High-performance near-infrared (NIR) polymer light-emitting diodes (PLEDs) based on bipolar Ir(iii)-complex-grafted polymers

2021 ◽  
Vol 9 (1) ◽  
pp. 173-180
Author(s):  
Wentao Li ◽  
Baowen Wang ◽  
Tiezheng Miao ◽  
Jiaxiang Liu ◽  
Guorui Fu ◽  
...  

Despite the cost-effective and large-area scalable advantages of NIR-PLEDs based on iridium(iii)-complex-doped polymers, the intrinsic phase-separation issue leading to inferior device performance is difficult to address.

2020 ◽  
Vol 11 (10) ◽  
pp. 2640-2646 ◽  
Author(s):  
Guorui Fu ◽  
Yani He ◽  
Wentao Li ◽  
Tiezheng Miao ◽  
Xingqiang Lü ◽  
...  

Using [Zn2(MP)3(OAc)]-grafted polymer as a single emitting layer, record-high efficiencies and weak (ca. 25%) efficiency roll-off are realized for cost-effective and large-area flexible WPLEDs.


Author(s):  
Yan Zhang ◽  
Baowen Wang ◽  
Jiaxiang Liu ◽  
Xingqiang Lv ◽  
Guorui Fu ◽  
...  

Among reliable vacuum-deposited or solution-processed NIR-OLEDs/PLEDs doped with NIR-emitting iridium(III)-complexes, high-performance achievement of their all-solution-processed NIR-PLEDs remains a great challenge. In this study, owing to the forceful electronic perturbation achieved...


Author(s):  
Wentao Li ◽  
Tiezheng Miao ◽  
Baowen Wang ◽  
Jiaxiang Liu ◽  
Xingqiang Lv ◽  
...  

Using conventionally fac-[Ir(C^N)3]-homoleptic or [Ir(C^N)2(L^X)]-bis-heteroleptic iridium(III)-complexes with NIR-phosphorescence (NIR = near infrared) as dopants, the realization of their reliable NIR-OLEDs/PLEDs (organic/polymer light-emitting diodes) with high-performance remains a real challenge. In...


Author(s):  
Siyu Hou ◽  
Jiaxiang Liu ◽  
Baowen Wang ◽  
Tiezheng Miao ◽  
Xingqiang Lv ◽  
...  

Despite the domination of conventional [Ir(C^N)2(L^X)]-bis-heteroleptic iridium(III)-complexes with NIR-phosphorescence (NIR = near infrared) as dopants for reliable NIR-OLEDs/PLEDs (organic/polymer light-emitting diodes), the achievement of their high-performance remains a real challenge....


2011 ◽  
Vol 1340 ◽  
Author(s):  
Alasdair J. Campbell ◽  
Dae-Young Chung ◽  
Jingsong Huang ◽  
Dong-Seok Leem ◽  
Donal D. C. Bradley

ABSTRACTGravure contact printing is the highest volume, large area printing technique known. It is ideally suited for the fabrication of large-area polymer light emitting diode (PLED) based lighting, backlights and displays. Here we show how gravure can be used to fabricate the poly (3,4-ethylene dioxythiophene) : poly(styrene sulfonate) hole injection layer and the light emitting polymer emissive layer in a conventional PLED, as well as the cesium carbonate electron injection layer in an inverted PLED. The performance equals or exceeds that of devices where these layers are deposited by conventional spin-coating.


2021 ◽  
Vol 9 (36) ◽  
pp. 12068-12072
Author(s):  
Wentao Li ◽  
Jiaxiang Liu ◽  
Baowen Wang ◽  
Siyu Hou ◽  
Xingqiang Lü ◽  
...  

Based on geometrical isomerisation of [Ir(C^N1)(C^N2)((N^O))]-tris-heteroleptic Ir(iii)-complexes, the augmented transition dipole transition (TMD) with a preferential horizontal orientation, which is beneficial for their NIR-phosphorescence, is reported.


CrystEngComm ◽  
2021 ◽  
Author(s):  
Mingming Jiang ◽  
Fupeng Zhang ◽  
Kai Tang ◽  
Peng Wan ◽  
Caixia Kan

Achieving electrically-driven exciton-polaritons has drawn substantial attention toward developing ultralow-threshold coherent light sources, containing polariton laser devices and high-performance light-emitting diodes (LEDs). In this work, we demonstrate an electrically driven...


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Changjiu Sun ◽  
Yuanzhi Jiang ◽  
Minghuan Cui ◽  
Lu Qiao ◽  
Junli Wei ◽  
...  

AbstractSerious performance decline arose for perovskite light-emitting diodes (PeLEDs) once the active area was enlarged. Here we investigate the failure mechanism of the widespread active film fabrication method; and ascribe severe phase-segregation to be the reason. We thereby introduce L-Norvaline to construct a COO−-coordinated intermediate phase with low formation enthalpy. The new intermediate phase changes the crystallization pathway, thereby suppressing the phase-segregation. Accordingly, high-quality large-area quasi-2D films with desirable properties are obtained. Based on this, we further rationally adjusted films’ recombination kinetics. We reported a series of highly-efficient green quasi-2D PeLEDs with active areas of 9.0 cm2. The peak EQE of 16.4% is achieved in <n > = 3, represent the most efficient large-area PeLEDs yet. Meanwhile, high brightness device with luminance up to 9.1 × 104 cd m−2 has achieved in <n> = 10 film.


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