Electrode materials and device architecture strategies for flexible supercapacitors in wearable energy storage

2021 ◽  
Vol 9 (13) ◽  
pp. 8099-8128
Author(s):  
Xinyu Zhang ◽  
Changzhong Jiang ◽  
Jing Liang ◽  
Wei Wu

Efficient strategies of electrode materials and the device architecture for wearable flexible supercapacitors have been systematically summarized.

2021 ◽  
Vol 7 (3) ◽  
pp. 151-162
Author(s):  
Gabriela Queirós ◽  
Natalia Rey-Raap ◽  
Clara Pereira ◽  
Manuel Fernando R. Pereira

Supercapacitors are energy storage devices that have received much interest in the past decade. These devices have unique characteristics, such as high energy density, fast charging, extensive life cycle, and excellent stability. Currently, wearable electronic gadgets have appeared as an interesting application for flexible supercapacitors, in which lightness and flexibility of the electrodes are two of the most important properties. In addition, the materials used as electrodes severely affect the behavior of these devices. Carbon nanomaterials are the most proficient and most studied electrode materials in flexible supercapacitors. Among them, carbon nanotubes (CNTs) have been extensively studied owing to their excellent mechanical and electrical properties. Therefore, this short review focuses on the new progress in the use of CNT materials as electrodes in flexible energy storage devices.


2021 ◽  
Author(s):  
Mirai Ohara ◽  
A. Shahul Hameed ◽  
Kei Kubota ◽  
Akihiro Katogi ◽  
Kuniko Chihara ◽  
...  

K-ion batteries (KIBs) are promising for large-scale electrical energy storage owing to the abundant resources and the electrochemical specificity of potassium. Among the positive electrode materials for KIBs, vanadium-based polyanionic...


Author(s):  
Tingting Xia ◽  
Chengfei Xu ◽  
Pengfei Dai ◽  
Xiaoyun Li ◽  
Riming Lin ◽  
...  

Three-dimensional (3D) conductive polymers are promising conductive matrices for electrode materials toward electrochemical energy storage. However, their fragile nature and weak binding forces with active materials could not guarantee long-term...


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2325
Author(s):  
Ronan Invernizzi ◽  
Liliane Guerlou-Demourgues ◽  
François Weill ◽  
Alexia Lemoine ◽  
Marie-Anne Dourges ◽  
...  

Nanostructuration is one of the most promising strategies to develop performant electrode materials for energy storage devices, such as hybrid supercapacitors. In this work, we studied the influence of precipitation medium and the use of a series of 1-alkyl-3-methylimidazolium bromide ionic liquids for the nanostructuration of β(III) cobalt oxyhydroxides. Then, the effect of the nanostructuration and the impact of the different ionic liquids used during synthesis were investigated in terms of energy storage performances. First, we demonstrated that forward precipitation, in a cobalt-rich medium, leads to smaller particles with higher specific surface areas (SSA) and an enhanced mesoporosity. Introduction of ionic liquids (ILs) in the precipitation medium further strongly increased the specific surface area and the mesoporosity to achieve well-nanostructured materials with a very high SSA of 265 m2/g and porosity of 0.43 cm3/g. Additionally, we showed that ILs used as surfactant and template also functionalize the nanomaterial surface, leading to a beneficial synergy between the highly ionic conductive IL and the cobalt oxyhydroxide, which lowers the resistance charge transfer and improves the specific capacity. The nature of the ionic liquid had an important influence on the final electrochemical properties and the best performances were reached with the ionic liquid containing the longest alkyl chain.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 631
Author(s):  
Aleksander Cholewinski ◽  
Pengxiang Si ◽  
Marianna Uceda ◽  
Michael Pope ◽  
Boxin Zhao

Binders play an important role in electrode processing for energy storage systems. While conventional binders often require hazardous and costly organic solvents, there has been increasing development toward greener and less expensive binders, with a focus on those that can be processed in aqueous conditions. Due to their functional groups, many of these aqueous binders offer further beneficial properties, such as higher adhesion to withstand the large volume changes of several high-capacity electrode materials. In this review, we first discuss the roles of binders in the construction of electrodes, particularly for energy storage systems, summarize typical binder characterization techniques, and then highlight the recent advances on aqueous binder systems, aiming to provide a stepping stone for the development of polymer binders with better sustainability and improved functionalities.


Author(s):  
Yaning Gao ◽  
Haoyi Yang ◽  
Ying Bai ◽  
Chuan Wu

Aqueous rechargeable metal ion batteries (ARMBs), featuring safety, facile manufacturing and environmental benignity, have recently attracted extensive attention as promising energy storage systems. Particularly, pursuit of electrode materials with abundance,...


Author(s):  
Linlin Liu ◽  
Zhen Ji ◽  
Shuyan Zhao ◽  
Qingyuan Niu ◽  
Songqi Hu

The delignified wood-based self-supporting carbon material is an ideal basic interdigital flexible electrode material, which has good application potential.


Electrochem ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 236-250
Author(s):  
Arjun Prasad Tiwari ◽  
Tanka Mukhiya ◽  
Alagan Muthurasu ◽  
Kisan Chhetri ◽  
Minju Lee ◽  
...  

The development of smart negative electrode materials with high capacitance for the uses in supercapacitors remains challenging. Although several types of electrode materials with high capacitance in energy storage have been reported, carbon-based materials are the most reliable electrodes due to their high conductivity, high power density, and excellent stability. The most common complaint about general carbon materials is that these electrode materials can hardly ever be used as free-standing electrodes. Free-standing carbon-based electrodes are in high demand and are a passionate topic of energy storage research. Electrospun nanofibers are a potential candidate to fill this gap. However, the as-spun carbon nanofibers (ECNFs) have low capacitance and low energy density on their own. To overcome the limitations of pure CNFs, increasing surface area, heteroatom doping and metal doping have been chosen. In this review, we introduce the negative electrode materials that have been developed so far. Moreover, this review focuses on the advances of electrospun nanofiber-based negative electrode materials and their limitations. We put forth a future perspective on how these limitations can be overcome to meet the demands of next-generation smart devices.


Author(s):  
Mohan Kumar Anand Raj ◽  
Rajasekar Rathanasamy ◽  
Prabhakaran Paramasivam ◽  
Santhosh Sivaraj

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