Ligand Influence Versus Electronic Configuration of d-metal Ion in Determining the Fate of NIR Emission from LnIII Ions: A Case Study with CuII, NiII and ZnII Complexes.

2021 ◽  
Author(s):  
Abhineet Verma ◽  
Sk Saddam Hossain ◽  
Sailaja S Sunkari ◽  
Joseph Reibenspies ◽  
Satyen Saha

Lanthanides (LnIII) are well known for their characteristic emission in the Near-Infrared Region (NIR). However, direct excitation of lanthanides is not feasible as described by Laporte’s parity selection rule. Here,...

2021 ◽  
Vol 3 (1) ◽  
Author(s):  
N. D. C. Santana ◽  
A. López ◽  
L. P. Sosman ◽  
S. S. Pedro

AbstractThis study reports the synthesis and photoluminescence spectroscopic studies of Cr3+-doped Mg2SnO4–SnO2 ceramics. The crystal structure was analyzed by X-ray powder diffraction, and photoluminescence was investigated at room temperature. The diffractogram confirmed the presence of Mg2SnO4 and SnO2 phases. Photoluminescence spectroscopy identified broad and intense emission bands assigned to the Cr3+ cation occupation in octahedral Mg2SnO4 sites and an orange band assigned to SnO2 emission. All spectra were analyzed and interpreted according to crystal field theory and Tanabe–Sugano theory for the d3 electronic configuration. The broad and intense emission band covering the visible/near-infrared region suggests that this system may be a promising material for use as an active medium in a broadband light source at room temperature.


2017 ◽  
Vol 41 (22) ◽  
pp. 13495-13503 ◽  
Author(s):  
Shan-kun Yao ◽  
Ying Qian ◽  
Zheng-qing Qi ◽  
Chang-gui Lu ◽  
Yi-ping Cui

In this work, a smart two-photon fluorescent platform based on desulfurization–cyclization was developed, in the construction of TBET-based fluorescent chemodosimeter CyRSN towards Hg2+ in near-infrared region at 746 nm.


2020 ◽  
Vol 4 (11) ◽  
pp. 3378-3383
Author(s):  
Yangyang Li ◽  
Xian Wang ◽  
Lei Zhang ◽  
Luqi Liu ◽  
Qiusheng Wang ◽  
...  

An AIEgen exhibits a fluorescence switch between the visible and the NIR region upon acid/base stimuli, and accessible solid-state NIR emission.


Author(s):  
Cong Shen ◽  
Yan Qing Zhu ◽  
Zixiao Li ◽  
Jingling Li ◽  
Hong Tao ◽  
...  

InP quantum dots (QDs) are considered as the most promising alternative to Cd-based QDs with the lower toxicity and emission spectrum tunability ranging from visible to near-infrared region. Although high-quality...


LWT ◽  
2021 ◽  
Vol 143 ◽  
pp. 111092
Author(s):  
Jose Marcelino S. Netto ◽  
Fernanda A. Honorato ◽  
Patrícia M. Azoubel ◽  
Louise E. Kurozawa ◽  
Douglas F. Barbin

Nanoscale ◽  
2020 ◽  
Vol 12 (41) ◽  
pp. 21459-21459
Author(s):  
Charlotte Marshall

Retraction of ‘Water-soluble multidentate polymers compactly coating Ag2S quantum dots with minimized hydrodynamic size and bright emission tunable from red to second near-infrared region’ by Rijun Gui et al., Nanoscale, 2014, 6, 5467–5473, DOI: 10.1039/C4NR00282B.


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