Characteristics, Properties, Synthesis and Advanced Applications of 2D Graphdiyne vs Graphene

Author(s):  
Ying Zhao ◽  
Luxiao Chai ◽  
Xiaobing Yan ◽  
Weichun Huang ◽  
Taojian Fan ◽  
...  

Like graphene, graphdiyne is a newly discovered two-dimensional planar carbon allotrope with uniform pores and highly π-conjugated interactions. It shows a lot of affinities with graphene in properties and applications....

Carbon ◽  
2020 ◽  
Vol 170 ◽  
pp. 477-486 ◽  
Author(s):  
Xin Chen ◽  
Adrien Bouhon ◽  
Linyang Li ◽  
François M. Peeters ◽  
Biplab Sanyal

2020 ◽  
Vol 8 (45) ◽  
pp. 16143-16150
Author(s):  
Jyotirmoy Deb ◽  
Debolina Paul ◽  
Utpal Sarkar

Herein, we have proposed a novel two-dimensional (2D) carbon allotrope, namely pentagraphyne (PG-yne), which is energetically favourable than other graphyne members, including experimentally synthesized graphyne and graphdiyne monolayer.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Lei Wang ◽  
Ranran Zhang ◽  
Jiao Shi ◽  
Kun Cai

Abstract Diamondene is a new kind of two dimensional carbon allotrope with excellent properties and passivation approaches are often used to reduce the extremely high pressure required during its fabrication. When a one-end-clamped diamondene ribbon is hydrogenated on one surface, the ribbon tends to bend and vibrate due to asymmetric layout of C-H bonds on two surfaces. In the present work, the vibration behavior, including natural curvatures and vibration frequencies of diamondene ribbons, were investigated by molecular dynamics simulations. Results indicate that the natural curvature radius of a narrow diamondene ribbon is close to 12.17 nm at a temperature below 150 K, which is essential for fabricating an arc nanodevice. The first order frequency (f1) of a cantilever beam made from the ribbon follows traditional beam vibration theory if the slenderness ratio is low. In particular, f1 increases logarithmically at temperature below 50 K, but changes slightly between 50 K and 150 K. It suggests a design scheme for a nanoresonator with temperature-controlled frequency.


2020 ◽  
Vol 13 (05) ◽  
pp. 2030010 ◽  
Author(s):  
Pengkun Yin ◽  
Qingyu Lin ◽  
Yixiang Duan

At present, two-dimensional (2D) materials have shown great application potential in numerous fields based on their physical chemical and electronic properties. Raman spectroscopy and derivative techniques are effective tools for characterizing 2D materials. Raman spectroscopy conveys lots of knowledge on 2D materials, including layer number, doping type, strain and interlayer coupling. This review summarized advanced applications of Raman spectroscopy in 2D materials. The challenges and possible applied directions of Raman spectroscopy to 2D materials are discussed in detail.


2017 ◽  
Vol 87 ◽  
pp. 107-111 ◽  
Author(s):  
Guohui Zheng ◽  
Yalei Jia ◽  
Song Gao ◽  
San-Huang Ke

2020 ◽  
Author(s):  
Xianjue Chen ◽  
Marc Dubois ◽  
Silvana Radescu Cioranescu ◽  
Aditya Rawal ◽  
Chuan Zhao

Fluorinated single-layer diamond (“F-diamond”) is a new form of two-dimensional carbon allotrope. Herein, poly(dicarbon monofluoride) (C<sub>2</sub>F)<sub>n</sub> that is essentially made of stacked layers of “F-diamane” has been synthesized and exfoliated in a variety of solvents to yield well-dispersed ultrathin sheets. Microscopic and spectroscopic analyses revealed that the exfoliated sheets retained the “F-diamane”-like structure. The experimental results are supported by the density functional theory (DFT) calculations.


2016 ◽  
Vol 52 (32) ◽  
pp. 5629-5632 ◽  
Author(s):  
Chunxia Wang ◽  
Ping Yu ◽  
Shuyue Guo ◽  
Lanqun Mao ◽  
Huibiao Liu ◽  
...  

Graphdiyne (GD), a new kind of two-dimensional carbon allotrope consisting of a hexagonal ring and a diacetylenic linkage unit, is observed to exhibit a high fluorescence quenching ability and can be used as a new platform for fluorescence sensing, where GD oxide, the oxidized form of GD, is found to exhibit higher quenching ability than GD.


2018 ◽  
Vol 6 (15) ◽  
pp. 6687-6687 ◽  
Author(s):  
Shuaiwei Wang ◽  
Baocheng Yang ◽  
Houyang Chen ◽  
Eli Ruckenstein

Correction for ‘Popgraphene: a new 2D planar carbon allotrope composed of 5–8–5 carbon rings for high-performance lithium-ion battery anodes from bottom-up programming’ by Shuaiwei Wang et al., J. Mater. Chem. A, 2018, DOI: 10.1039/c8ta00438b.


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