scholarly journals Modelling of kinetic interface sensitive tracers reactive transport in 2D two-phase flow heterogeneous porous media

2019 ◽  
Vol 85 ◽  
pp. 07003 ◽  
Author(s):  
Alexandru Tatomir ◽  
Dejian Zhou ◽  
Huhao Gao ◽  
Alexandru-Nicolae Dimache ◽  
Iulian Iancu ◽  
...  
Keyword(s):  
Reactive Transport ◽  
Interfacial Area ◽  
Breakthrough Curves ◽  
Heterogeneous Porous Media ◽  
Contaminant Removal ◽  
Geothermal Systems ◽  
Two Phase ◽  
Gas Recovery ◽  
Two Fluids ◽  
Oil Gas

Fluid-fluid interfacial area plays an important role for mass- and energy-transfer processes across the interface which is relevant in several hydrogeological and engineering applications, e.g. enhanced oil-gas recovery, CO2 storage in geological formations, unconventional geothermal systems, contaminant removal, etc. Kinetic interface sensitive tracers were designed to determine the size of the interface between two fluids by undergoing hydrolysis at the fluid-fluid interface. This study investigates by means of numerical modelling the influence of heterogeneity on the KIS tracer breakthrough curves in six idealized scenarios (S1-S6). It is an extension of the previous work conducted in “one-dimensional” column experiments by Tatomir et al. (2018) [1]. The changes in interfacial area are created by inclusion of heterogeneities at the Darcy-scale. The results show that KIS tracers can be used in two-dimensional experimental setup and can provide information about the size and dynamic evolution of interfacial area. Therefore, this is a first step for the dimensioning of an experimental flume.

Estimation of the fluid-fluid interfacial area using kinetic interface sensitive tracers in dynamic porous media experiments

2021 ◽  
Author(s):  
Alexandru Tatomir ◽  
Huhao Gao ◽  
Hiwa Abdullah ◽  
Martin Sauter
Keyword(s):  
Porous Medium ◽  
Porous Media ◽  
Two Phase Flow ◽  
Organic Liquid ◽  
Column Experiment ◽  
Interfacial Area ◽  
Breakthrough Curves ◽  
Water Soluble ◽  
Phase Flow ◽  
Two Phase

<p>Fluid-fluid interfacial area (IFA) in a two-phase flow in porous media is an important parameter for many geoscientific applications involving mass- and energy-transfer processes between the fluid-phases. Schaffer et al. (2013) introduced a new category of reactive tracers termed kinetically interface sensitive (KIS) tracers, able to quantify the size of the fluid-fluid IFA. In our previous experiments (Tatomir et al., 2018) we have demonstrated the application of the KIS tracers in a highly-controlled column experiment filled with a well-characterized porous medium consisting of well-sorted, spherical glass beads.</p><p>In this work we investigate several types of glass-bead materials and natural sands to quantitatively characterize the influence of the porous-medium grain-, pore-size and texture on the mobile interfacial area between an organic liquid and water. The fluid-fluid interfacial area is determined by interpretation of the breakthrough curves (BTCs) of the reaction product of the KIS tracer. When the tracer which is dissolved in the non-wetting phase meets the water, an irreversible hydrolysis process begins leading to the formation of two water-soluble products. For the experiments we use a peristaltic pump and a high precision injection pump to control the injection rate of the organic liquid and tracer.</p><p>A Darcy-scale numerical model is used to simulate the immiscible displacement process coupled with the reactive tracer transport across the fluid-fluid interface. The results show that the current reactive transport model is not always capable to reproduce the breakthrough curves of tracer experiments and that a new theoretical framework may be required.</p><p>Investigations of the role of solid surface area of the grains show that the grain surface roughness has an important influence on the IFA. . Furthermore, a linear relationship between the mobile capillary associated IFA and the inverse mean grain diameter can be established. The results are compared with the data collected from literature measured with high resolution microtomography and partitioning tracer methods. The capillary associated IFA values are consistently smaller because KIS tracers measure the mobile part of the interface. Through this study the applicability range of the KIS tracers is considerably expanded and the confidence in the robustness of the method is improved.</p><p> </p><p> </p><p>Schaffer M, Maier F, Licha T, Sauter M (2013) A new generation of tracers for the characterization of interfacial areas during supercritical carbon dioxide injections into deep saline aquifers: Kinetic interface-sensitive tracers (KIS tracer). International Journal of Greenhouse Gas Control 14:200–208. https://doi.org/10.1016/j.ijggc.2013.01.020</p><p>Tatomir A, Vriendt KD, Zhou D, et al (2018) Kinetic Interface Sensitive Tracers: Experimental Validation in a Two-Phase Flow Column Experiment. A Proof of Concept. Water Resources Research 54:10,223-10,241. https://doi.org/10.1029/2018WR022621</p>

A Multiscale Finite Element Framework for Reactive Contaminant Transport in Heterogeneous Porous Media

2008 ◽  
Author(s):  
K. B. Nakshatrala ◽  
A. J. Valocchi
Keyword(s):  
Reactive Transport ◽  
Chemical Species ◽  
Interfacial Area ◽  
Heterogeneous Porous Media ◽  
Major Influence ◽  
Small Scale ◽  
Full Resolution ◽  
Scale Heterogeneity ◽  
Reactive Pollutant ◽  
Reservoir Description

Mixing of chemical species across plume boundaries has a major influence upon the fate of the reactive pollutant in the subsurface. Small-scale heterogeneity leads to irregular plume boundaries which enhances mixing-controlled reactions through increasing the interfacial area of the plume. Therefore, it is crucial to capture this small-scale heterogeneity in order to properly model reactive transport. Unfortunately, computational limitations do not permit full resolution of the smallest scales of heterogeneity as the size of geomodels used for reservoir description typically exceeds by several orders of magnitude the capabilities of conventional reservoir simulators. Thus, it is necessary to use a coarse numerical grid, particularly for the cases with a large number of reactive species.

A phase field method pore-scale model for simulating kinetic interface sensitive tracers reactive transport in porous media two-phase flow systems

2020 ◽  
Author(s):  
Huhao Gao ◽  
Alexandru Tatomir ◽  
Nikolaos Karadimitriou ◽  
Martin Sauter
Keyword(s):  
Diffusion Process ◽  
Phase Field ◽  
Reactive Transport ◽  
Two Phase Flow ◽  
Interfacial Area ◽  
Field Method ◽  
Phase Field Method ◽  
Phase Flow ◽  
Pore Scale ◽  
Two Phase

<p>Over the last few years, our understanding of the processes involved in the application of Kinetic Interfacial Sensitive (KIS) tracers in two-phase flow as a means to quantify the fluid-fluid interfacial area has been enhanced with the use of controlled column experiments (Tatomir et al. 2015,2018). However, there are still some open questions regarding the effect of immobile water, either as capillary and dead-end trapped water or as a film, and the measured by product concentration at the outflow.</p><p>In this study, a new pore-scale reactive transport model is presented, based on the phase-field method, which is able to deal with the KIS tracer interfacial reaction and selective distribution of the by-production into the water phase. The model is validated by comparing the analytical solutions for a diffusion process across the interface and a reaction-diffusion process, and is tested for a drainage process in a capillary tube for different Péclet numbers. The applicability of the model is demonstrated in a realistic 2D porous medium NAPL/water drainage scenario used in the literature. Four case studies are investigated in detail to obtain macroscopic parameters, like saturation, capillary pressure, specific interfacial area, and concentration, for a number of combinations between the inflow rate, the contact angle and diffusivity. We derive a relation between the by-product mass at the outflow and the mobile part of the interfacial area, which is formulated by adding a residual factor. This term relates to the part of the by-product produced by mobile interface that becomes residual in the immobile zones.</p>

Lagrangian models of reactive transport in heterogeneous porous media with uncertain properties

2011 ◽  
Vol 468 (2140) ◽  
pp. 1154-1174 ◽  
Author(s):  
G. Severino ◽  
D. M. Tartakovsky ◽  
G. Srinivasan ◽  
H. Viswanathan
Keyword(s):  
Porous Media ◽  
Reactive Transport ◽  
Three Dimensional ◽  
Chemical Properties ◽  
Parametric Uncertainty ◽  
Bimolecular Reaction ◽  
Breakthrough Curves ◽  
Heterogeneous Porous Media ◽  
Advective Transport ◽  
Transport Parameters

We consider multi-component reactive transport in heterogeneous porous media with uncertain hydraulic and chemical properties. This parametric uncertainty is quantified by treating relevant flow and transport parameters as random fields, which renders the governing equations stochastic. We adopt a stochastic Lagrangian framework to replace a three-dimensional advection–reaction transport equation with a one-dimensional equation for solute travel times. We derive approximate expressions for breakthrough curves and their temporal moments. To illustrate our general theory, we consider advective transport of dissolved species undergoing an irreversible bimolecular reaction.

Pressure Drop for Oil-Gas Two-Phase Flow Through Straight Horizontal Pipe

2007 ◽  
Author(s):  
Wenhong Liu ◽  
Liejin Guo ◽  
Ximin Zhang ◽  
Kai Lin ◽  
Long Yang ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Two Phase Flow ◽  
Phase Flow ◽  
Two Phase ◽  
Horizontal Pipe ◽  
Flow Through ◽  
Oil Gas

Determination of specific interfacial areas in swirled two-phase flow

1983 ◽  
Vol 48 (3) ◽  
pp. 842-853
Author(s):  
Kurt Winkler ◽  
František Kaštánek ◽  
Jan Kratochvíl
Keyword(s):  
Interfacial Area ◽  
Liquid Volume ◽  
Upward Flow ◽  
Two Phase ◽  
Flow Rates ◽  
Mist Flow ◽  
Interfacial Areas ◽  
Correlation Parameters ◽  
Flow Components

Specific gas-liquid interfacial area in flow tubes 70 mm in diameter of the length 725 and 1 450 mm resp. containing various swirl bodies were measured for concurrent upward flow in the ranges of average gas (air) velocities 11 to 35 ms-1 and liquid flow rates 13 to 80 m3 m-2 h-1 using the method of CO2 absorption into NaOH solutions. Two different flow regimes were observed: slug flow swirled annular-mist flow. In the latter case the determination was carried out separately for the film and spray flow components, respectively. The obtained specific areas range between 500 to 20 000 m3 m-2. Correlation parameters are energy dissipation criteria, related to the geometrical reactor volume and to the static liquid volume in the reactor.

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