Fenton-like reaction system with an analyte-activated catfish effect for enhanced colorimetric and photothermal dopamine bioassay

The Analyst ◽  
2020 ◽  
Author(s):  
Zhengrong Niu ◽  
Hong-Hong Rao ◽  
Xin Xue ◽  
Mingyue Luo ◽  
Xiuhui Liu ◽  
...  

Fenton-like reaction systems have been proven to be more efficient as the powerful promoters in advanced oxidation processes (AOPs) due to their resultantly generated reactive oxygen species (ROS) such as...

2003 ◽  
Vol 31 (6) ◽  
pp. 1316-1317 ◽  
Author(s):  
V.N. Popov

The non-coupled substrate oxidation mediated by components of the electron transport chain that are not coupled to energy accumulation (such as plant alternative oxidase and rotenone-insensitive NADH dehydrogenases) and uncoupled respiration are peculiar features of plant mitochondria. The physiological significance of such energy-wasting oxidation processes is still debated. It is proposed that non-coupled oxidation could regulate the level of reduction of components of the electron transport chain and the rate of one-electron reduction of oxygen, thereby affecting the rate of formation of reactive oxygen species.


2021 ◽  
Author(s):  
Qiaobo Liao ◽  
Can Ke ◽  
Dongni Wang ◽  
Yiying Zhang ◽  
Qingwen Han ◽  
...  

The Fenton reaction is one of the most efficient and widely used advanced oxidation processes for remediating the ever-growing water pollution. Metal-free photocatalysts for Fenton-like reactions have gathered enormous scientific interest for their advantages including board pH operation range and high stability. Herein, we demonstrate a metal-free covalent organic framework (COF)-based standalone photocatalyst with superior reactivity and reusability for Fenton-like reactions at acid and neutral pH solutions, which can be attributed to its large porosity, high density of the photoactive triazine moiety, vertical π arrays formed by eclipsed layer stacking and the <i>β</i>‑ketoenamine linkage. Our experiments showed that the photocatalyst can absorb visible light effectively for activation of H<sub>2</sub>O<sub>2</sub>, producing abundant reactive oxygen species including superoxide radical (O<sub>2</sub><sup>·-</sup>), hydroxyl radical (<sup>·</sup>OH), and singlet oxygen (<sup>1</sup>O<sub>2</sub>) for oxidizing organic pollutants. This work not only provides an efficient metal-free photocatalyst for Fenton-like reactions, but also paves the way for COFs towards advanced oxidation processes, opening up the possibilities to their future applications in industry.


Hydrobiologia ◽  
2016 ◽  
Vol 789 (1) ◽  
pp. 7-29 ◽  
Author(s):  
Ora E. Johannsson ◽  
D. Scott Smith ◽  
Helen Sadauskas-Henrique ◽  
Giselle Cimprich ◽  
Chris M. Wood ◽  
...  

2016 ◽  
Vol 87 (20) ◽  
pp. 2505-2512 ◽  
Author(s):  
Guanghui Qin ◽  
Jian Liu ◽  
Yong Xue ◽  
Jiajia Ding ◽  
Naizhong Huang ◽  
...  

Currently, the antimicrobial textile market is emerging and has rapidly developed to meet the inherent demands placed on public hygiene. Silver (Ag) is an efficient antimicrobial due to its direct function with the cellular membrane of probe samples. The application of Ag in the textile industry is limited due to its poor stability in repeatedly washing. In this study we synthesized a kind of novel antibacterial fiber containing nano-size silver particles in a reversed emulsion reaction system. The Ag nano-particles are incorporated onto the bamboo fibers solidly through primitive oxidation by sodium periodate. The identification, dependent on Staphylococcus aureus, was implemented to check the influence of the reaction conditions on the antimicrobial property. Meanwhile, reactive oxygen species and the leakage of cytoplasmic contents were focused on investigating the antimicrobial mechanism. The antimicrobial assay suggested that samples from inversed micelle and aqueous system own the comparative antibacterial activity. However, samples from an emulsion system could maintain a better bactericidal property than samples from an aqueous system. Meanwhile, the reactive oxygen species and ultraviolet absorption show the same trend consistent with the antibacterial result. This result might be explained by the morphology and size of Ag particles attached on cellulose surface, which was proved by scanning electron microscopy and energy dispersive spectroscopy. It was revealed that the surface-to-volume ratio of Ag particles played a more crucial role in achieving higher antimicrobial activity than the mass. This approach will provide a practical solution for the synthesis of wash-durable antimicrobial substances.


2020 ◽  
Vol 250 ◽  
pp. 117269 ◽  
Author(s):  
Michael M. Sablas ◽  
Mark Daniel G. de Luna ◽  
Sergi Garcia-Segura ◽  
Chiu-Wen Chen ◽  
Chih-Feng Chen ◽  
...  

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