Applications of Raman spectroscopy in two-dimensional materials

2020 ◽  
Vol 13 (05) ◽  
pp. 2030010 ◽  
Author(s):  
Pengkun Yin ◽  
Qingyu Lin ◽  
Yixiang Duan

At present, two-dimensional (2D) materials have shown great application potential in numerous fields based on their physical chemical and electronic properties. Raman spectroscopy and derivative techniques are effective tools for characterizing 2D materials. Raman spectroscopy conveys lots of knowledge on 2D materials, including layer number, doping type, strain and interlayer coupling. This review summarized advanced applications of Raman spectroscopy in 2D materials. The challenges and possible applied directions of Raman spectroscopy to 2D materials are discussed in detail.

Nanoscale ◽  
2021 ◽  
Author(s):  
Yuan Cheng ◽  
Xing Wu ◽  
Zijian Zhang ◽  
Yao Sun ◽  
Yunshan Zhao ◽  
...  

Two-dimensional (2D) materials have received tremendous attention from the research community in the past decades, because of their numerous striking physical, chemical and mechanical properties and promising potential in a...


2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Ming Xia

Two-dimensional (2D) materials, such as graphene and MoS2, have been attracting wide interest in surface enhancement Raman spectroscopy. This perspective gives an overview of recent developments in 2D materials’ application in surface-enhanced Raman spectroscopy. This review paper focuses on the applications of using bare 2D materials and metal/2D material hybrid substrate for Raman enhancement. The Raman enhancing mechanism of 2D materials will also be discussed. The progress covered herein shows great promise for widespread adoption of 2D materials in SERS application.


Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5213
Author(s):  
Oliver Dubnack ◽  
Frank A. Müller

The possibility of producing stable thin films, only a few atomic layers thick, from a variety of materials beyond graphene has led to two-dimensional (2D) materials being studied intensively in recent years. By reducing the layer thickness and approaching the crystallographic monolayer limit, a variety of unexpected and technologically relevant property phenomena were observed, which also depend on the subsequent arrangement and possible combination of individual layers to form heterostructures. These properties can be specifically used for the development of multifunctional devices, meeting the requirements of the advancing miniaturization of modern manufacturing technologies and the associated need to stabilize physical states even below critical layer thicknesses of conventional materials in the fields of electronics, magnetism and energy conversion. Differences in the structure of potential two-dimensional materials result in decisive influences on possible growth methods and possibilities for subsequent transfer of the thin films. In this review, we focus on recent advances in the rapidly growing field of two-dimensional materials, highlighting those with oxidic crystal structure like perovskites, garnets and spinels. In addition to a selection of well-established growth techniques and approaches for thin film transfer, we evaluate in detail their application potential as free-standing monolayers, bilayers and multilayers in a wide range of advanced technological applications. Finally, we provide suggestions for future developments of this promising research field in consideration of current challenges regarding scalability and structural stability of ultra-thin films.


Molecules ◽  
2018 ◽  
Vol 24 (1) ◽  
pp. 88 ◽  
Author(s):  
Zuoyuan Dong ◽  
Hejun Xu ◽  
Fang Liang ◽  
Chen Luo ◽  
Chaolun Wang ◽  
...  

The emergence and development of two-dimensional (2D) materials has provided a new direction for enhancing the thermoelectric (TE) performance due to their unique structural, physical and chemical properties. However, the TE performance measurement of 2D materials is a long-standing challenge owing to the experimental difficulties of precise control in samples and high demand in apparatus. Until now, there is no universal methodology for measuring the dimensionless TE figure of merit (ZT) (the core parameter for evaluating TE performance) of 2D materials systematically in experiments. Raman spectroscopy, with its rapid and nondestructive properties for probing samples, is undoubtedly a powerful tool for characterizing 2D materials as it is known as a spectroscopic ‘Swiss-Army Knife’. Raman spectroscopy can be employed to measure the thermal conductivity of 2D materials and expected to be a systematic method in evaluating TE performance, boosting the development of thermoelectricity. In this review, thermoelectricity, 2D materials, and Raman techniques, as well as thermal conductivity measurements of 2D materials by Raman spectroscopy are introduced. The prospects of obtaining ZT and testing the TE performance of 2D materials by Raman spectroscopy in the future are also discussed.


Nanophotonics ◽  
2020 ◽  
Vol 9 (8) ◽  
pp. 2315-2340 ◽  
Author(s):  
Junli Wang ◽  
Xiaoli Wang ◽  
Jingjing Lei ◽  
Mengyuan Ma ◽  
Cong Wang ◽  
...  

AbstractDue to the unique properties of two-dimensional (2D) materials, much attention has been paid to the exploration and application of 2D materials. In this review, we focus on the application of 2D materials in mode-locked fiber lasers. We summarize the synthesis methods for 2D materials, fiber integration with 2D materials and 2D materials based saturable absorbers. We discuss the performance of the diverse mode-locked fiber lasers in the typical operating wavelength such as 1, 1.5, 2 and 3 μm. Finally, a summary and outlook of the further applications of the new materials in mode-locked fiber lasers are presented.


2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Mei Zhao ◽  
Sijie Yang ◽  
Kenan Zhang ◽  
Lijie Zhang ◽  
Ping Chen ◽  
...  

AbstractNonlayered two-dimensional (2D) materials have attracted increasing attention, due to novel physical properties, unique surface structure, and high compatibility with microfabrication technique. However, owing to the inherent strong covalent bonds, the direct synthesis of 2D planar structure from nonlayered materials, especially for the realization of large-size ultrathin 2D nonlayered materials, is still a huge challenge. Here, a general atomic substitution conversion strategy is proposed to synthesize large-size, ultrathin nonlayered 2D materials. Taking nonlayered CdS as a typical example, large-size ultrathin nonlayered CdS single-crystalline flakes are successfully achieved via a facile low-temperature chemical sulfurization method, where pre-grown layered CdI2 flakes are employed as the precursor via a simple hot plate assisted vertical vapor deposition method. The size and thickness of CdS flakes can be controlled by the CdI2 precursor. The growth mechanism is ascribed to the chemical substitution reaction from I to S atoms between CdI2 and CdS, which has been evidenced by experiments and theoretical calculations. The atomic substitution conversion strategy demonstrates that the existing 2D layered materials can serve as the precursor for difficult-to-synthesize nonlayered 2D materials, providing a bridge between layered and nonlayered materials, meanwhile realizing the fabrication of large-size ultrathin nonlayered 2D materials.


Author(s):  
Adam Brill ◽  
Elad Koren ◽  
Graham de Ruiter

Atomically thin two-dimensional materials (2DMs) have moved in the past 15 years from a serendipitously isolated single-layered graphene curiosity to a near technological renaissance, where 2DMs such as graphene and...


Author(s):  
L Malard ◽  
Lucas Lafetá ◽  
Renan Cunha ◽  
Rafael Nadas ◽  
Andreij Gadelha ◽  
...  

Raman spectroscopy is established as a valuable tool to study and characterize two-dimensional (2D) systems, but it exhibits two drawbacks: a relatively weak signal response and a limited spatial resolution....


2021 ◽  
Vol 8 (1) ◽  
pp. 182-200
Author(s):  
Yanglizhi Li ◽  
Luzhao Sun ◽  
Haiyang Liu ◽  
Yuechen Wang ◽  
Zhongfan Liu

Recent advances on preparing single-crystal metals and their crucial roles in controlled growth of high-quality 2D materials are reviewed.


Sign in / Sign up

Export Citation Format

Share Document