Structural and properties evolution of copper–nickel (Cu–Ni) alloys: a review of the effects of alloying materials

2021 ◽  
Vol 109 (2) ◽  
pp. 204
Author(s):  
Cynthia C. Nwaeju ◽  
Francis O. Edoziuno ◽  
Adeolu A. Adediran ◽  
Eugene E. Nnuka ◽  
Olanrewaju S. Adesina

Copper–nickel alloy has the potential in sustaining the recent demands in advanced marine engineering applications. It has been found advantageous over other copper alloys due to the unique properties and corrosion resistance they possess. However, the structure of Cu–Ni alloy alone is not sufficient to withstand many applications, as the structure cannot perform efficiently in an aggressive environment. The performance of this alloy inherently depends on carefully select alloying compositions, as the alloying elements are associated with the precipitation of intermetallic particles that will enhance mechanical properties and corrosion resistance when designing the component of Cu–Ni alloys. A combination of alloying elements has been conceptualized in the designing of copper–nickel alloy. This review described the role of alloying elements in modifying the microstructural features through phase transformation and how it affects the improvement of the mechanical and physical properties of Cu–Ni based alloys. The effect of alloying elements on the structure and properties of Cu–Ni alloys have been critically summarized based on surveying the works done by authors on this category of structural modification binary Cu–Ni alloy.

2019 ◽  
Vol 944 ◽  
pp. 389-397 ◽  
Author(s):  
Zhen Jiang Tan ◽  
Tong Da Ma ◽  
Li Min Zhang ◽  
Wen Mei Zhang ◽  
Rong Guang Jia ◽  
...  

Copper-Nickel alloy pipes in marine engineering have been suffering severe seawater corrosion and erosion-corrosion. In this work, six kinds of Cu-Ni alloy pipes with different service lives delivered by two manufacturers were used to clarify the relationship between corrosion resistance and microstructure. The corrosion behaviors of the samples in 3.5 wt.% NaCl solution were studied by electrochemical measurements. Chemical composition, grain size distribution, crystallographic orientation, and grain boundary characterization distribution (GBCD) were investigated by energy-dispersive spectrometry (EDS), metallography and electron backscattered diffraction (EBSD) technology. There were no obvious differences in chemical composition and GBCD in contrast with size and uniformity of grains. Pipes with large grains and a broader grain size distribution had better corrosion resistance. It was also found that the accuracy of experimental data greatly depended on the quality of the sample surface in EBSD analysis. The scratches and contamination during sample preparation have a strong impact on the imaging quality and the calculation of GBCD.


Alloy Digest ◽  
1978 ◽  
Vol 27 (2) ◽  

Abstract DRIVER 180 ALLOY is a copper-nickel alloy for use where moderate electrical resistance is required. The number designation refers to its specific resistivity (180 ohms/cir mil/ft) which is combined with a fairly low coefficient of resistance (180 x 10^-6 per C). Its maximum recommended operating temperature is 1000 F. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Cu-348. Producer or source: Wilbur B. Driver Company.


Alloy Digest ◽  
2006 ◽  
Vol 55 (7) ◽  

Abstract Olin Alloy C72200 is a chromium-containing copper-nickel alloy used extensively in seawater. The alloy is used for its corrosion-erosion resistance and is often called Cupronickel with Cr. This datasheet provides information on composition, physical properties, elasticity, tensile properties, and shear strength. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: CU-745. Producer or source: Olin Brass.


Alloy Digest ◽  
2002 ◽  
Vol 51 (6) ◽  

Abstract Wieland-L25 is a copper-nickel alloy used almost exclusively as a coining alloy. It shows little variation in its electrical conductivity. This datasheet provides information on composition, physical properties, hardness, and elasticity as well as deformation. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: CU-682. Producer or source: Wieland Metals Inc., Wieland-Werke AG.


2021 ◽  
Vol 68 (5) ◽  
pp. 365-372
Author(s):  
Yuhang Gao ◽  
Xiaohong Chen ◽  
Ping Liu ◽  
Honglei Zhou ◽  
Shaoli Fu ◽  
...  

Purpose This study aims to investigate the effect of coatings prepared by the addition of copper-aluminum alloy powder on the corrosion behavior of 90/10 copper-nickel alloy. Design/methodology/approach Coatings of copper-aluminum alloy powder at different contents (Wt.% = 50%, 60%, 70% and 80%) were prepared by the high-temperature heat treatment process. The microstructure and component of the coatings were characterized by scanning electron microscope, X-ray diffraction, energy dispersive spectrometer and X-ray photoelectron spectroscopy. The electrochemical properties of the coating were explored by electrochemical impedance spectroscopy. Findings The results show that the aluminized layer was successfully constructed on the surface of 90/10 copper-nickel alloy, the composition of the coating was composed of copper-aluminum phase and aluminum-nickel phase, the existence of the aluminum-nickel phase was formed by the diffusion of Ni elements within the substrate and because of the diffusion, the Al-Ni phase was distributed in the middle and bottom of the coating more. The Al-Ni phase is considered to be the enhanced phase for corrosion resistance. When the copper-aluminum alloy powder content is 70 Wt.%, the corrosion resistance is the best. Originality/value The enhancement of corrosion resistance of 90/10 copper-nickel alloy by the copper-aluminum alloy powder was revealed, the composition of the aluminized layer and the mechanism of corrosion resistance were discussed.


2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Yanbo Zhu ◽  
Xiaohong Chen ◽  
Ping Liu ◽  
Shaoli Fu ◽  
Honglei Zhou ◽  
...  

Purpose This study aims to investigate the effect of changes in iron content in 70/30 copper–nickel alloy on the corrosion process. Design/methodology/approach 70Copper–30Nickel-xFe-1Mn (x = 0.4,0.6,0.8,1.0 Wt.%) alloy were prepared by the high frequency induction melting furnace. The scanning electron microscope, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy were used to analyze the morphology and component of the corrosion product film. Findings The results show that the corrosion resistance of 70/30 copper–nickel alloy added with 1.0%Fe is the best, and the film is divided into inner dense Cu2O composite film and outer hydration loose layer; XRD showed that after adding 1.0% Fe, the content of Cu2(OH)3Cl in the corrosion product film was significantly reduced, while the content of Cu2O remained unchanged; XPS showed that nickel accumulates in the inner layer of corrosion product film; the stage growth mode of the film, the role of nickel in it and the enrichment mechanism of iron in the inner film were summarized and discussed. Originality/value The changes in the composition and structure of the corrosion product film caused by the iron content are revealed, and the mechanism of the difference in corrosion resistance is discussed.


2020 ◽  
Vol 27 (12) ◽  
pp. 2050018
Author(s):  
AHMET OZAN GEZERMAN

Anticorrosion requirements for the metallurgy, automotive, and aeronautical industries have increased in recent years, for which alternative plating chemicals must be developed. This study focuses on obtaining a Zn-Ni alloy plating with higher corrosion resistance and brightness. For this purpose, tetraethylenepentaamine as complexing agent, triethanolamine as the surfactant, and gelatin and [Formula: see text]-aminobenzenesulfonic acid as brightening agents for the plating were selected and their optimal concentrations were determined for applications. The optimal Zn-Ni ratio and plating thickness were analyzed using an X-ray Dal device. Improved plating performance of the Zn-Ni alloys was achieved with a Zn-Ni alloy containing 12–14% Ni.


Alloy Digest ◽  
1958 ◽  
Vol 7 (11) ◽  

Abstract CUPRO-NICKEL 30% is a copper-nickel alloy having high strength, ductility and corrosion resistance. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as creep. It also includes information on corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Cu-70. Producer or source: American Brass Company.


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