Primary and conditional basic exchangeable cations in Australian soil profiles

Soil Research ◽  
1975 ◽  
Vol 13 (1) ◽  
pp. 91
Author(s):  
BM Tucker

The examination of a range of soil profiles showed that both primary and conditional exchangeable calcium, magnesium and sodium are present in all the soils, but the proportions of these subsets vary widely. There are some general correlations with profile form, and it is likely that the partition of these exchangeable cations will prove useful in studying the properties and behaviour of soils. Potassium differs from the other three cations in its exchange reactions-it is present almost entirely in the conditional subset-and it requires an additional exchange reagent to partition it successfully.


Soil Research ◽  
1977 ◽  
Vol 15 (3) ◽  
pp. 255 ◽  
Author(s):  
WW Emerson ◽  
CL Chi

Samples of illites, two extracted from soils, one from a shale, prepared with a range of exchangeable calcium, magnesium, sodium were immersed dry into water. The extent of dispersion with time was estimated visually and also deduced from the O.D. of the suspensions derived from the dispersed clay. The dispersion of wet calcium and magnesium soil illites sheared at a given water content and then immersed in water was also assessed visually. The dispersion of all three illites was enhanced when magnesium was the dominant cation rather than calcium. For the soil clays a lower ESP was required to initiate dispersion of the dry clay when immersed in water. Both calcium and magnesium forms of the shale illite dispersed partially over a period of several days when immersed dry into water, the magnesium to a greater extent than calcium. The magnesium form of the coarser of the two soil illites also dispersed slowly. By comparing the calcium-magnesium and calcium-sodium forms of the last clay, it was deduced that about 10 times the equivalent concentration of exchangeable magnesium as sodium was needed to cause the same degree of dispersion. For the other soil illite the water content for dispersion of the wet, sheared magnesium clay was found to be less than for the calcium clay. The O.D. of suspensions of the clays was found to decrease with increasing ESP and when magnesium was the dominant cation rather than calcium. This is explained in terms of particle aggregation. The ease of dispersion of the illites was correlated with particle size. Possible reasons for this, and the effect of magnesium, as opposed to calcium, on the forces between the clay particles are discussed.



Soil Research ◽  
1973 ◽  
Vol 11 (2) ◽  
pp. 151 ◽  
Author(s):  
WW Emerson ◽  
AC Bakker

Aggregates from the subsoils of four red-brown earths were brought into equilibrium with chloride solutions of known SAR, 1 mM in calcium or magnesium. The solutions were replaced by water and the amount of clay which subsequently dispersed from the aggregates measured. For the three soils from the same area, the ESP required to induce dispersion was about 3 for magnesium-sodium aggregates compared with 5 for calcium-sodium aggregates. For the other soil the respective ESP values had to be increased by a factor of 2. The increased resistance to dispersion of the latter was maintained even after sodium saturation. The results are used to show that differences in the dispersion of the natural aggregates in water are due primarily to the composition of the cations on the exchange sites, including aluminium. Shepparton aggregates of known ESP were wetted with water at 12 cm suction. Compared with calcium or magnesium aggregates, there was a marked further water uptake by magnesium-sodium aggregates for ESP > 3 and for calcium-sodium aggregates for ESP >9. The subsequent dispersion in water of such aggregates was much less than that of aggregates treated in the standard way. It is suggested that the spontaneous dispersion of clay from a wet aggregate of low ESP immersed in water depends on the gradient of the soluble salt concentration at the boundary of the intact portion of the aggregate, as well as the actual concentration.



Soil Research ◽  
1975 ◽  
Vol 13 (1) ◽  
pp. 77 ◽  
Author(s):  
BM Tucker

The sets of basic exchangeable cations in soil samples can be divided into subsets by changing the conditions under which their displacement takes place. Using a large cation (cholinium) in a nonaqueous solvent (alcohol), primary subsets of exchangeable calcium, magnesium and sodium are displaced. When ammonium ion in an aqueous solvent is used after this primary displacement, a conditionally exchangeable subset is obtained. Potassium is almost completely conditionally exchangeable in the soils studied. The conditional subsets may be further divided depending on whether the condition of using a smaller displacing cation (NH4+) or of having water present is met first. The concept of partition by exchange conditions is distinct from a partition based on exchange constants (under unchanged conditions) to which the epithets easily and difficultly exchangeable are appropriate.



Soil Research ◽  
1973 ◽  
Vol 11 (2) ◽  
pp. 143 ◽  
Author(s):  
AC Bakker ◽  
WW Emerson ◽  
JM Oades

The susceptibility to waterlogging of red-brown earth subsoils is discussed. One of these, Shepparton, has been leached with chloride solutions of given SAR, in the range 0-7, the last solution being 1 mM in calcium or magnesium. The soil was then extracted with neutral lM ammonium chloride and the displaced cations measured. The exchange of sodium for both calcium and magnesium was similar, following the Gapon equation except at very low SAR values. Some potassium and sodium was extracted from calcium and magnesium soils. Shepparton soil of known SAR was remoulded over a range of water contents and synthetic aggregates formed. The percentage of the clay fraction which dispersed from the aggregates was measured. The water content for perceptible dispersion of magnesium soil was only about half that of calcium soil, the water contents being near the 15 bar and 0.1 bar values respectively for unsheared soil. The water content for dispersion decreased sharply with increasing SAR of the soil. Calcium-sodium soil with an ESP of 3.5 dispersed at the same water content as magnesium soil. Possible reasons for the enhanced dispersion of sheared, wet magnesium soil compared with similar calcium soil are discussed.



2015 ◽  
Vol 2 (2) ◽  
pp. 148-158
Author(s):  
Surianto

Spodosol soil of Typic Placorthod sub-group of East Barito District is one of the problem soils with the presence of hardpan layer, low fertility, low water holding capacity, acid reaction and it is not suitable for oil palm cultivation without any properly specific management of land preparation and implemented best agronomic practices. A study was carried out to evaluate the soil characteristic of a big hole (A profile) and no big hole (B profile) system and comparative oil palm productivity among two planting systems. This study was conducted in Spodosol soil at oil palm plantation (coordinate X = 0281843 and Y = 9764116), East Barito District, Central Kalimantan Province on February 2014, by surveying of placic and ortstein depth and observing soil texture and chemical properties of 2 (two) oil palm's soil profiles that have been planted in five years. Big hole system of commercial oil palm field planting on the Spodosol soil area was designed for the specific purpose of minimizing the potential of a negative effect of shallow effective planting depth for oil palms growing due to the hardpan layer (placic and ortstein) presence as deep as 0.25 - 0.50 m. The big hole system is a planting hole type which was vertical-sided with 2.00 m x 1.50 m on top and bottom side and 3.00 m depth meanwhile the 2:1 drain was vertical-sided also with 1.50 m depth and 300 m length. Oil palm production was recorded from the year 2012 up to 2014. Results indicated that the fractions both big hole profile (A profile) and no big hole profile (B profile) were dominated by sands ranged from 60% to 92% and the highest sands content of non-big hole soil profile were found in A and E horizons (92%). Better distribution of sand and clay fractions content in between layers of big hole soil profiles of A profile sample is more uniform compared to the B profile sample. The mechanical holing and material mixing of soil materials of A soil profile among the upper and lower horizons i.e. A, E, B and C horizons before planting that resulted a better distribution of both soil texture (sands and clay) and chemical properties such as acidity value (pH), C-organic, N, C/N ratio, CEC, P-available and Exchangeable Bases. Investigation showed that exchangeable cations (Ca, Mg, K), were very low in soil layers (A profile) and horizons (B profile) investigated. The low exchangeable cations due to highly leached of bases to the lower layers and horizons. Besides, the palm which was planted on the big hole system showed good adaptation and response positively by growing well of tertiary and quaternary roots that the roots were penetrable into deeper rooting zone as much as >1.00 m depth. The roots can grow well and penetrate much deeper in A profile compared to the undisturbed hardpan layer (B profile). The FFB (fresh fruit bunches) production of the non-big hole block was higher than the big hole block for the first three years of production. This might be due to the high variation of monthly rainfall in-between years of observation from 2009 to 2014. Therefore, the hardness of placic and ortstein as unpenetrable agents by roots and water to prevent water loss and retain the water in the rhizosphere especially in the drier weather. In the high rainfall condition, the 2:1 drain to prevent water saturation in the oil palm rhizosphere by moving some water into the drain. Meanwhile, the disturbed soil horizon (big hole area) was drier than un disturbance immediately due to water removal to deeper layers. We concluded that both big hole and 2:1 drain are a suitable technology for Spodosol soil land especially in preparing palms planting to minimize the negative effect of the hardpan layer for oil palm growth.



2009 ◽  
Vol 44 (8) ◽  
pp. 996-1001 ◽  
Author(s):  
Pedro Rodolfo Siqueira Vendrame ◽  
Robélio Leandro Marchão ◽  
Osmar Rodrigues Brito ◽  
Maria de Fátima Guimarães ◽  
Thierry Becquer

The objective of this work was to assess the relationship between macrofauna, mineralogy and exchangeable calcium and magnesium in Cerrado Oxisols under pasture. Twelve collection points were chosen in the Distrito Federal and in Formosa municipality, Goiás state, Brazil, representing four soil groups with varied levels of calcium + magnesium and kaolinite/(kaolinite + gibbsite) ratios. Soil macrofauna was collected in triplicate at each collection point, and identified at the level of taxonomic groups. Macrofauna density showed correlation with contents of kaolinite, gibbsite and exchangeable Ca + Mg in the soils. Mineralogy and exchangeable Ca + Mg had significant effects on taxonomic groups and relative density of soil macrofauna. The termites (Isoptera) were more abundant in soils with low exchangeable Ca + Mg; earthworms (Oligochaeta), in soils with high levels of kaolinite; and Hemiptera and Coleoptera larvae were more abundant in gibbsitic soils with higher contents of total carbon.



Química Nova ◽  
2021 ◽  
Author(s):  
Andréia Rodrigues ◽  
Rômulo Angélica ◽  
Simone Paz

CATIONIC DIFFERENTIATION OF BENTONITES BY INFRARED: A STUDY OF THE HYDRATION EFFECTS OF EXCHANGEABLE CATIONS. In the bentonite industry, the most common procedure for quality control of the ore and the sodium activation process is the swelling method. However, this tool is restricted only to the differentiation of the sodium and non-sodium types, not considering the other cationic varieties. The objective of this study was to establish parameters for cationic differentiation of bentonites based on Near Infrared (NIR) and Medium (MIR) spectroscopy, which proved to be an effective technique in the cationic differentiation of bentonites using the characteristic bands “7072 cm-1” and “3620 and 3430 cm-1” under the condition of the dry-hydrated sample and not under the anhydrous condition. NIRS can be considered a measure of great scientific and technological contribution, as it allows the cationic differentiation of bentonites in a practical way and with low analytical cost.



1958 ◽  
Vol 38 (2) ◽  
pp. 105-115
Author(s):  
W. A. Ehrlich ◽  
R. E. Smith

The analysis of the principal horizons of 11 halomorphic profiles was undertaken in an attempt to ascertain, chiefly, the kind and quantity of soluble salts and exchangeable cations assumed to be the main causative agents in the formation of solonetzic soils in Manitoba. The results showed that water-soluble sodium was equal to or greater in quantity than water-soluble calcium or water-soluble magnesium; that exchangeable calcium followed closely by exchangeable magnesium dominated the exchange complexes; and that exchangeable sodium in excess of 15 per cent of the exchangeable cations was found only in some horizons of the Solonchak, Solonetz and Solodized-Solonetz soils in the Chesterfield Association.





Soil Research ◽  
2001 ◽  
Vol 39 (1) ◽  
pp. 81 ◽  
Author(s):  
Stuart William Johnston

Aeolian sediment collected from 2 locations across the ‘Main Range’ of Kosciuszko National Park, along with a series of soil profiles that were analysed for particle size, were used as a baseline from which to estimate the effects of aeolian sedimentation in this region. Laboratory analysis of the soil profiles indicated that the properties of the surface horizons of the alpine humus soils were heavily influenced by aeolian dust accumulation; however, the sub-surface horizons were mainly derived from the natural bedrock. The surface and subsurface horizons differed in texture bulk density, pH, electrical conductivity, exchangeable cations, and clay mineralogy. This study confirmed that the snow patch meadow soils exhibited particle size and mineralogy consistent with dust enrichment, with distinct bands being found in some profiles.



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