Synthesis of lead-free Cs4(Cd1−xMnx)Bi2Cl12 (0 ≤ x ≤ 1) layered double perovskite nanocrystals with controlled Mn–Mn coupling interaction

Nanoscale ◽  
2020 ◽  
Vol 12 (45) ◽  
pp. 23191-23199
Author(s):  
Hanjun Yang ◽  
Wenwu Shi ◽  
Tong Cai ◽  
Katie Hills-Kimball ◽  
Zhenyang Liu ◽  
...  
Keyword(s):  
Double Perovskite ◽  
Lead Free ◽  
Optoelectronic Materials ◽  
Next Generation ◽  
Coupling Interaction ◽  
Perovskite Nanocrystals

Lead-free perovskites and their analogues have been extensively studied as a class of next-generation luminescent and optoelectronic materials.

Initiation and future prospects of colloidal metal halide double-perovskite nanocrystals: Cs2AgBiX6 (X = Cl, Br, I)

2018 ◽  
Vol 6 (44) ◽  
pp. 21666-21675 ◽  
Author(s):  
Vikash Kumar Ravi ◽  
Nancy Singhal ◽  
Angshuman Nag
Keyword(s):  
Double Perovskite ◽  
Metal Halide ◽  
Optoelectronic Materials ◽  
Future Prospects ◽  
Perovskite Nanocrystals ◽  
Colloidal Metal

Reviewing the present and future of “Green” metal halide double perovskite nanocrystals as potential optoelectronic materials.

scholarly journals Colloidal Synthesis of Lead-free Cs2TiBr6-xIx Perovskite Nanocrystals

2021 ◽  
Author(s):  
Shanti Maria Liga ◽  
Gerasimos Konstantatos
Keyword(s):  
Solar Cells ◽  
Power Conversion ◽  
Lead Free ◽  
Colloidal Synthesis ◽  
Optoelectronic Materials ◽  
Perovskite Nanocrystals ◽  
Halide Perovskites ◽  
Conversion Efficiencies

Cesium titanium halide perovskites are novel lead-free optoelectronic materials that have attracted attention in the last two years for their application in solar cells with power conversion efficiencies reaching 3.3%....

Lead-Free Direct Band Gap Double-Perovskite Nanocrystals with Bright Dual-Color Emission

2018 ◽  
Vol 140 (49) ◽  
pp. 17001-17006 ◽  
Author(s):  
Bin Yang ◽  
Xin Mao ◽  
Feng Hong ◽  
Weiwei Meng ◽  
Yuxuan Tang ◽  
...  
Keyword(s):  
Band Gap ◽  
Double Perovskite ◽  
Lead Free ◽  
Perovskite Nanocrystals ◽  
Direct Band Gap ◽  
Dual Color ◽  
Direct Band ◽  
Color Emission

scholarly journals Moisture-assisted Near-UV Emission Enhancement of Lead-free Cs4CuIn2Cl12 Double Perovskite Nanocrystals

2021 ◽  
Author(s):  
Maning Liu ◽  
Sri Kasi Matta ◽  
Anastasia Matuhina ◽  
G. Krishnamurthy Grandhi ◽  
Harri Ali-Löytty ◽  
...  
Keyword(s):  
Double Perovskite ◽  
Lead Free ◽  
Colloidal Synthesis ◽  
Morphological Transformation ◽  
Perovskite Nanocrystals ◽  
Uv Emission ◽  
Radiative Transitions ◽  
Emission Enhancement ◽  
Wide Range ◽  
Halide Perovskite

Lead-based halide perovskite nanocrystals (NCs) are recognized as emerging emissive materials with superior photoluminescence (PL) properties. However, the toxicity of lead and the swift chemical decomposition under atmospheric moisture severely hinder their commercialization process. Herein, we report the first colloidal synthesis of lead-free Cs4CuIn2Cl12 layered double perovskite NCs via a facile moisture-assisted hot-injection method stemming from relatively nontoxic precursors. While moisture is typically detrimental to NC synthesis, we demonstrate that the presence of water molecules in Cs4CuIn2Cl12 synthesis enhances the PL quantum yield (mainly in the near-UV range), induces a morphological transformation from 3D nanocubes to 2D nanoplatelets, and converts the dark transitions to radiative transitions for the observed self-trapped excitons relaxation. This work paves the way for further studies on the moisture-assisted synthesis of novel lead-free halide perovskite NCs for a wide range of applications.

scholarly journals Probing the Stability and Band Gaps of Cs2AgInCl6 and Cs2AgSbCl6 Lead-Free Double Perovskite Nanocrystals

2019 ◽  
Vol 31 (9) ◽  
pp. 3134-3143 ◽  
Author(s):  
Jakob C. Dahl ◽  
Wojciech T. Osowiecki ◽  
Yao Cai ◽  
Joseph K. Swabeck ◽  
Yehonadav Bekenstein ◽  
...  
Keyword(s):  
Double Perovskite ◽  
Band Gaps ◽  
Lead Free ◽  
Perovskite Nanocrystals ◽  
The Stability

Lead-Free Silver-Bismuth Halide Double Perovskite Nanocrystals

2018 ◽  
Vol 130 (19) ◽  
pp. 5457-5461 ◽  
Author(s):  
Bin Yang ◽  
Junsheng Chen ◽  
Songqiu Yang ◽  
Feng Hong ◽  
Lei Sun ◽  
...  
Keyword(s):  
Double Perovskite ◽  
Lead Free ◽  
Perovskite Nanocrystals

Lattice Dynamics and Electron–Phonon Coupling in Lead-Free Cs2AgIn1–xBixCl6 Double Perovskite Nanocrystals

2020 ◽  
Vol 11 (6) ◽  
pp. 2113-2120 ◽  
Author(s):  
Debjit Manna ◽  
Jiban Kangsabanik ◽  
Tapan Kumar Das ◽  
Debashish Das ◽  
Aftab Alam ◽  
...  
Keyword(s):  
Lattice Dynamics ◽  
Double Perovskite ◽  
Lead Free ◽  
Phonon Coupling ◽  
Perovskite Nanocrystals ◽  
Electron Phonon Coupling

Self-trapped exciton engineering for white-light emission in colloidal lead-free double perovskite nanocrystals

2020 ◽  
Vol 65 (13) ◽  
pp. 1078-1084 ◽  
Author(s):  
Muyu Cong ◽  
Bin Yang ◽  
Feng Hong ◽  
Tiancheng Zheng ◽  
Youbao Sang ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Double Perovskite ◽  
White Light Emission ◽  
Lead Free ◽  
Perovskite Nanocrystals ◽  
Colloidal Lead
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