scholarly journals Water-Sediment Partition of Polycyclic Aromatic Hydrocarbons (PAHs) in Nansi Lake

2018 ◽  
Vol 38 ◽  
pp. 02003
Author(s):  
Guizhai Zhang ◽  
Youjiang Diao
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Field Data ◽  
Low Molecular Weight ◽  
Nansi Lake ◽  
Water And Sediment ◽  
Kd Values ◽  
Polycyclic Aromatic ◽  
High Molecular Weight Pahs

Based on field data of polycyclic aromatic hydrocarbons (PAHs) in water and sediment in Nansi Lake. The concentrations and the partitioning characteristic of PAHs in the water and sediment were studied. The lgKd of high molecular weight PAHs were higher than the low molecular weight PAHs. The most of PAHs Kd values were negligible correlated with TOC, soluble salt, clay and pH of the sediment in Nansi Lake.

scholarly journals Investigation and Assessment of Polycyclic Aromatic Hydrocarbons Concentrations in Sediments at Drainage Discharge Points into the Mangrove Stretch of New Calabar River, Port Harcourt, Nigeria

2020 ◽  
Vol 3 (4) ◽  
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Low Molecular Weight ◽  
Total Pahs ◽  
Standard Procedures ◽  
Mangrove Wetlands ◽  
Port Harcourt ◽  
Polycyclic Aromatic ◽  
High Molecular Weight Pahs

Sediment samples were collected from surface of sediments from parts of the mangrove wetlands of the New Calabar River at points of effluents discharge. The samples were treated according to standard procedures and analyzed for the concentrations of polycyclic aromatic hydrocarbons (PAHs). The results showed the presence of ten PAHs at Iwofe Jetty and Police Post stations and eleven PAHs at the Minipiti station. The summation of the total PAHs in the stations showed 23.440, 33.694 and 51.094 mg/Kg in sediments from Iwofe Jetty, Minipiti and Police Post stations respectively. Pyrene was the most abundant PAH in sediment from Iwofe station, Dibenzo (a,h) anthracene was the most abundant PAH at the Minipiti Station and acenaphthylene was the most abundant PAH at the Police Post Station. The categorization of the PAHs classes showed that the high molecular weight PAHs (HMW PAHS) were more abundant than the low molecular weight (PAHs) in all the stations examined, although, at the Police Post station, the values were very close. The 4-membered rings were more abundant in sediments from Iwofe Jetty station. The 4 and 5-membered rings were more abundant at the Minipiti station and the 2-3 membered rings were dominant at the police Post station. The 6-membered rings were the least abundant or undetected in all the stations. Source and origin diagnosis showed that LMW/ HMW PAHs as pyrogenic in all the stations, An/(An+Phe) ratio revealed pyrogenic sources of PAHs, Fl/(Fl+Pyr) analysis in all the stations indicated petrogenic origin of PAHs, BaA/ (BaA+Chr) evaluation in all the stations revealed pyrogenic sources of PAHs. The mixed sources of PAHs in the wetlands drainage discharge points calls for concern and therefore, efforts should be geared to identify the points at which they were introduced into the effluents and be adequately controlled to prevent harm to the environment.

scholarly journals Concentrations and Sources of Polycyclic Aromatic Hydrocarbons in the Seawater around Langkawi Island, Malaysia

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Essam Nasher ◽  
Lee Yook Heng ◽  
Zuriati Zakaria ◽  
Salmijah Surif
Keyword(s):  
Molecular Weight ◽  
European Union ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Organic Carbon ◽  
Aromatic Hydrocarbons ◽  
Significant Positive Correlation ◽  
Fish Farms ◽  
Secondary Sources ◽  
Polycyclic Aromatic ◽  
High Molecular Weight Pahs

This paper reports the levels of polycyclic aromatic hydrocarbons (PAHs) in the water around the Island and their probable sources. Water samples were collected from four jetties and three marine fish farms around the main Langkawi Island and analysed for 18 polycyclic aromatic hydrocarbons (PAHs) in December 2010. The total PAH concentrations ranged from 6.1 ± 0.43 to 46 ± 0.42 μgL−1, which exceed the maximum admissible concentrations of PAHs (0.20 μgL−1) for the water standard of European Union. The calculated diagnostic benzo[a]anthracene : benzo[a]anthracene + chrysene ratio of between 0.52 and 1.0 suggests that the sources of PAHs at the majority of the stations studied are derived primarily from pyrogenic sources, from incomplete fuel combustion of the boats and vehicle engines, with lesser amounts of PAHs contributed from petrogenic sources. Some stations displayed mixed sources. A significant positive correlation was found between total organic carbon (TOC) and the concentrations of the high-molecular-weight PAHs (r2=0.86,P<0.05), which suggests significant secondary sources of PAHs, such as those from atmospheric deposition.

scholarly journals The significance of pyrogenic polycyclic aromatic hydrocarbons in Borneo peat core for the reconstruction of fire history

PLoS ONE ◽  
2021 ◽  
Vol 16 (9) ◽  
pp. e0256853
Author(s):  
Sher-Rine Kong ◽  
Masanobu Yamamoto ◽  
Hasrizal Shaari ◽  
Ryoma Hayashi ◽  
Osamu Seki ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Fire History ◽  
Low Molecular Weight ◽  
Aromatic Rings ◽  
Peat Core ◽  
Polycyclic Aromatic ◽  
Core Depth ◽  
Similar Depth

The reconstruction of fire history is essential to understand the palaeoclimate and human history. Polycyclic aromatic hydrocarbons (PAHs) have been extensively used as a fire marker. In this work, the distribution of PAHs in Borneo peat archives was investigated to understand how PAHs reflect the palaeo-fire activity. In total, 52 peat samples were analysed from a Borneo peat core for the PAH analysis. Pyrogenic PAHs consist of 2–7 aromatic rings, some of which have methyl and ethyl groups. The results reveal that the concentration of pyrogenic PAHs fluctuated with the core depth. Compared to low-molecular-weight (LMW) PAHs, the high-molecular-weight (HMW) PAHs had a more similar depth variation to the charcoal abundance. This finding also suggests that the HMW PAHs were mainly formed at a local fire near the study area, while the LMW PAHs could be transported from remote locations.

Low molecular weight organic acids enhance the high molecular weight polycyclic aromatic hydrocarbons degradation by bacteria

Chemosphere ◽  
2019 ◽  
Vol 222 ◽  
pp. 132-140 ◽  
Author(s):  
Anithadevi Kenday Sivaram ◽  
Panneerselvan Logeshwaran ◽  
Robin Lockington ◽  
Ravi Naidu ◽  
Mallavarapu Megharaj
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Organic Acids ◽  
High Molecular Weight ◽  
Aromatic Hydrocarbons ◽  
Low Molecular Weight ◽  
Polycyclic Aromatic

scholarly journals Polycyclic Aromatic Hydrocarbons (PAHs) in water of Al-Kahlaa River in Missan Province, Iraq

2016 ◽  
Vol 21 (1) ◽  
pp. 1
Author(s):  
Salih Hassan Jazza ◽  
Abdul Hussain Y. Al-Adhub ◽  
Hamid T. Al-Saad
Keyword(s):  
Molecular Weight ◽  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Dry Weight ◽  
Reference Station ◽  
Low Molecular Weight ◽  
Treatment Unit ◽  
Tigris River ◽  
Polycyclic Aromatic ◽  
Total Concentrations

The present study was performed to have knowledge of Polycyclic Aromatic  Hydrocarbonspollution status in water. The samples were collected during two seasons (winter and summer 2012 ,2013) from four different stations) Al-Magideh, Treatment unit, Al-Husaichi and Al-Zubair) distributed along Al-KahlaaRiver in Missan province, in addition to reference station lies on the Tigris river before  25 Km  from entering to Amara city. The concentrations of PAHs were determined in by using capillary Gas Chromatography. Results of the present  study revealed that the total concentrations of PAHs  in dissolved fraction  ranged from 0.739 ng.l-1 in Reference station to 1.974 ng.l-1 in Treatment unit during winter, and from 0.300 ng.l-1 in Reference station to 1.125 ng.l-1 in Treatment unit during summer, while in the particulate fraction they varied from 0.79 ng.g-1 dry weight in Reference station to 24.42  ng.g-1 dry weight in Treatment unit during winter, and from 4.369 ng.g-1 dry weight in Reference station to 10.545 ng.g-1 dry weight in Al-Husaich during summer. It had been noticed that there were a predominance of high molecular weight PAHs on low molecular weight, while  BaA/(BaA+Chr) ratio in water ranged from 0.218 to 0.804. InP/(InP+BghiP) ratio ranged between 0 and 0.578,whereas Fl/Pyratio ranged between 0.150 and 2 ,this give an indication of  the origin  of PAHs compounds in water which were mainly pyrogenic and few from them  petrogenic. Keywords: polycyclic aromatic hydrocarbons, PAHs, water, pollution

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