scholarly journals Electroanalytical Overview: The Electroanalytical Sensing of Hydrazine

2022 ◽  
Author(s):  
Robert Crapnell ◽  
Craig E. Banks
Keyword(s):  
Electrochemical Sensing ◽  
Chemical Reagent ◽  
Important Chemical

In this overview, we explore the electroanalytical sensing of the important chemical reagent hydrazine, highlighting the plethora of electrochemical sensing strategies utilised from the first reports in 1951 to the...

Deinking of recycled paper by coupling of the enzyme endo-β-1,4-D-glucanasa and the cellulose, and by using a laboratory flotation column

MRS Advances ◽  
2020 ◽  
Vol 5 (52-53) ◽  
pp. 2669-2678
Author(s):  
Jeovani González P. ◽  
Ramiro Escudero G
Keyword(s):  
Amino Acids ◽  
Sodium Hydroxide ◽  
Paper Industry ◽  
Computational Simulation ◽  
Cellulose Fibers ◽  
Residual Water ◽  
Chemical Reagent ◽  
Recycled Paper ◽  
Flotation Column ◽  
Hydrolysis Of

AbstractDeinking of recycled office (MOW) paper was carried out by using a flotation column and adding separately sodium hydroxide, and the enzyme Cellulase Thricodema Sp., as defibrillators.The de-inked cellulose fibers were characterized according to the standards of the paper industry, to compare the efficiency of the deinking of each chemical reagent used to hydrolyze the fibers and defibrillate them.The computational simulation of the molecular coupling between the enzyme and cellulose was performed, to establish the enzyme-cellulose molecular complex and then to identify the principal amino-acids of endo-β-1,4-D-glucanase in this molecular link, which are responsible for the hydrolysis of the cellulose.Experimental results show the feasibility to replace sodium hydroxide with the enzyme Cellulase Thricodema Sp., by obtaining deinked cellulose with similar optical and physical properties.The use of the enzyme instead of sodium hydroxide avoids the contamination of the residual water; in addition to that, the column is operated more easily, taking into consideration that the pH of the system goes from alkaline to neutral.

Electrochemical Sensing System for Detection of Tricresyl-phosphate

2011 ◽  
Author(s):  
Xiaoyun Yang ◽  
Ruel Overfelt ◽  
Alice Zitova ◽  
Aleksandr Simonian ◽  
Jeffrey Kirsch ◽  
...  
Keyword(s):  
Electrochemical Sensing ◽  
Tricresyl Phosphate ◽  
Sensing System

Copper Catalyzed sp3 C-H α-Acetylation

2019 ◽  
Author(s):  
Otome Okoromoba ◽  
Eun Sil Jang ◽  
Claire McMullin ◽  
Thomas Cundari ◽  
Timothy H. Warren
Keyword(s):  
Natural Products ◽  
Dft Studies ◽  
Alkyl Radicals ◽  
Important Chemical ◽  
Alkyl Electrophiles ◽  
Synthetic Intermediates ◽  
Alkylation Reactions

<p>α-substituted ketones are important chemical targets as synthetic intermediates as well as functionalities in in natural products and pharmaceuticals. We report the sp<sup>3</sup> C-H α-acetylation of sp<sup>3</sup> C-H substrates R-H with arylmethyl ketones ArC(O)Me to provide α-alkylated ketones ArC(O)CH<sub>2</sub>R at RT with <sup>t</sup>BuOO<sup>t</sup>Bu as oxidant via copper(I) β-diketiminato catalysts. Proceeding via alkyl radicals R•, this method enables α-substitution with bulky substituents without competing elimination that occurs in more traditional alkylation reactions between enolates and alkyl electrophiles. DFT studies suggest the intermediacy of copper(II) enolates [Cu<sup>II</sup>](CH<sub>2</sub>C(O)Ar) that capture alkyl radicals R• to give R-CH<sub>2</sub>C(O)Ar under competing dimerization of the copper(II) enolate to give the 1,4-diketone ArC(O)CH<sub>2</sub>CH<sub>2</sub>C(O)Ar.</p>

Copper Catalyzed sp3 C-H α-Acetylation

2019 ◽  
Author(s):  
Otome Okoromoba ◽  
Eun Sil Jang ◽  
Claire McMullin ◽  
Thomas Cundari ◽  
Timothy H. Warren
Keyword(s):  
Natural Products ◽  
Dft Studies ◽  
Alkyl Radicals ◽  
Important Chemical ◽  
Alkyl Electrophiles ◽  
Synthetic Intermediates ◽  
Alkylation Reactions

<p>α-substituted ketones are important chemical targets as synthetic intermediates as well as functionalities in in natural products and pharmaceuticals. We report the sp<sup>3</sup> C-H α-acetylation of sp<sup>3</sup> C-H substrates R-H with arylmethyl ketones ArC(O)Me to provide α-alkylated ketones ArC(O)CH<sub>2</sub>R at RT with <sup>t</sup>BuOO<sup>t</sup>Bu as oxidant via copper(I) β-diketiminato catalysts. Proceeding via alkyl radicals R•, this method enables α-substitution with bulky substituents without competing elimination that occurs in more traditional alkylation reactions between enolates and alkyl electrophiles. DFT studies suggest the intermediacy of copper(II) enolates [Cu<sup>II</sup>](CH<sub>2</sub>C(O)Ar) that capture alkyl radicals R• to give R-CH<sub>2</sub>C(O)Ar under competing dimerization of the copper(II) enolate to give the 1,4-diketone ArC(O)CH<sub>2</sub>CH<sub>2</sub>C(O)Ar.</p>

Scientific and technological aspects and prospects for application of cryogenic drilling technology

2020 ◽  
pp. 54-62
Author(s):  
A. B. Tulubaev ◽  
E. V. Panikarovskii
Keyword(s):  
Low Temperatures ◽  
Western Siberia ◽  
Wellbore Stability ◽  
Drilling Mud ◽  
Chemical Reagent ◽  
Production Chain ◽  
Foreign Experience ◽  
Permafrost Rocks ◽  
The North ◽  
Drilling Technology

In the article, we analyze types of drilling mud, which are used to drilling intervals of permafrost rocks; the importance of wellbore stability is noted. Wedescribethemain technologies, which have been being applied in the north of Western Siberia; these technologies are aimed at minimizing the loss wellbore stability due to violation of the temperature conditions in the well. We also analyze hydrocarbon systems, taking into account foreign experience, which is based on prospecting and exploratory drilling of ice deposits in Greenland and Antarctica. The article draws your attention to using synthetic fluids, monoesters and chladones. The difficulties of the existing technology and the disadvantages of the hydrocarbon systems are highlighted. We propose to apply a new cryogenic drilling technology, which consists in the use of synthetic fluorine-containing agents as flushing fluid at low temperatures. The text gives valuable information on composition of the proposed flushing fluid and the prospects of using the technology to prevent complications. Much attention is given to issue of manufacturing the main chemical reagent with the reduction of the generalized production chain of its production from the starting material, it is fluorspar.

Lime salts: origin and control in beet processing

2020 ◽  
pp. 282-287
Author(s):  
Jan Maarten de Bruijn
Keyword(s):  
Heat Transfer ◽  
Heat Exchange ◽  
Performance Indicator ◽  
Key Performance Indicator ◽  
Process Measures ◽  
Trouble Shooting ◽  
Important Chemical ◽  
And Control ◽  
Affect Processing ◽  
White Sugar

Lime salts in the thin juice obtained after juice purification is one of the most important chemical KPI’s (Key Performance Indicator) in beet processing. Too high lime salts content will significantly affect processing costs – particularly energy – due to scaling of heat exchange surfaces thus decreasing heat transfer. In addition, high lime salts are at the origin of turbidity and insoluble solids in white sugar. Therefore, it is of the utmost importance to understand the chemistry behind lime salts in beet processing in order to be able preventing too high lime salts contents in thin juice. This paper will explain the details of the chemistry behind the presence of lime salts. Further, a trouble-shooting guide is included to elucidate the different causes for high lime salts contents and how these causes can be identified, as well as the process measures to reduce the lime salts content in thin juice.

Electrochemical sensing of Sudan I using the modified graphite screen-printed electrode

2020 ◽  
pp. 1-14
Author(s):  
Somayeh Tajik ◽  
Hadi Beitollahi ◽  
Fariba Garkani Nejad ◽  
Mohadeseh Safaei ◽  
Peyman Mohammadzadeh Jahani
Keyword(s):  
Electrochemical Sensing ◽  
Screen Printed Electrode ◽  
Sudan I ◽  
Screen Printed

scholarly journals Simultaneous electrochemical sensing of dihydroxy benzene isomers at cost-effective allura red polymeric film modified glassy carbon electrode

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Pattan-Siddappa Ganesh ◽  
Ganesh Shimoga ◽  
Seok-Han Lee ◽  
Sang-Youn Kim ◽  
Eno E. Ebenso
Keyword(s):  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Limit Of Detection ◽  
Tap Water ◽  
Differential Pulse ◽  
Oxidation Potential ◽  
Electrochemical Sensing ◽  
Carbon Electrode ◽  
Buffer Solution ◽  
Allura Red

Abstract Background A simple and simultaneous electrochemical sensing platform was fabricated by electropolymerization of allura red on glassy carbon electrode (GCE) for the interference-free detection of dihydroxy benzene isomers. Methods The modified working electrode was characterized by electrochemical and field emission scanning electron microscopy methods. The modified electrode showed excellent electrocatalytic activity for the electrooxidation of catechol (CC) and hydroquinone (HQ) at physiological pH of 7.4 by cyclic voltammetric (CV) and differential pulse voltammetric (DPV) techniques. Results The effective split in the overlapped oxidation signal of CC and HQ was achieved in a binary mixture with peak to peak separation of 0.102 V and 0.103 V by CV and DPV techniques. The electrode kinetics was found to be adsorption-controlled. The oxidation potential directly depends on the pH of the buffer solution, and it witnessed the transfer of equal number of protons and electrons in the redox phenomenon. Conclusions The limit of detection (LOD) for CC and HQ was calculated to be 0.126 μM and 0.132 μM in the linear range of 0 to 80.0 μM and 0 to 110.0 μM, respectively, by ultra-sensitive DPV technique. The practical applicability of the proposed sensor was evaluated for tap water sample analysis, and good recovery rates were observed. Graphical abstract Electrocatalytic interaction of ALR/GCE with dihydroxy benzene isomers.

scholarly journals Numerical Analysis of the Bond Strength between Two Methacrylic Polymers by Surface Modification

Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3927
Author(s):  
Joanna Taczała ◽  
Katarzyna Rak ◽  
Jacek Sawicki ◽  
Michał Krasowski
Keyword(s):  
Numerical Analysis ◽  
Bond Strength ◽  
Angular Position ◽  
Fem Analysis ◽  
Groove Depth ◽  
Chemical Reagent ◽  
Shear Process ◽  
3D Geometry ◽  
The Right ◽  
Artificial Teeth

The creation of acrylic dentures involves many stages. One of them is to prepare the surfaces of artificial teeth for connection with the denture plates. The teeth could be rubbed with a chemical reagent, the surface could be developed, or retention hooks could be created. Preparation of the surface is used to improve the bond between the teeth and the plate. Choosing the right combination affects the length of denture use. This work focuses on a numerical analysis of grooving. The purpose of this article is to select the shape and size of the grooves that would most affect the quality of the bond strength. Two types of grooves in different dimensional configurations were analyzed. The variables were groove depth and width, and the distance between the grooves. Finally, 24 configurations were obtained. Models were analyzed in terms of their angular position to the loading force. Finite element method (FEM) analysis was performed on the 3D geometry created, which consisted of two polymer bodies under the shear process. The smallest values of the stresses and strains were characterized by a sample with parallel grooves with the grooving dimensions width 0.20 mm, thickness 0.10 mm, and distance between the grooves 5.00 mm, placed at an angle of 90°. The best dimensions from the parallel (III) and cross (#) grooves were compared experimentally. Specimens with grooving III were not damaged in the shear test. The research shows that the shape of the groove affects the distribution of stresses and strains. Combining the selected method with an adequately selected chemical reagent can significantly increase the strength of the connection.

Sign in / Sign up

Export Citation Format

Share Document