Influence of process conditions on hydrothermal liquefaction of eucalyptus biomass for biocrude production and investigation of the inorganics distribution

Author(s):  
Tahir Hussain Seehar ◽  
Saqib Sohail Toor ◽  
Kamaldeep Sharma ◽  
Asbjørn Haaning Nielsen ◽  
Thomas Helmer Pedersen ◽  
...  

In the present study, eucalyptus biomass was processed to produce biocrude via hydrothermal liquefaction.

2021 ◽  
Vol 11 (04) ◽  
pp. 157-186
Author(s):  
Dan Egesa ◽  
Patrick Mulindwa ◽  
Edward Mubiru ◽  
Hilda Dinah Kyomuhimbo ◽  
Godwin Aturagaba

Author(s):  
Niloufar Ghavami ◽  
Karhan Özdenkçi ◽  
Gabriel Salierno ◽  
Margareta Björklund-Sänkiaho ◽  
Cataldo De Blasio

AbstractBiomass is often referred to as a carbon–neutral energy source, and it has a role in reducing fossil fuel depletion. In addition, biomass can be converted efficiently into various forms of biofuels. The biomass conversion processes involve several thermochemical, biochemical, and hydrothermal methods for biomass treatment integration. The most common conversion routes to produce biofuels include pyrolysis and gasification processes. On the other hand, supercritical water gasification (SCWG) and hydrothermal liquefaction (HTL) are best suitable for converting biomass and waste with high moisture content. Despite promising efficiencies, SCWG and HTL processes introduce operational issues as obstacles to the industrialization of these technologies. The issues include process safety aspects due to operation conditions, plugging due to solid deposition, corrosion, pumpability of feedstock, catalyst sintering and deactivation, and high production costs. The methods to address these issues include various reactor configurations to avoid plugging and optimizing process conditions to minimize other issues. However, there are only a few studies investigating the operational issues as the main scope, and reviews are seldomly available in this regard. Therefore, further research is required to address operational problems. This study reviews the main operational problems in SCWG and HTL. The objective of this study is to enhance the industrialization of these processes by investigating the operational issues and the potential solutions, i.e., contributing to the elimination of the obstacles. A comprehensive study on the operational issues provides a holistic overview of the biomass conversion technologies and biorefinery concepts to promote the industrialization of SCWG and HTL.


RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 20193-20207 ◽  
Author(s):  
B. E. Eboibi ◽  
D. M. Lewis ◽  
P. J. Ashman ◽  
S. Chinnasamy

The direct conversion of microalgae to advanced biofuels with hydrothermal liquefaction (HTL) is an attractive option which has drawn attention in recent years.


2021 ◽  
Vol 27 (1) ◽  
pp. 200555-0
Author(s):  
Chitra Devi Venkatachalam ◽  
Sathish Raam Ravichandran ◽  
Mothil Sengottian

Thermochemical conversion is an effective process in production of biocrude. It mainly includes techniques such as torrefaction, liquefaction, gasification and pyrolysis in which Hydrothermal Liquefaction (HTL) has the potential to produce significant energy resource. Algae, one of the third-generation feedstocks is placed in the top order for production of bio-oil compared to the first and second-generation feedstock, as the algae can get multiplied in shorter time with the uptake of greenhouse gases. In HTL, the subcritical water helps the biomass to undergo thermal depolymerisation and produce various chemicals such as nitrogenates, alkanes, phenolics, esters, etc. The produced “biocrude” or “bio-oil” may be further upgraded into value-added chemicals and fuels. In addition, the bio-gas and bio-char are also synthesized as by-products. This review provides an overview of different routes available for thermochemical conversion of biomass. It also provides an insight on the operating parameters such as temperature, pressure, dosage of catalyst and solvent for lignocellulosic and algal biomass under HTL environment. In extent, the article covers the conversion mechanism for these two feedstocks and also the effects of the operating parameters on the yield of biocrude are studied in detail.


2018 ◽  
Vol 134 ◽  
pp. 415-426 ◽  
Author(s):  
Mariusz Wądrzyk ◽  
Rafał Janus ◽  
Mathijs P. Vos ◽  
Derk Willem Frederik Brilman

Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3165 ◽  
Author(s):  
Daniele Castello ◽  
Thomas Pedersen ◽  
Lasse Rosendahl

Hydrothermal liquefaction (HTL) of biomass is emerging as an effective technology to efficiently valorize different types of (wet) biomass feedstocks, ranging from lignocellulosics to algae and organic wastes. Significant research into HTL has been conducted in batch systems, which has provided a fundamental understanding of the different process conditions and the behavior of different biomass. The next step towards continuous plants, which are prerequisites for an industrial implementation of the process, has been significantly less explored. In order to facilitate a more focused future development, this review—based on the sources available in the open literature—intends to present the state of the art in the field of continuous HTL as well as to suggest means of interpretation of data from such plants. This contributes to a more holistic understanding of causes and effects, aiding next generation designs as well as pinpointing research focus. Additionally, the documented experiences in upgrading by catalytic hydrotreating are reported. The study reveals some interesting features in terms of energy densification versus the yield of different classes of feedstocks, indicating that some global limitations exist irrespective of processing implementations. Finally, techno-economic considerations, observations and remarks for future studies are presented.


2022 ◽  
Vol 12 (2) ◽  
pp. 569
Author(s):  
Yuliya Kulikova ◽  
Stanislav Sukhikh ◽  
Svetlana Ivanova ◽  
Olga Babich ◽  
Natalia Sliusar

At the moment, macroalgae blooms in sea waters, the rotting of which causes greenhouse gas emissions and contributes to the formation of a negative ecological and economic situation in coastal zones, which has become a serious problem. Fuel production through hydrothermal liquefaction (HTL) of macroalgae and marine debris is a promising solution to this ecological problem. The article provides an overview of studies on producing fuel from macroalgae and an assessment of the possibility of their joint recovery with marine debris. The optimal process conditions and their technological efficiency were evaluated. The article shows the feasibility of using heterogeneous catalysis and co-solvent to increase the yield of bio-oil and improve its quality. An assessment of the possibility of joint processing of waste macroalgae and marine debris showed the inexpediency of this direction. The high degree of drift macroalgae contamination also raises the question of the appropriateness of the preliminary extraction of other valuable components for nutrition use, such as fats, proteins, carbohydrates, and their derivatives.


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