icosahedral Au7Ag6 units by sharing one common Au vertex can produce two temperature-responsive conformational isomers with complete reversibility, which forms the basis of a rotary nanomotor driven by temperature. Differential scanning calorimetry analysis on the reversible isomeric transformation demonstrates that the Gibbs free energy is the driving force for the transformation. This work offers a strategy for rational design and development of atomically precise nanomaterials via ligand tailoring and alloy engineering for a reversible stimuli-response behavior required for intelligent devices. The two temperature-driven, mutually convertible isomers of the nanoclusters open up an avenue to employ ultra-small nanoclusters (1 nm) for the design of thermal sensors and intelligent catalysts.


2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Qingxiang Ji ◽  
Johnny Moughames ◽  
Xueyan Chen ◽  
Guodong Fang ◽  
Juan J. Huaroto ◽  
...  

AbstractMetamaterials have attracted wide scientific interest to break fundamental bounds on materials properties. Recently, the field has been extending to coupled physical phenomena where one physics acts as the driving force for another. Stimuli-responsive or 4D metamaterials have been demonstrated for thermo-elasticity, magneto-optics or piezo-electricity. Herein, a soft, ultra-compact and accurate microrobot is described which can achieve controlled motion under thermal stimuli. The system consists of an organized assembly of two functional structures: a rotational and a translational element. Both elements are designed basing upon the principle of the thermoelastic bilayer plate that bends as temperature changes. Samples are fabricated using gray-tone lithography from a single polymer but with two different laser writing powers, making each part different in its thermal and mechanical behaviors. Excellent motion-controllable, reversible and stable features in a dry environment are verified by simulations and experiments, revealing broad application prospects for the designed soft micro actuators.


2015 ◽  
Vol 54 (2) ◽  
pp. 159-168 ◽  
Author(s):  
Heonjoo Ha ◽  
Kadhiravan Shanmuganathan ◽  
Yunping Fei ◽  
Christopher J. Ellison

The evolution of responsive polymers has amplified expressively in consequence of the growth of precise polymer architecture with predetermined structure-to-property behavior. In this study, new thermal responsive self-healing polycaprolactone urethane coatings were prepared from waste palm cooking oil. Nine different formulations of coatings with various percentages of ε-caprolactone (ε-CL) were successfully developed and the effect of polycaprolactone network in the polyurethane coating on the self-healing behavior. The remendability of the coatings was studied by using thermal analysis and dynamic mechanical analysis. The PCLU coating with the highest content of PCL network was nearly completely healed after 2 hours at 90ºC. The results were confirmed by scanning electron microscopy before and after healing. The mechanism of scratch closure by thermal stimuli-responsive self-healing was also discussed.


2020 ◽  
Vol 11 (24) ◽  
pp. 3940-3950 ◽  
Author(s):  
Patrick Verkoyen ◽  
Holger Frey

Amino-functional polyethers have emerged as a new class of “smart”, i.e. pH- and thermoresponsive materials. This review article summarizes the synthesis and applications of these materials, obtained from ring-opening of suitable epoxide monomers.


2001 ◽  
Vol 209 (2) ◽  
pp. 105-117 ◽  
Author(s):  
Thomas Kleinsorge ◽  
Herbert Heuer ◽  
Volker Schmidtke

Summary. When participants have to shift between four tasks that result from a factorial combination of the task dimensions judgment (numerical vs. spatial) and mapping (compatible vs. incompatible), a characteristic profile of shift costs can be observed that is suggestive of a hierarchical switching mechanism that operates upon a dimensionally ordered task representation, with judgment on the top and the response on the bottom of the task hierarchy ( Kleinsorge & Heuer, 1999 ). This switching mechanism results in unintentional shifts on lower levels of the task hierarchy whenever a shift on a higher level has to be performed, leading to non-shift costs on the lower levels. We investigated whether this profile depends on the way in which the individual task dimensions are cued. When the cues for the task dimensions were exchanged, the basic pattern of shift costs was replicated with only minor modifications. This indicates that the postulated hierarchical switching mechanism operates independently of the specifics of task cueing.


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