SHEAR TRANSFORMATION IN SOLID 1 → SOLID 2 + GAS ENDOTHERMIC DECOMPOSITIONS

1977 ◽  
Vol 38 (C7) ◽  
pp. C7-365-C7-368 ◽  
Author(s):  
J. C. NIEPCE ◽  
G. WATELLE
Keyword(s):  
Author(s):  
F. I. Grace

An interest in NiTi alloys with near stoichiometric composition (55 NiTi) has intensified since they were found to exhibit a unique mechanical shape memory effect at the Naval Ordnance Laboratory some twelve years ago (thus refered to as NITINOL alloys). Since then, the microstructural mechanisms associated with the shape memory effect have been investigated and several interesting engineering applications have appeared.The shape memory effect implies that the alloy deformed from an initial shape will spontaneously return to that initial state upon heating. This behavior is reported to be related to a diffusionless shear transformation which takes place between similar but slightly different CsCl type structures.


Author(s):  
C. W. Allen ◽  
D. L. Kuruzar

The rare earth/transition element intermetallics R2T17 are essentially topologically close packed phases for which layer structure models have already been presented. Many of these compounds are known to undergo allotropic transformation of the type at elevated temperatures. It is not unexpected that shear transformation mechanisms are involved in view of the layering character of the structures. The transformations are evidently quite sluggish, illustrated in furnace cooled Dy2Co17 by the fact that only rarely has the low temperature rhombohedral form been seen. The more usual structures observed so far in furnace cooled alloys include 4H and 6H in Dy2Co17 (Figs. 1 and 2) . In any event it is quite clear that the general microstructure is very complicated as a consequence of the allotropy, illustrated in Fig. 3. Numerous planar defects in the layer plane orientation are evident as are non-layer plane defects inherited from a high temperature structure.


The results of an earlier paper are extended. The elastic field outside an inclusion or inhomogeneity is treated in greater detail. For a general inclusion the harmonic potential of a certain surface distribution may be used in place of the biharmonic potential used previously. The elastic field outside an ellipsoidal inclusion or inhomogeneity may be expressed entirely in terms of the harmonic potential of a solid ellipsoid. The solution gives incidentally the velocity field about an ellipsoid which is deforming homogeneously in a viscous fluid. An expression given previously for the strain energy of an ellipsoidal region which has undergone a shear transformation is generalized to the case where the region has elastic constants different from those of its surroundings. The Appendix outlines a general method of calculating biharmonic potentials.


2020 ◽  
Vol 130 ◽  
pp. 107-115
Author(s):  
Pengfei Xu ◽  
Jun Guo ◽  
Feng Chen ◽  
Yun Xiao ◽  
Qishou Xia ◽  
...  

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