Quantitative detection of dithiocarbamate pesticides by surface-enhanced Raman spectroscopy combined with an exhaustive peak-seeking method

2021 ◽  
Vol 13 (12) ◽  
pp. 1479-1488
Author(s):  
Qiaoling Wei ◽  
Liangdong Zhang ◽  
Chunfeng Song ◽  
Hongfu Yuan ◽  
Xiaoyu Li

A surface-enhanced Raman spectroscopy (SERS) detection method for dithiocarbamate (DTC) with good signal repeatability and a wide linear quantitative range is developed combined with an exhaustive peak-seeking method.

2021 ◽  
pp. 000370282110329
Author(s):  
Ling Wang ◽  
Mario O. Vendrell-Dones ◽  
Chiara Deriu ◽  
Sevde Doğruer ◽  
Peter de B. Harrington ◽  
...  

Recently there has been upsurge in reports that illicit seizures of cocaine and heroin have been adulterated with fentanyl. Surface-enhanced Raman spectroscopy (SERS) provides a useful alternative to current screening procedures that permits detection of trace levels of fentanyl in mixtures. Samples are solubilized and allowed to interact with aggregated colloidal nanostars to produce a rapid and sensitive assay. In this study, we present the quantitative determination of fentanyl in heroin and cocaine using SERS, using a point-and-shoot handheld Raman system. Our protocol is optimized to detect pure fentanyl down to 0.20 ± 0.06 ng/mL and can also distinguish pure cocaine and heroin at ng/mL levels. Multiplex analysis of mixtures is enabled by combining SERS detection with principal component analysis and super partial least squares regression discriminate analysis (SPLS-DA), which allow for the determination of fentanyl as low as 0.05% in simulated seized heroin and 0.10% in simulated seized cocaine samples.


2017 ◽  
Vol 37 (9) ◽  
pp. 0930001 ◽  
Author(s):  
房晓倩 Fang Xiaoqian ◽  
彭彦昆 Peng Yankun ◽  
李永玉 Li Yongyu ◽  
王 凡 Wang Fan ◽  
卜晓朴 Bu Xiaopu ◽  
...  

2020 ◽  
Vol 8 (21) ◽  
pp. 7051-7058
Author(s):  
Weng-I Katherine Chio ◽  
Suresh Moorthy ◽  
Jayakumar Perumal ◽  
Dinish U. S. ◽  
Ivan P. Parkin ◽  
...  

A novel nanosensing platform was developed for the quantitative detection of creatinine of clinically relevant concentrations via UV-Vis spectroscopy and surface-enhanced Raman spectroscopy.


2012 ◽  
Vol 234 (6) ◽  
pp. 1091-1098 ◽  
Author(s):  
Yunfei Xie ◽  
Godelieve Mukamurezi ◽  
Yingying Sun ◽  
Heya Wang ◽  
He Qian ◽  
...  

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