scholarly journals Surface Response to Mechanics of Hardness and Wear Characteristics of Nanoscale Hydrophobic Film

2021 ◽  
Vol 347 ◽  
pp. 00017
Author(s):  
Akinsanya D. Baruwa ◽  
Elizabeth M. Makhatha ◽  
Esther T. Akinlabi

There is an increase in demand for durable and efficient organic nanoscale coatings for modern manufacturing systems and/or components for various applications. In wake of this demand, a new superhydrophobic silane compound was deposited on mild steel, stainless steel and titanium substrates which were pre-treated with alumina via the atomic layer deposition (ALD) method. Three substrates were considered for evolving properties comparison, also, determination of the influence of substrates’ response to films mechanical properties. The mechanical properties and the failure mechanics were investigated through nanoindentation and nanoscratch while the morphologies were examined through a field emission scanning electron microscope. The morphological evolution and mechanical viability indicated that stainless steel showed the most robust properties when compared with other substrates. Therefore, a nanoscale coating’s mechanical strength can be influenced by the substrate’s material compositions.

2011 ◽  
Vol 104 (1-2) ◽  
pp. 6-11 ◽  
Author(s):  
Hyemin Kang ◽  
Chang-Soo Lee ◽  
Do-Young Kim ◽  
Jungwon Kim ◽  
Wonyong Choi ◽  
...  

2020 ◽  
Vol 299 ◽  
pp. 1058-1063
Author(s):  
Denis Nazarov ◽  
Ilya Mitrofanov ◽  
Maxim Yu. Maximov

Tin oxide is the most promising material for thin film anodes of Li-ion batteries due to its cycling performance and high theoretical capacity. It is assumed that lithium-tin oxide can demonstrate even higher performance. Lithium-silicon-tin oxide nanofilms were prepared by atomic layer deposition (ALD), using the lithium bis (trimethylsilyl) amide (LiHMDS), tetraethyltin (TET) as a metal containing reagents and ozone or water or oxygen plasma as counter-reactants. Monocrystalline silicon (100) and stainless steel (316SS) were used as supports. The thicknesses of the nanofilms were measured by spectral ellipsometry (SE) and scanning electron microscopy (SEM). It was found that oxygen plasma is the most optimal ALD counter-reactant. The composition and structure were studied by Time-of-Flight Secondary Ion Mass Spectroscopy (ToF-SIMS), X-ray Photoelectron Spectroscopy (XPS) and X-ray diffraction (XRD). The nanofilms contain silicon as impurity, whose source is the ALD precursor (LiHMDS). The nanofilms deposited on stainless steel have shown the high Coulombic efficiency (99.1-99.8%) and cycling performance at a relatively high voltage (0.01 to 2.0V).


2016 ◽  
Vol 2016 ◽  
pp. 1-7 ◽  
Author(s):  
Anna Majtyka ◽  
Anna Nowak ◽  
Benoît Marchand ◽  
Dariusz Chrobak ◽  
Mikko Ritala ◽  
...  

The present paper pertains to mechanical properties and structure of nanocrystalline multiferroic BeFiO3(BFO) thin films, grown by atomic layer deposition (ALD) on the Si/SiO2/Pt substrate. The usage of sharp-tip-nanoindentation and multiple techniques of structure examination, namely, grazing incidence X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, and energy dispersive X-ray spectrometry, enabled us to detect changes in elastic properties(95 GPa≤E≤118 GPa)and hardness(4.50 GPa≤H≤7.96 GPa)of BFO after stages of annealing and observe their relation to the material’s structural evolution. Our experiments point towards an increase in structural homogeneity of the samples annealed for a longer time. To our best knowledge, the present report constitutes the first disclosure of nanoindentation mechanical characteristics of ALD-fabricated BeFiO3, providing a new insight into the phenomena that accompany structure formation and development of nanocrystalline multiferroics. We believe that our systematic characterization of the BFO layers carried out at consecutive stages of their deposition provides pertinent information which is needed to control and optimize its ALD fabrication.


2012 ◽  
Vol 522 ◽  
pp. 283-288 ◽  
Author(s):  
E. Marin ◽  
L. Guzman ◽  
A. Lanzutti ◽  
W. Ensinger ◽  
L. Fedrizzi

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