Heteroarchitecturing a Novel Three-Dimensional Hierarchical MoO2/MoS2/Carbon Electrode Material for High-Energy and Long-Life Lithium Storage

2021 ◽  
Author(s):  
Xufei Liu ◽  
Peng Mei ◽  
Yu Dou ◽  
Rui Luo ◽  
Yusuke Yamauchi ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Electrode Material ◽  
Electrode Materials ◽  
Three Dimensional ◽  
Lithium Ion ◽  
High Energy ◽  
Carbon Electrode ◽  
Lithium Storage ◽  
Large Capacity ◽  
Long Life

The urgent desire for high-energy lithium-ion batteries (LIBs) has motivated scientists to develop large-capacity electrode materials with innovative compositions and/or architectures. Herein, we report a three-dimensional (3D) hierarchical MoO2/MoS2/C heterostructure...

Cyano-bridged coordination polymer gel as a precursor to a nanoporous In2O3–Co3O4 hybrid network for high-capacity and cycle-stable lithium storage

2015 ◽  
Vol 39 (11) ◽  
pp. 8249-8253 ◽  
Author(s):  
Weiyu Zhang ◽  
Jinjing Zhang ◽  
Meiling Zhang ◽  
Chenxing Zhang ◽  
Anping Zhang ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
Three Dimensional ◽  
High Capacity ◽  
Lithium Ion ◽  
Hybrid Network ◽  
Polymer Gel ◽  
Lithium Storage ◽  
Long Life

A cyanogel-derived three-dimensional nanoporous In2O3–Co3O4 hybrid network as a high-capacity and long-life anode material for lithium-ion batteries.

High energy density lithium ion batteries using Li2.6Co0.4−xCuxN (anode) and Cu0.04V2O5 (cathode) electrode materials

2008 ◽  
Vol 62 (26) ◽  
pp. 4210-4212 ◽  
Author(s):  
Daliang Liu ◽  
Shiying Zhan ◽  
Gang Chen ◽  
Wencheng Pan ◽  
Chunzhong Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Lithium Ion Batteries ◽  
Electrode Materials ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Cathode Electrode

scholarly journals A mechanistic study of mesoporous TiO2 nanoparticle negative electrode materials with varying crystallinity for lithium ion batteries

2020 ◽  
Vol 8 (6) ◽  
pp. 3333-3343 ◽  
Author(s):  
Changjian Deng ◽  
Miu Lun Lau ◽  
Chunrong Ma ◽  
Paige Skinner ◽  
Yuzi Liu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Power Density ◽  
Electrode Materials ◽  
Negative Electrode ◽  
Lithium Ion ◽  
High Energy ◽  
Mesoporous Tio2 ◽  
Mechanistic Study ◽  
Negative Electrodes ◽  
Negative Electrode Materials

Nanoscale oxide-based negative electrodes are of great interest for lithium ion batteries due to their high energy/power density, and enhanced safety. The crystallinity effect of mesoporous TiO2 nanoparticle electrode was investigated in this work.

A universal strategy for thein situsynthesis of TiO2(B) nanosheets on pristine carbon nanomaterials for high-rate lithium storage

2018 ◽  
Vol 6 (16) ◽  
pp. 7070-7079 ◽  
Author(s):  
Long Pan ◽  
Zheng-Wei Zhou ◽  
Yi-Tao Liu ◽  
Xu-Ming Xie
Keyword(s):  
Synergistic Effect ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Carbon Nanomaterials ◽  
Lithium Ion ◽  
High Energy ◽  
High Rate ◽  
Lithium Storage ◽  
Storage Performance

A universal strategy is proposed for thein situsynthesis of TiO2(B) nanosheets on pristine carbon nanomaterials. Benefiting from a remarkable synergistic effect, the resulting nanohybrids exhibit superior high-rate lithium storage performance. In this sense, our strategy may open the door to next-generation, high-power and high-energy anode materials for lithium-ion batteries.

scholarly journals 3D Porous Ti3C2 MXene/NiCo-MOF Composites for Enhanced Lithium Storage

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 695 ◽  
Author(s):  
Yijun Liu ◽  
Ying He ◽  
Elif Vargun ◽  
Tomas Plachy ◽  
Petr Saha ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
High Current Density ◽  
Composite Films ◽  
Three Dimensional ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Energy Storage Devices ◽  
Lithium Storage ◽  
Hierarchical Porous

To improve Li storage capacity and the structural stability of Ti3C2 MXene-based electrode materials for lithium-ion batteries (LIBs), a facile strategy is developed to construct three-dimensional (3D) hierarchical porous Ti3C2/bimetal-organic framework (NiCo-MOF) nanoarchitectures as anodes for high-performance LIBs. 2D Ti3C2 nanosheets are coupled with NiCo-MOF nanoflakes induced by hydrogen bonds to form 3D Ti3C2/NiCo-MOF composite films through vacuum-assisted filtration technology. The morphology and electrochemical properties of Ti3C2/NiCo-MOF are influenced by the mass ratio of MOF to Ti3C2. Owing to the interconnected porous structures with a high specific surface area, rapid charge transfer process, and Li+ diffusion rate, the Ti3C2/NiCo-MOF-0.4 electrode delivers a high reversible capacity of 402 mAh g−1 at 0.1 A g−1 after 300 cycles; excellent rate performance (256 mAh g−1 at 1 A g−1); and long-term stability with a capacity retention of 85.7% even after 400 cycles at a high current density, much higher than pristine Ti3C2 MXene. The results highlight that Ti3C2/NiCo-MOF have great potential in the development of high-performance energy storage devices.

scholarly journals High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure

Energies ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1602 ◽  
Author(s):  
Jun-Ping Hu ◽  
Hang Sheng ◽  
Qi Deng ◽  
Qiang Ma ◽  
Jun Liu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Three Dimensional ◽  
Rate Capability ◽  
Lithium Ion ◽  
High Energy ◽  
High Rate ◽  
High Energy Density ◽  
High Rate Capability ◽  
Closed Structure ◽  
Short Lifecycle

LiNixCoyMnzO2 (LNCM)-layered materials are considered the most promising cathode for high-energy lithium ion batteries, but suffer from poor rate capability and short lifecycle. In addition, the LiNi1/3Co1/3Mn1/3O2 (NCM 111) is considered one of the most widely used LNCM cathodes because of its high energy density and good safety. Herein, a kind of NCM 111 with semi-closed structure was designed by controlling the amount of urea, which possesses high rate capability and long lifespan, exhibiting 140.9 mAh·g−1 at 0.85 A·g−1 and 114.3 mAh·g−1 at 1.70 A·g−1, respectively. The semi-closed structure is conducive to the infiltration of electrolytes and fast lithium ion-transfer inside the electrode material, thus improving the rate performance of the battery. Our work may provide an effective strategy for designing layered-cathode materials with high rate capability.

Three-dimensional Fe3O4/carbonaceous matrix with long-life performance for high-rate lithium ion batteries

2016 ◽  
Vol 688 ◽  
pp. 605-610 ◽  
Author(s):  
Yang Yu ◽  
Wei Wang ◽  
Zhihong Jing ◽  
Xiaofeng Zheng ◽  
Xiaoling Geng ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Three Dimensional ◽  
Lithium Ion ◽  
High Rate ◽  
Long Life

Al-doped VO2(B) nanobelts as cathode material with enhanced electrochemical properties for lithium-ion batteries

2018 ◽  
Vol 11 (04) ◽  
pp. 1850068 ◽  
Author(s):  
Changlei Niu
Keyword(s):  
Electrochemical Performance ◽  
Cathode Material ◽  
Lithium Ion Batteries ◽  
Valence State ◽  
Electrode Materials ◽  
High Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Free Standing ◽  
Lattice Volume

Aluminium has shown its superiority in stabilization of the monoclinic VO2(B) in free-standing nanobelts. In this paper, aluminium-doped VO2(B) nanobelts are successfully fabricated by a facile one-step hydrothermal method and used as cathode for lithium-ion battery. XPS results show that Al-doping promotes the formation of high valence state of vanadium in VO2(B) nanobelts. Due to the accommodation of valence state of vanadium and lattice volume, Al-doped VO2(B) nanobelts used as the cathode material for lithium-ion batteries exhibit better lithium storage properties with high capacity of 172[Formula: see text]mAh[Formula: see text]g[Formula: see text] and cycling stability than undoped VO2(B) nanobelts. This work demonstrates that the doping of aluminium can significantly enhance the electrochemical performance of VO2(B), suggesting that appropriate cationic doping is an efficient path to improve the electrochemical performance of electrode materials.

scholarly journals A review of laser electrode processing for development and manufacturing of lithium-ion batteries

Nanophotonics ◽  
2018 ◽  
Vol 7 (3) ◽  
pp. 549-573 ◽  
Author(s):  
Wilhelm Pfleging
Keyword(s):  
Electrochemical Performance ◽  
Thick Film ◽  
Laser Annealing ◽  
Electrode Materials ◽  
Positive Impact ◽  
Three Dimensional ◽  
Lithium Ion ◽  
High Energy ◽  
Active Surface Area ◽  
Lithium Ion Cells

AbstractLaser processes for cutting, annealing, structuring, and printing of battery materials have a great potential in order to minimize the fabrication costs and to increase the electrochemical performance and operational lifetime of lithium-ion cells. Hereby, a broad range of applications can be covered such as micro-batteries, mobile applications, electric vehicles, and stand-alone electric energy storage devices. Cost-efficient nanosecond (ns)-laser cutting of electrodes was one of the first laser technologies which were successfully transferred to industrial high-energy battery production. A defined thermal impact can be useful in electrode manufacturing which was demonstrated by laser annealing of thin-film electrodes for adjusting of battery active crystalline phases or by laser-based drying of composite thick-film electrodes for high-energy batteries. Ultrafast or ns-laser direct structuring or printing of electrode materials is a rather new technical approach in order to realize three-dimensional (3D) electrode architectures. Three-dimensional electrode configurations lead to a better electrochemical performance in comparison to conventional 2D one, due to an increased active surface area, reduced mechanical tensions during electrochemical cycling, and an overall reduced cell impedance. Furthermore, it was shown that for thick-film composite electrodes an increase of electrolyte wetting could be achieved by introducing 3D micro-/nano-structures. Laser structuring can turn electrodes into superwicking. This has a positive impact regarding an increased battery lifetime and a reliable battery production. Finally, laser processes can be up-scaled in order to transfer the 3D battery concept to high-energy and high-power lithium-ion cells.

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