Control over Interpenetration for Boosting Methane Storage Capacity in Metal‒Organic Frameworks

2021 ◽  
Author(s):  
Jing Tan ◽  
Yu Tao ◽  
Xiangyu Zhang ◽  
Qing Wang ◽  
Tengwu Zeng ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Heavy Duty ◽  
Metal Organic ◽  
Heavy Duty Vehicles

Metal‒organic frameworks (MOFs) have been recognized as prominent methane adsorbents for use in cleaner modes of transportation. Currently, ultrahigh methane deliverable capacity is required for use in heavy-duty vehicles and...

scholarly journals High Methane Storage Capacity in Aluminum Metal–Organic Frameworks

2014 ◽  
Vol 136 (14) ◽  
pp. 5271-5274 ◽  
Author(s):  
Felipe Gándara ◽  
Hiroyasu Furukawa ◽  
Seungkyu Lee ◽  
Omar M. Yaghi
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Aluminum Metal ◽  
Metal Organic

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

Achieving Large Volumetric Gas Storage Capacity in Metal–Organic Frameworks by Kinetic Trapping: A Case Study of Xenon Loading in MFU-4

2018 ◽  
Vol 140 (32) ◽  
pp. 10191-10197 ◽  
Author(s):  
Hana Bunzen ◽  
Felicitas Kolbe ◽  
Andreas Kalytta-Mewes ◽  
German Sastre ◽  
Eike Brunner ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Metal Organic ◽  
Kinetic Trapping

High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links

2016 ◽  
Vol 138 (32) ◽  
pp. 10244-10251 ◽  
Author(s):  
Juncong Jiang ◽  
Hiroyasu Furukawa ◽  
Yue-Biao Zhang ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

Enhanced water stability and high CO2 storage capacity of Lewis basic sites containing zirconium metal–organic framework

2021 ◽  
Author(s):  
Selcuk Demir ◽  
Nuray Bilgin ◽  
H. Merve Cepni ◽  
Hiroyasu Furukawa ◽  
Fatih Yilmaz ◽  
...  
Keyword(s):  
Metal Ions ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Co2 Storage ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
High Co2 ◽  
Metal Organic ◽  
Zirconium Metal ◽  
Selection Of

Metal–organic frameworks (MOFs) are an emerging class of materials employed for custom-designed purposes by judicious selection of the linker and the metal ions. Among the MOFs composed of carboxylate linkers,...

scholarly journals Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

2019 ◽  
Vol 55 (76) ◽  
pp. 11402-11405 ◽  
Author(s):  
Kai Shao ◽  
Jiyan Pei ◽  
Jia-Xin Wang ◽  
Yu Yang ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

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