Intermolecular Nucleophilic Addition Reaction of C-7 Anions from N-bis(dimethylamino)phosphinoyl Indoles to Electrophiles/Arynes: Synthesis of 7-Substituted Indoles.
Keyword(s):
A novel approach for C-7 substitution of N-bis(dimethylamino)phosphinoyl indole by nucleophilic addition of C-7 carbanion to electrophiles and arynes is described and the directing group can be easily removed which provides a facile route for synthesis of 7-functionalized indoles.
1986 ◽
Vol 108
(10)
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pp. 2517-2527
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Keyword(s):
1976 ◽
Vol 17
(36)
◽
pp. 3109-3112
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1975 ◽
Vol 40
(9)
◽
pp. 2838-2844
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Keyword(s):