A study of the rate of inversion of sucrose in aqueous solutions of some strongly dissociated acids: primary kinetic salt effects and acidity constants

Author(s):  
A. D. Pethybridge
1973 ◽  
Vol 26 (5) ◽  
pp. 1005 ◽  
Author(s):  
PD Bolton ◽  
J Ellis ◽  
KA Fleming ◽  
IR Lantzke

Thermodynamic acidity constants have been measured over the temperature range 5-50� for aqueous solutions of sodium 4?-dimethylaminoazobenzene- 4-sulphonate (methyl orange) and sodium 4?-dimethylaminoazobenzene-2- sulphonate (ortho-methyl orange). From these data values of the standard enthalpy, entropy, and heat capacity changes have been calculated for these compounds. These results are discussed in conjunction with previous spectrophotometric and other data with reference to the nature of the equilibrium systems involved in these protonation reactions. It is concluded that existing evidence does not allow an unequivocal assignment of the sites of protonation of these and related molecules.


1970 ◽  
Vol 59 (11) ◽  
pp. 1625-1630 ◽  
Author(s):  
Richard E. Lindstrom ◽  
Alexander R. Giaquinto

2016 ◽  
Vol 18 (22) ◽  
pp. 15060-15069 ◽  
Author(s):  
Katsuyoshi Aoki ◽  
Kentaro Shiraki ◽  
Toshiaki Hattori

The addition of salts into protein aqueous solutions causes changes in protein solubility and stability, the ability of which is known to be ordered in the Hofmeister series.


Talanta ◽  
1987 ◽  
Vol 34 (12) ◽  
pp. 1039-1042 ◽  
Author(s):  
G Reartes

2011 ◽  
Vol 45 (1) ◽  
pp. 555-562 ◽  
Author(s):  
Ran Zhang ◽  
Tongfei Shi ◽  
Lijia An ◽  
Qingrong Huang

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