Monitoring the Impact of Sulfate Attack on a Cement-Clay Mix

Author(s):  
G. Di Emidio ◽  
R. D. Verástegui Flores
Keyword(s):  
2022 ◽  
Vol 961 (1) ◽  
pp. 012085
Author(s):  
Aseel Mansi ◽  
Nadhim Hamah Sor ◽  
Nahla Hilal ◽  
Shaker M A Qaidi

Abstract The use of nano clay to improve the qualities of construction materials and engineering applications has attracted a lot of discussion in recent years. This review article summarizes the influence of nano clay as a cement substitute and supplement on the performance of conventional and high-performance concrete. The addition of nano clay to high performance concrete revealed an increase in compressive and flexural strength, as well as durability attributes such as resistance to elevated temperatures and sulfate attack, while simultaneously decreasing porosity, permeability, and water absorption. This enhancement is a result of nano clay’s roles as nano reinforcements, nanofillers, nucleation sites, and reactive pozzolans, which promote hydration and increase material characteristics.


2021 ◽  
Vol 11 (2) ◽  
pp. 888
Author(s):  
Jin-Jun Guo ◽  
Peng-Qiang Liu ◽  
Cun-Liang Wu ◽  
Kun Wang

Dry–wet cycle conditions have significant effects on the corrosion of concrete under sulfate attack. However, previous studies have only applied them as a method for accelerating sulfate attack and not systematically studied them as an object. In order to explore the impact of sulfate attack with different dry–wet cycle periods on concrete, in this study, four dry–wet cycle periods (3, 7, 14, and 21 days) were selected. The flexure strength, relative dynamic modulus, and mass were tested, and the microstructures of the eroded specimens were also analyzed. The intensity and depth of sulfate erosion were influenced by the wet–dry cycle period. The results show that the deterioration of concrete first increased and then decreased with an extension of the dry–wet cycle period. Microstructural analysis indicated that, with an increase in the dry–wet cycle period, the corrosion depth of sulfate attack increased. Moreover, the erosion products such as ettringite and gypsum were greatly increased, in agreement with the macroscopic variations. However, excessively prolonging the dry–wet periods does not significantly further the deterioration of concrete’s performance. Therefore, considering the strength and depth of corrosion caused by sulfate attack, it would be appropriate to employ dry–wet cycle periods of 7–14 days under natural dry conditions in studies on concrete.


2015 ◽  
Vol 06 (06) ◽  
pp. 539-548
Author(s):  
Alexey Brykov ◽  
Anna Anisimova ◽  
Natalya Rozenkova ◽  
Mohammed Hadi ◽  
Maxim Mokeev

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Fang Liu ◽  
Zhanping You ◽  
Rui Xiong ◽  
Xu Yang

It has been widely observed that sulfate attack can damage the durability of concrete. This research investigated the mass loss and damage degree of concrete under sodium sulfate attack incorporated with drying-wetting cycles. The impact factors, including water-binder ratio, solution concentration of sodium sulfate, fly ash content, curing time, and drying-wetting cycle system, were observed to influence the sodium sulfate attack by the mass loss rate and damage degree at regular time intervals. Also, the hydrates of sulfate-attacked samples were analyzed using X-ray diffraction. Results indicated that a high water-binder and high-concentration sodium sulfate solution could accelerate the transportation of sulfate ion inside the concrete and the deterioration degree of concrete. Appropriate fly ash and longer curing time can effectively improve the internal pore structure of concrete to reduce the sulfate corrosion damage. The sulfate ion erosion and deterioration degree of the concrete are synchronously intensified along with the increase of the baking-immersing time ratio. The trend of the predicted life for concrete is basically consistent with the damage evolution result, indicating the feasibility of the Weibull distribution model to predict the service life of concrete under sodium sulfate attack incorporated with drying-wetting cycles.


1962 ◽  
Vol 14 ◽  
pp. 415-418
Author(s):  
K. P. Stanyukovich ◽  
V. A. Bronshten

The phenomena accompanying the impact of large meteorites on the surface of the Moon or of the Earth can be examined on the basis of the theory of explosive phenomena if we assume that, instead of an exploding meteorite moving inside the rock, we have an explosive charge (equivalent in energy), situated at a certain distance under the surface.


1962 ◽  
Vol 14 ◽  
pp. 169-257 ◽  
Author(s):  
J. Green

The term geo-sciences has been used here to include the disciplines geology, geophysics and geochemistry. However, in order to apply geophysics and geochemistry effectively one must begin with a geological model. Therefore, the science of geology should be used as the basis for lunar exploration. From an astronomical point of view, a lunar terrain heavily impacted with meteors appears the more reasonable; although from a geological standpoint, volcanism seems the more probable mechanism. A surface liberally marked with volcanic features has been advocated by such geologists as Bülow, Dana, Suess, von Wolff, Shaler, Spurr, and Kuno. In this paper, both the impact and volcanic hypotheses are considered in the application of the geo-sciences to manned lunar exploration. However, more emphasis is placed on the volcanic, or more correctly the defluidization, hypothesis to account for lunar surface features.


1997 ◽  
Vol 161 ◽  
pp. 197-201 ◽  
Author(s):  
Duncan Steel

AbstractWhilst lithopanspermia depends upon massive impacts occurring at a speed above some limit, the intact delivery of organic chemicals or other volatiles to a planet requires the impact speed to be below some other limit such that a significant fraction of that material escapes destruction. Thus the two opposite ends of the impact speed distributions are the regions of interest in the bioastronomical context, whereas much modelling work on impacts delivers, or makes use of, only the mean speed. Here the probability distributions of impact speeds upon Mars are calculated for (i) the orbital distribution of known asteroids; and (ii) the expected distribution of near-parabolic cometary orbits. It is found that cometary impacts are far more likely to eject rocks from Mars (over 99 percent of the cometary impacts are at speeds above 20 km/sec, but at most 5 percent of the asteroidal impacts); paradoxically, the objects impacting at speeds low enough to make organic/volatile survival possible (the asteroids) are those which are depleted in such species.


1997 ◽  
Vol 161 ◽  
pp. 189-195
Author(s):  
Cesare Guaita ◽  
Roberto Crippa ◽  
Federico Manzini

AbstractA large amount of CO has been detected above many SL9/Jupiter impacts. This gas was never detected before the collision. So, in our opinion, CO was released from a parent compound during the collision. We identify this compound as POM (polyoxymethylene), a formaldehyde (HCHO) polymer that, when suddenly heated, reformes monomeric HCHO. At temperatures higher than 1200°K HCHO cannot exist in molecular form and the most probable result of its decomposition is the formation of CO. At lower temperatures, HCHO can react with NH3 and/or HCN to form high UV-absorbing polymeric material. In our opinion, this kind of material has also to be taken in to account to explain the complex evolution of some SL9 impacts that we observed in CCD images taken with a blue filter.


1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.


Author(s):  
Lucien F. Trueb

Crushed and statically compressed Madagascar graphite that was explosively shocked at 425 kb by means of a planar flyer-plate is characterized by a black zone extending for 2 to 3 nun below the impact plane of the driver. Beyond this point, the material assumes the normal gray color of graphite. The thickness of the black zone is identical with the distance taken by the relaxation wave to overtake the compression wave.The main mechanical characteristic of the black material is its great hardness; steel scalpels and razor blades are readily blunted during attempts to cut it. An average microhardness value of 95-3 DPHN was obtained with a 10 kg load. This figure is a minimum because the indentations were usually cracked; 14.8 DPHN was measured in the gray zone.


Sign in / Sign up

Export Citation Format

Share Document