Kinetic regularities of solid-phase formation in the branching chain reaction of dichlorosilane oxidation in rf plasma at low pressures and 293 K

2006 ◽  
Vol 16 (1) ◽  
pp. 38-40 ◽  
Author(s):  
Nikolai M. Rubtsov ◽  
Georgii I. Tsvetkov ◽  
Victor I. Chernysh
Author(s):  
G. Schiller ◽  
M. Müller ◽  
F. Gitzhofer ◽  
M.I. Boulos ◽  
R.B. Heimann

Abstract Fine (median size 6 μm and 0.3 μm) cobalt spinel (Co3O4) powders were processed suspended in a suitable liquid phase. Suspensions exceeding 50 wt.% solid phase content were successfully injected into an inductively coupled plasma. Spheroidized powders with large particle size (up to 80 μm) were prepared, and cobalt oxide coatings were produced by this novel RF-SPS method. The microstructural features of the coatings can be controlled by parameter optimization similarly to plasma spraying of dry powders. Numerous variations of the physical and chemical conditions of the process were performed in an attempt to overcome the main disadvantage of the process, i.e. the decomposition of the spinel phase to CoO. So far, the spinel phase could be reestablished only by a post-treatment of the deposited coatings with atomic oxygen in the RF plasma.


1972 ◽  
Vol 60 (8) ◽  
pp. 1018-1018 ◽  
Author(s):  
A.M. Fern ◽  
J.O. McCaldin

2001 ◽  
Vol 299 (1) ◽  
pp. 24-30 ◽  
Author(s):  
Martin Huber ◽  
Doris Losert ◽  
Reinhard Hiller ◽  
Christian Harwanegg ◽  
Manfred W. Mueller ◽  
...  

Langmuir ◽  
2007 ◽  
Vol 23 (10) ◽  
pp. 5548-5556 ◽  
Author(s):  
Xin Chen ◽  
Sungjong Kwak ◽  
Michel Lafleur ◽  
Myer Bloom ◽  
Neil Kitson ◽  
...  

2014 ◽  
Vol 2014 ◽  
pp. 1-7
Author(s):  
Hongtao Wang ◽  
Lijuan Chen ◽  
Yongkang Lv ◽  
Jianwen Liu ◽  
Gang Feng

The chemisorptions of H2on fullerenes C60and C80, endofullerene Sc3C@C80and solid C60were comparatively studied. A chain reaction mechanism for dissociative adsorption of H2on solid C60is proposed under high pressure. The breaking of H–H bond is concerted with the formation of two C–H bonds on two adjacent C60in solid phase. The adsorption process is facilitated by the application of high pressure. The initial H2adsorption on two adjacent C60gives a much lower barrier 1.36 eV in comparison with the barrier of adsorption on a single C60(about 3.0 eV). As the stereo conjugate aromaticity of C60is destructed by the initial adsorption, some active sites are created. Hence the successive adsorption becomes easier with much low barriers (0.6 eV). In addition, further adsorption can create new active sites for the next adsorption. Thus, a chain reaction path is formed with the initial adsorption dominating the whole adsorption process.


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