scholarly journals Sorption characteristics of ready-made mixtures containing oatflakes, apples, and cinnamon

2021 ◽  
Vol 286 ◽  
pp. 03003
Author(s):  
Albena Durakova ◽  
Adelina Vasileva ◽  
Kornelia Choroleeva

The present paper studies the sorption characteristics of readymade mixtures containing oatflakes – 89.5%, apples – 10%, and cinnamon – 0.5 % at the temperatures of 10°C, 25°C and 40°C and for eight water activities in the 11% - 85% range. The results obtained demonstrate that at a constant water activity, the increase in temperature is coupled with a decrease in equilibrium moisture content. The sorption isotherms of the analyzed ready-made mixture belong to Type III according to the classification of Brunauer et аl. In order to describe the isotherms following the evaluation criteria, that is mean relative error, standard deviation, and distribution of residuals, the study recommends the threeparameter modified Oswin for adsorption and the Henderson model for desorption. Via linearization of the Brunauer-Emmett-Teller model, we calculate the values of monolayer moisture content (MMC) at aw < 0.5 for both processes. For adsorption, the ММC falls within the 2.51% - 3.57% d.b. range, whereas for desorption it is within the 3.41% - 3.71% d.b. range. Temperature affects the MMC since its increase leads to a decrease in the ММC for both processes. For adsorption, at a temperature between 10°C and 40°C the ММC decreases by 1.06%, and for desorption - by 0.3%.

2019 ◽  
Vol 2 (2) ◽  
pp. 91
Author(s):  
Adelina Bogoeva ◽  
Albena Durakova ◽  
Velichka Yanakieva ◽  
Bozhidar Bozadzhiev

The current scientific research is focused on the sorption isotherms, monolayer moisture content and storage study of full-fatted grape seeds flakes (FGSF) of different grape variety locally grow in Bulgaria (Mavrud, Cabernet Sauvignon, Syrah, Merlot, Dimyat and Sauvignon Blanc). To determine the sorption characteristics of FGSF, we are used a static gravimetric method of saturated salt solution and relative humidity from 0.11 to 0.90 at three different temperatures – 10, 25 and 40°C. In the condition of constant water activity and increasing temperatures, the sorption capacity of the product decrease. We are recommend the modified Henderson model for description of sorption isotherms of FGSF. The monolayer moisture content values are obtained by linearization of Braunauer-Emmett-Teller (BET), in the range of Mmads = 2.32 ÷ 3.41, Mmdes = 2.59 ÷ 3.68. The three months storage study of samples was monitored at moisture value reduced to a value corresponded to the calculated monolayer moisture content. FGSF was packed in a co-extruded barrier film with copolymer covering for heat sealing, in the conditions for storage - temperature 18 ÷ 25°C and relative humidity 75 ÷ 85%. No living cells of pathogenic organisms (Escherichia coli, Staphylococcus aureus and Salmonella spp.) or apparent molding were detected. The flour particle size has not changed either.


2020 ◽  
Vol 180 ◽  
pp. 03008
Author(s):  
Albena Durakova

The present study determined the sorption characteristics of Bulgarian penny buns (Boletus) for eight water activities in the 10 % 90 % range and at three temperatures, of 10 °С, 25 °С and 40 °С. The coefficients of the modified Oswin, Chung-Pfost, Halsey and Henderson models were obtained statistically. The modified Halsey model is recommended as a description of adsorption and desorption isotherms since it corresponds to the criteria for model assessment and suitability. Via BET model linearization, the values of the monolayer moisture content for water activity of aw > 0.5 and temperatures of 10 °С, 25 °С and 40 °С were established. The approximate physico-chemical composition of Bulgarian penny buns (Boletus) – moisture content – 10.80 %, protein – 32.23 %, carbohydrate 0.99 %, fat – 6.62 %, ashes – 6.20 % - was also determined.


2021 ◽  
Vol 286 ◽  
pp. 03002
Author(s):  
Albena Durakova ◽  
Adelina Vasileva ◽  
Tzvetana Gogova ◽  
Milena Temelkova ◽  
Rumyana Krasteva

The current study presents a mixture for raw energy bars of fresh fruits of the exotic fruit Zizyphus jujuba Mill. with origin - Bulgaria. The physico-chemical indices of the ready mixture are analyzed. A high content of carbohydrates - 24.45% and of nourishing fiber - 22.08% is reported. The desorption capacity of the exotic mixture is examined for temperatures of 10°С, 25° and 40°С in eight watery activities from 11% to 85%. The analysis shows that the equilibrium moisture lowers with the raise of temperature in constant watery activities. The desorption isotherms are of type III according to the classification of Brunauer et al. The modified model of Halsey is recommended for the isotherms description according to the estimation criteria distribution, and the model of Oswin - as a second modified model. The values of the monolayer moisture content in aw <0.5 for temperatures 10°С - 5.46% dry basis (d.b.), 25°С - 5.72% d.b. and 40°C - 4.05% d.b. are calculated Brunauer-Emett-Teller model.


2013 ◽  
Vol 9 (4) ◽  
pp. 499-504 ◽  
Author(s):  
Ocheme Boniface Ocheme ◽  
Chukwuma Charles Ariahu ◽  
Emmanuel Kongo Ingbian

AbstractThe moisture sorption characteristics of dakuwa at 10, 20, 30 and 400°C were studied. The experimental sorption data obtained were applied to BET, GAB, Oswin and Henderson equations to test fitness of the equations to moisture sorption of dakuwa. The sorption isotherms of dakuwa were type III isotherms (J shaped), and the equilibrium moisture content increased with increasing water activity but decreased with increasing temperature. The BET and GAB monolayer moisture contents all decreased with increasing temperature. For adsorption, the BET monolayer was higher (3.163–4.158 g/100 g solid) than that of GAB (2.931–3.728 g/100 g solid), but for desorption, the GAB monolayer (4.792–7.741 g/100 g solid) was higher than that of BET (3.962–4.480 g/100 g solid). Evaluation of goodness of fit of models revealed that moisture sorption of dakuwa was best modelled by GAB equation.


Author(s):  
Traiphop PHAHOM

The research delved into the sorption characteristics of dried crab stick products using dynamic vapor sorption (DVS). The obtained sorption isotherm data, including equilibrium moisture content (Me) and water activity (aw), were fitted with 6 different sorption isotherm models, such as Brunauer-Emmett-Teller (BET), Guggenheim-Anderson-Boer (GAB), Pickett-Modified BET, Adam and Shove, Blahovec-Yanniotis, and Peleg. The results showed that the Peleg model was the best-describing model with a coefficient of determination (R2), chi-square (χ2), root mean square error (RMSE), and standard error of estimate (SEE) ranging from 0.988 to 0.998, 0.719 to 4.349, 0.431 to 2.609 and 0.692 to 1.703, respectively. According to the classification of the shape of moisture sorption isotherm, the isotherm type III and II were found in this research for adsorption and desorption, respectively. The GAB and BET models were used to estimate monolayer moisture content (M0) of the sample and it was found that the M0 ranged from 3.65 to 5.36 % dry basis and 4.57 to 4.83 % dry basis for GAB and BET models, respectively. Blahovec-Yanniotis’s model was applied in this work to investigate the contribution of water and the result showed that the contribution of solution water played a major in the moisture changes of the sample during the adsorption and desorption process. Moreover, sorption isotherm data were modeled with 0 and 1st order reaction kinetics, and the results demonstrated that 0 order and 1st order models were the most appropriate model to describe moisture changes behavior of the sample at each relative humidity step for adsorption and desorption, respectively. HIGHLIGHTS The construction of sorption isotherms of dried crab stick product using dynamic vapor sorption GAB and BET models were used to estimate monolayer moisture content Peleg model was the most appropriate model to describe sorption behaviors of dried crab stick product Blahovec-Yanniotis provided the contribution of water information of dried crab stick during adsorption and desorption processes The application of reaction order kinetics could provide the information of moisture changing behaviors at each relative humidity step for adsorption and desorption processes GRAPHICAL ABSTRACT


Foods ◽  
2020 ◽  
Vol 9 (1) ◽  
pp. 50
Author(s):  
Nasim Mansoori ◽  
Mahsa Majzoobi ◽  
Mohsen Gavahian ◽  
Fojan Badii ◽  
Asgar Farahnaky

The thermoplastic and hygroscopic behaviors of date syrup (DS) challenge the DS drying process. In this context, DS was mixed with 30%, 40%, 50%, and 60% acacia gum (AG) and subjected to a drum dryer. The chemical composition, bulk density (pb), caking degree (CD), glass transition temperature (Tg), and color values of DS powders were studied. The sorption isotherms were also obtained and compared to that of those predicted by mathematical models. According to the results, increasing the AG concentration enhanced the moisture content, pb, brightness, and Tg while it reduced the CD and equilibrium moisture sorption. All DS powders had type III isotherm behavior, i.e., similar to high-sugar foods. Guggenheim-Anderson-de Boer (GAB) and Peleg models were found to be suitable for fitting the experimental data and these models explained the monolayer moisture content decrease with increasing AG concentration. These results of the present study, for the first time, verified that the AG can be used as a natural anti-plasticizer agent for DS powder production.


2020 ◽  
Vol 180 ◽  
pp. 03007
Author(s):  
Albena Durakova ◽  
Adelina Bogoeva ◽  
Velichka Yanakieva ◽  
Tzvetana Gogova ◽  
Kornelia Choroleeva

The present study determined the physico-chemical parameters of the exotic fruit jujube (Ziziphus jujube mill) of Bulgarian origin – pH of 4.62, refractometric dry matter of 31.6 %, dry matter (in weight) of 36.78 %, TTA (total titratable acidity) – citric acid – of 0.67 %, 0.70 % malic acid, 65.95 % moisture, 0.78 % fibre, 1.41 % protein, 23.65 % carbohydrate, 0.24 % fat and energy value of 428.44 kJ/102.4 kcal. Equilibrium moisture content and monolayer moisture content were established for desorption concerning eight water activities in the 0.1 0.9 range and the temperatures of 10 °С, 25 °С and 40 °С. The coefficients of the modified Oswin, Chung-Pfost, Halsey and Henderson models were obtained statistically. The modified Halsey model is recommended as a description of the desorption isotherms of jujube (Ziziphus jujube mill) since it corresponds to the criteria for model assessment and suitability. Via BET model linearization, the values of the monolayer moisture content for desorption at the temperatures of 10 °С 5.41 % d.b., 25 °С – 4.65 % d.b. and 40 °С 5.08 % d.b were determined.


Author(s):  
J Roy ◽  
MA Alim ◽  
MN Islam

The study was carried out for the purpose of determining the drying kinetics as well as moisture sorption isotherm of hybrid-81 corn. Corn at about 31% moisture content (wb) was dried in a forced convective hot air cabinet dryer at different drying conditions, such as variable air dry bulb temperature (40°C, 50°C and 60°C) and loading density (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2) as well as in shining sun at different layers (3.56 kg/m2, 7.12 kg/m2, and 10.68 kg/m2). The water sorption isotherm of the dried corn was developed using vacuum desiccators, which contained saturated salt solutions in the range of 11-93% RHs. The mono-layer moisture content calculated by the Brunauer–Emmett–Teller (BET) model (6.76 g/100 g solid) was lesser than that calculated by the Guggenheim–Anderson–De Boer (GAB) model (10.53 g/100 g solid). The energy constants were 10.45 and 4.64 as per BET and GAB equation, respectively. Both models gave suitable fits for corn. The activation energy (Ea) for diffusion of water was found to be 11.09 kcal/gm-mole for corn. Furthermore, it was noticed that, with the increase of corn layer, the drying rate decreased in case of both sun and mechanical drying. However, higher loading density resulted in efficient drying, at least up to 10.7 kg/m2. It was shown that the drying time to obtain stability was the lowest for moisture content (12.08 %) corresponding to aw of 0.65 in case of BET or GAB monolayer moisture content. This finding could be helpful in predicting the storage life of corn.J. Bangladesh Agril. Univ. 15(2): 309-317, December 2017


2018 ◽  
Vol 16 (02) ◽  
pp. 35-42 ◽  
Author(s):  
Md Wadud Ahmed ◽  
Mohammad Gulzarul Aziz ◽  
Md Nazrul Islam

The moisture adsorption behavior is a fundamental knowledge in the processing and storage of food materials. In this paper, the experimental adsorption behavior of wheat, rice and corn flours were compared with five widely recommended adsorption models (BET, GAB, Oswin, Smith and Halsey) in the literature. From the sorption data, monolayer moisture content of wheat, rice and corn flours were estimated as per BET and GAB models. For all flours, GAB model gave higher monolayer moisture content compare to the BET model. Linear regression analysis was done to determine the model constants where all models were compared using regression coefficient and standard error of the estimate. It was observed that there is no single model that could describe accurately the sorption isotherm over the whole range of water activity (aw) and for all types of flours. BET model was found as the best model for the prediction of equilibrium moisture content (EMC) of the most stable region (i.e. EMC corresponding to aw range below 0.52) but it was not suitable at aw above 0.52. The GAB model was found to be the most suitable to predict the EMC for wide range of water activity (0.11 to 0.93). The Agriculturists 2018; 16(2) 35-42


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