Intrinsic-to-Extrinsic Emission Tuning in Luminescent Cu Nanoclusters by in-situ Ligand Engineering

Author(s):  
Joy Chatterjee ◽  
Abhijit Chatterjee ◽  
Partha Hazra

Enhancement in the emission quantum yield and expansion of the emission tunability spectrum are the key incentive aspects of an emitter, which directs the evolution of future generation light harvesting...

2006 ◽  
Vol 21 (2) ◽  
pp. 505-511 ◽  
Author(s):  
Lili Hu ◽  
Junlan Wang ◽  
Zijian Li ◽  
Shuang Li ◽  
Yushan Yan

Nanoporous silica zeolite thin films are promising candidates for future generation low-dielectric constant (low-k) materials. During the integration with metal interconnects, residual stresses resulting from the packaging processes may cause the low-k thin films to fracture or delaminate from the substrates. To achieve high-quality low-k zeolite thin films, it is important to carefully evaluate their adhesion performance. In this paper, a previously reported laser spallation technique is modified to investigate the interfacial adhesion of zeolite thin film-Si substrate interfaces fabricated using three different methods: spin-on, seeded growth, and in situ growth. The experimental results reported here show that seeded growth generates films with the highest measured adhesion strength (801 ± 68 MPa), followed by the in situ growth (324 ± 17 MPa), then by the spin-on (111 ± 29 MPa). The influence of the deposition method on film–substrate adhesion is discussed. This is the first time that the interfacial strength of zeolite thin films-Si substrates has been quantitatively evaluated. This paper is of great significance for the future applications of low-k zeolite thin film materials.


2021 ◽  
Author(s):  
Ànnia Tubau ◽  
Laura Rodríguez ◽  
Ariadna L.azaro ◽  
Ramon Vicente ◽  
Merce Font-Bardia

The reaction of Ln(NO3)2·6H2O salts (Ln = Eu and Tb) with an excess of 2-fluorobenzoic acid (H-2FBz) in ethanol/water mixture allows the isolation of dinuclear compounds of formula [Ln2(-2FBz)4(2FBz)2(H-2FBz)2(H2O)2] (Ln...


Nano Letters ◽  
2014 ◽  
Vol 14 (12) ◽  
pp. 6787-6791 ◽  
Author(s):  
Thomas S. Bischof ◽  
Raoul E. Correa ◽  
Danna Rosenberg ◽  
Eric A. Dauler ◽  
Moungi G. Bawendi

2018 ◽  
Vol 6 (28) ◽  
pp. 7479-7486 ◽  
Author(s):  
Flavia Artizzu ◽  
Danilo Loche ◽  
Dimitrije Mara ◽  
Luca Malfatti ◽  
Angela Serpe ◽  
...  

Remote sensitization in hybrid organic–inorganic Eu3+-doped layered silica nanoarchitectures allows for unusually high emission quantum yield through efficient energy transfer and the removal of ultra-fast quenching effects of inner-shell emitters.


2020 ◽  
Vol 2020 (18) ◽  
pp. 1736-1742
Author(s):  
Sandra F. H. Correia ◽  
Ricardo L. Fernandes ◽  
Lianshe Fu ◽  
Mariela M. Nolasco ◽  
Luís D. Carlos ◽  
...  

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