Alternating ring-opening copolymerization of epoxides with saturated and unsaturated cyclic anhydrides: reduced viscosity poly(propylene fumarate) oligomers for use in cDLP 3D printing

2020 ◽  
Vol 11 (19) ◽  
pp. 3313-3321 ◽  
Author(s):  
Yongjun Shin ◽  
Matthew L. Becker
Keyword(s):  
3D Printing ◽  
Propylene Oxide ◽  
Ring Opening ◽  
Reduced Viscosity ◽  
Cyclic Anhydrides ◽  
Poly Propylene

A ring-opening copolymerization of propylene oxide with saturated and unsaturated anhydrides using Mg(BHT)2(THF)2 catalyst followed by an isomerization yields poly(propylene fumarate) (PPF) oligomers with improved properties for 3D printing.

Activated anionic ring-opening polymerization for the synthesis of reversibly cross-linkable poly(propylene oxide) based on furan/maleimide chemistry

2016 ◽  
Vol 7 (8) ◽  
pp. 1612-1622 ◽  
Author(s):  
Kévin Roos ◽  
Elena Dolci ◽  
Stéphane Carlotti ◽  
Sylvain Caillol
Keyword(s):  
Propylene Oxide ◽  
Ring Opening ◽  
Glycidyl Ether ◽  
Ring Opening Polymerization ◽  
Anionic Ring ◽  
Poly Propylene ◽  
Anionic Copolymerization

Controlled anionic copolymerization of propylene oxide and furfuryl glycidyl ether was developed for the synthesis of reversibly cross-linkable polyethers.

scholarly journals Organo-Catalyzed/Initiated Ring Opening Co-Polymerization of Cyclic Anhydrides and Epoxides: an Emerging Story

2021 ◽  
Author(s):  
Franck Le Bideau ◽  
Samuel Dagorne ◽  
Samir Messaoudi ◽  
Françoise Dumas ◽  
Gaël Printz ◽  
...  
Keyword(s):  
Ring Opening ◽  
Everyday Lives ◽  
Cyclic Anhydrides

Polyesters are omnipresent in our everyday lives and their synthesis via eco-friendly methods is becoming a major challenge today. The co-polymerization of cyclic anhydrides and epoxides was first reported by...

scholarly journals Heterotelechelic poly(propylene oxide) as migration-inhibited toughening agent in hot lithography based additive manufacturing

2021 ◽  
Vol 12 (9) ◽  
pp. 1260-1272
Author(s):  
Daniel Grunenberg ◽  
Katharina Ehrmann ◽  
Christian Gorsche ◽  
Bernhard Steyrer ◽  
Thomas Koch ◽  
...  
Keyword(s):  
Additive Manufacturing ◽  
Propylene Oxide ◽  
Chain Transfer ◽  
Poly Propylene ◽  
Toughening Agent

Linking an addition–fragmentation-chain-transfer (AFCT) functionality and methacrylate moiety via poly(propylene oxide)-oligomer within one molecule creates a non-migrating AFCT-reagent aiding network-homogeneity.

scholarly journals Ring-Opening Copolymerization of Cyclohexene Oxide and Cyclic Anhydrides Catalyzed by Bimetallic Scorpionate Zinc Catalysts

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1651
Author(s):  
Felipe de la Cruz-Martínez ◽  
Marc Martínez de Sarasa Buchaca ◽  
Almudena del Campo-Balguerías ◽  
Juan Fernández-Baeza ◽  
Luis F. Sánchez-Barba ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Reaction Mechanism ◽  
Catalytic System ◽  
Phthalic Anhydride ◽  
Ring Opening ◽  
High Selectivity ◽  
Zinc Complexes ◽  
Cyclohexene Oxide ◽  
Reaction Conditions ◽  
Cyclic Anhydrides

The catalytic activity and high selectivity reported by bimetallic heteroscorpionate acetate zinc complexes in ring-opening copolymerization (ROCOP) reactions involving CO2 as substrate encouraged us to expand their use as catalysts for ROCOP of cyclohexene oxide (CHO) and cyclic anhydrides. Among the catalysts tested for the ROCOP of CHO and phthalic anhydride at different reaction conditions, the most active catalytic system was the combination of complex 3 with bis(triphenylphosphine)iminium as cocatalyst in toluene at 80 °C. Once the optimal catalytic system was determined, the scope in terms of other cyclic anhydrides was broadened. The catalytic system was capable of copolymerizing selectively and efficiently CHO with phthalic, maleic, succinic and naphthalic anhydrides to afford the corresponding polyester materials. The polyesters obtained were characterized by spectroscopic, spectrometric, and calorimetric techniques. Finally, the reaction mechanism of the catalytic system was proposed based on stoichiometric reactions.

Chiral salenCo(iii) complexes with bulky substituents as catalysts for stereoselective alternating copolymerization of racemic propylene oxide with carbon dioxide and succinic anhydride

2021 ◽  
Vol 12 (12) ◽  
pp. 1776-1786
Author(s):  
Zhou Wang ◽  
Ying Mu
Keyword(s):  
Carbon Dioxide ◽  
Propylene Carbonate ◽  
Propylene Oxide ◽  
Succinic Anhydride ◽  
Poly Propylene ◽  
Alternating Copolymerization

Stereoregular poly(propylene carbonate)s and poly(propylene succinate-block-carbonate)s were synthesized with new chiral salenCo(iii) catalysts carrying bulky substituents.

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