The Photoelectron Spectrum of 1-Bromonortricyclene
Keyword(s):
The He I photoelectron spectrum of 1-bromotricyclo[2.2.1.02.6] heptane (1- bromonortricyclene ) is compared with that of the parent alkane . Extensive conjugation between bromine and alkane orbitals in the low ionization-energy range produces a complex band pattern which is adequately described by ab initio valence-electron molecular orbital calculations. Consequently 1-bromo-nortricyclene presents a rare example of an alkyl halide in which the halogen character is neither highly localized nor smeared over a high density of states.
1979 ◽
Vol 170
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pp. 285-292
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1975 ◽
Vol 343
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pp. 1-10
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1975 ◽
Vol 30
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pp. 58-59
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1981 ◽
Vol 36
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pp. 1246-1252
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1997 ◽
Vol 393
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pp. 121-126
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